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Question 11

BSF RO 2022• Chemistry

CO2 when passed in excess, in lime water turns colourless again because of:

  1. AOption (a)

    Calcium Carbonate

  2. BOption (b)

    Calcium Bicarbonate

  3. COption (c)

    Calcium Chloride

  4. DOption (d)

    Copper Carbonate

View answer & explanation

Correct answer

Answer: (b)B.

Calcium Bicarbonate

Why this answer is correct

Explanation:

  • Calcium carbonate, which is insoluble in water and becomes milky, is created when CO2 is carried through lime water.
  • The milkiness, however, disappears when too much CO2 is added to the solution.
  • This results from the production of colorless, water-soluble calcium bicarbonate.
  • When too much CO2 is added, it combines with water (H2O) and calcium carbonate (CaCO3) to generate calcium bicarbonate (Ca(HCO3)2), which dissolves in water to make the solution clear once more.

Additional InformationCalcium Chloride:

  1. The term "lime chloride" refers to calcium chloride.
  2. Calcium chloride has the chemical formula CaCl2.
  3. Lime water has the chemical formula Ca(OH)2.
  4. When lime water and chlorine interact, CaOCl2, or bleaching powder, is created (chloride of lime).

Copper Carbonate:

  1. While copper oxide is dark, copper carbonate is green.
  2. During the response, we can notice color a shift from green to black.
  3. By shaking the gas produced in a container containing lime water, we can demonstrate this.
  4. It is evident that this gas causes the lime water to turn milky.

Question 12

BSF RO 2022• Chemistry

Arrange the following elements in the increasing order of their metallic property

Li, Na, K, Rb, Cs

  1. AOption (a)

    Na, Li, Rb, K, Cs

  2. BOption (b)

    Cs, Rb, K, Na, Li

  3. COption (c)

    Li, Na, K, Rb, Cs

  4. DOption (d)

    Li, Na, K, Cs, Rb

View answer & explanation

Correct answer

Answer: (c)C.

Li, Na, K, Rb, Cs

Why this answer is correct

Explanation:

Metallic Properties of Elements:

  • Thin sheets of metal can be pounded out.
  • It indicates that they have the quality of malleability.
  • Metals can bend easily.
  • They are able to be drawn into wires.
  • Metals are efficient heat and electrical conductors.
  • Metals have a glossy appearance because they are lustrous.
  • The tensile strength of metals is high.
  • It implies that they can support large weights.
  • Metals have a resonant sound.
  • It indicates that they produce a ringing sound.
  • Except for mercury, which is a liquid at ambient temperature, metals are solids at that temperature.
  • Metals are brittle. It implies that they are difficult to cut.

Metal Reactivity Series:

Metals are included in the Reactivity Series in decreasing order of Reactivity. The topmost metals are the most reactive, whereas the bottommost metals are the least reactive. Any two metals in the series can have their salt solutions replaced by the metal that is higher in the series for any two metals in the series.

Concept:

Since the group atomic radius grows as we descend, the metallic character also grows.

Question 13

BSF RO 2022• Chemistry

The most electronegative elements among the following is

  1. AOption (a)

    sodium

  2. BOption (b)

    chlorine

  3. COption (c)

    oxygen

  4. DOption (d)

    fluorine 

View answer & explanation

Correct answer

Answer: (d)D.

fluorine 

Why this answer is correct

Explanation:

Electronegativity:

  1. The ability of an atom to draw an electron-binding pair determines its electronegativity.
  2. The propensity of an atom of a certain chemical element to draw shared electrons when forming a chemical connection is known as electronegativity.
  3. The atomic number and the separation of the valence electrons from the charged nucleus have an impact on an atom's electronegativity.

Factors responsible for electronegativity of elements:

  • The atomic number and the separation of the valence electrons from the charged nucleus have an impact on an atom's electronegativity.
  • An atom or a substituent group will draw electrons in greater amounts the higher the associated electronegativity.
  • The number of protons in the nucleus, the distance from the nucleus, and the degree of inner electron screening all have an impact on electronegativity.

Concept:

Fluorine is the most electronegative element in the current periodic table because of its tiny atomic radius and significant nuclear charge, which have the strongest pull for the shared pair of electrons in a covalent connection with any other element.

Question 14

BSF RO 2022• Chemistry

Highly reactive metals are found in combined state in nature. The natural substances containing metal in combined form are known as minerals. A mineral is called ore if

  1. AOption (a)

    the metal present in the mineral is costly

  2. BOption (b)

    a metal can be extracted from it

  3. COption (c)

    a metal can be profitably extracted from it

  4. DOption (d)

    a metal cannot be extracted from it

View answer & explanation

Correct answer

Answer: (c)C.

a metal can be profitably extracted from it

Why this answer is correct

Explanation:

Minerals:

  • In terms of geology and mineralogy, a mineral or mineral species is, generally speaking, a pure, naturally occurring solid chemical compound with a fairly well-defined chemical makeup.
  • Minerals are those substances found in meals and in the ground that our bodies require for healthy growth and development.
  • Calcium, phosphorus, potassium, sodium, chloride, magnesium, iron, zinc, iodine, chromium, copper, fluoride, molybdenum, manganese, and selenium are among the nutrients that are crucial for good health.
  • Leaching methods such as tank leaching, heap leaching, dump leaching, and pressured leaching are typically used in the commercial extraction of metals from minerals.
  • A leaching solution is percolated through mined ore that has low concentrations (low grade) of the target components to perform dump leaching.
  • There are three primary techniques for removing metals from their ore.
  • These include reducing the ore with carbon, electrolyzing the molten ore, and reducing it with a more reactive metal.
  • Minerals are created when different elements are layered on top of one another.
  • Minerals are merely a grouping of one or more elements arranged in a shape known as a crystal structure.

Confusion Points

  • A mineral is called ore if a metal can be profitably extracted from it, in the option you might get confused with options 2 and 3, which looks the same, but we need to get an accurate answer, so option 3 is correct.

Question 15

BSF RO 2022• Chemistry

Consider the following statements,

I. In Mendeleev's Periodic Table, position of the isotopes was not fixed.

II. In the 19th Century, Mendeleev propounded periodic law is based on atomic mass.

Which of the above statement(s) is/are correct?

  1. AOption (a)

    Only I

  2. BOption (b)

    Only II

  3. COption (c)

    Both a and b

  4. DOption (d)

    Either of them

View answer & explanation

Correct answer

Answer: (c)C.

Both a and b

Why this answer is correct

Explanation:

Mendeleev's Periodic Table:

  1. A Russian scientist named Dmitri Mendeleev presented a paper on the Law of Octaves in 1869, just five years after John Newlands first proposed it.
  2. Mendeleev stated that "Element characteristics are a periodic function of their atomic weight" in his renowned periodic law.
  3. The Periodic Table of Mendeleev is a table that Mendeleev created to list elements in the order of their atomic weights.
  4. Isotopes of an element must be given distinct locations in the periodic table because they have various atomic masses, according to Mendeleev's Periodic Law.
  5. Because Mendeleev's periodic chart was structured in increasing order of atomic number, which is not how isotopes are arranged, and because isotopes share the same atomic number, no one isotope can fit into a single box in the periodic table.

Question 16

BSF RO 2022• Chemistry

When a spoon is to be electroplated with nickel the spoon is

  1. AOption (a)

    Dipped in a nickel sulphate solution

  2. BOption (b)

    made anode and a pure nickel rod, the cathode

  3. COption (c)

    made cathode and a pure nickel rod, the anode

  4. DOption (d)

    coated with nickel sulphate and dried

View answer & explanation

Correct answer

Answer: (c)C.

made cathode and a pure nickel rod, the anode

Why this answer is correct

Explanation:

Electroplating:

  • The technique of using electrodeposition to cover an object in a layer of metal is known as electroplating.
  • The required metal coating is transferred from an anode (a component that contains the metal that will be plated) to a cathode via controlled electrolysis (the part to be plated).
  • Use good electrical conductors, such as gold and silver, in integrated circuits that are used in computers, smartphones, and other electronic devices.
  • The many electroplating processes include rack plating, continuous plating, in-line plating, and mass plating (also known as barrel plating).
  • Electroplating is the technique of utilizing electrolysis to create a layer of one metal on top of another metal.
  • This thin coating aids in both improving the metal's look and shielding it from corroding.
  • The method of nickel electroplating involves plating metal components with a thin layer of nickel.
  • In a galvanic cell, a spoon is used as the cathode, while nickel is used as the anode to deposit Ni+ ions across the cathode to prepare for plating.

Concept:

Sulfamate nickel is used in the majority of engineering applications, however, a nickel chloride/nickel sulfate bath is used for nickel-plated strip steel. The Watts baths, which combine nickel sulfate, nickel chloride, and boric acid, are the most often used nickel baths.

Question 17

BSF RO 2022• Chemistry

Alcohol obtained in the saponification process is

  1. AOption (a)

    Ethyl alcohol

  2. BOption (b)

    Methyl alcohol

  3. COption (c)

    Wood spirit

  4. DOption (d)

    Glycerol

View answer & explanation

Correct answer

Answer: (d)D.

Glycerol

Why this answer is correct

Explanation:

Saponification:

Esters are transformed into soaps and alcohols through the process of saponification, which uses an aqueous alkali. Fatty acids, which are long-chain carboxylic acids, are the building blocks of soaps.

Preparation of Alcohols:

  1. Alkenes can be hydrated to produce alcohol, or aldehydes, ketones, acids, and esters can be reduced to produce alcohol.
  2. An alkene's double-bonded carbons can be added to using either a Markovnikov's or an anti-method.
  3. Markovnikov's e is created by reducing aldehydes, ketones, acids, and esters or hydrating alkenes.
  4. In the process of saponification, an ester and an inorganic base combine to create soap and alcohol.
  5. In most cases, it happens when triglycerides react with potassium or sodium hydroxide (lye) to create glycerol and fatty acid salt, sometimes known as "soap," from triglycerides.
  6. Ethyl Alcohol speeds up the saponification process by making the catalyst more soluble in the oil-ethyl ester phase.

Question 18

BSF RO 2022• Chemistry

Which one among the following statements is correct?

  1. AOption (a)

    All bases are alkalis

  2. BOption (b)

    None of the bases is alkali

  3. COption (c)

    There are no more bases except the alkalis

  4. DOption (d)

    All alkalis are bases but all bases are not alkalis

View answer & explanation

Correct answer

Answer: (d)D.

All alkalis are bases but all bases are not alkalis

Why this answer is correct

Explanation:

Alkali:

  1. Alkalis are substances that can dissolve in water, produce salts when combined with acids, and lessen the acidity of acids.
  2. Alkalis have an unpleasant taste and render some colors blue.
  3. Some alkalis can support the body's normal functioning.
  4. The alkali is sodium hydroxide, for instance.
  5. A basic, ionic salt of an alkali metal or an alkaline earth metal is referred to as an alkali in chemistry.
  6. A base that dissolves in water is another definition of an alkali.
  7. A soluble base solution has a pH higher than 7.0.
  8. While all alkalis are bases, not all bases are alkalis.
  9. Only those bases which are water soluble are alkalis.
  10. Bases known as alkalis dissolve in water.
  11. Lyes, ammonia, hair relaxers, nonphosphate detergents, dishwasher soaps, and disc batteries are examples of common alkali-containing materials.
  12. Sodium hydroxide (NaOH), potassium hydroxide (KOH), or calcium hydroxide (Ca(OH)2) are the main components of lyes, which are alkaline substances.

Question 19

BSF RO 2022• Chemistry

The pH of fresh ground water slightly decreases upon exposure to air because 

  1. AOption (a)

    carbon dioxide from air is dissolved in the water

  2. BOption (b)

    oxygen from air is dissolved in the water

  3. COption (c)

    the dissolved carbon dioxide of the ground water escapes into air

  4. DOption (d)

    the dissolved oxygen of the ground water escapes into air

View answer & explanation

Correct answer

Answer: (a)A.

carbon dioxide from air is dissolved in the water

Why this answer is correct

Explanation:

pH Value:

  • The pH scale determines how acidic or basic water is.
  • The range is 0 to 14, with 7 representing neutrality.
  • Acidity is indicated by pH values below 7, whereas baseness is shown by pH values above 7.
  • In reality, pH is a measurement of the proportion of free hydrogen and hydroxyl ions in water.

Factors Affecting pH Value:

  1. A water supply's inherent pH of 7 will typically become unbalanced when chemicals, minerals, pollutants, soil or bedrock composition, and other impurities interact with it.
  2. In summary, environmental conditions play a major role in determining the pH of water, whether it is high or low.
  3. Temperature increases cause a drop in pH.
  4. However, this does not imply that as the temperature rises, water's acidity does as well.
  5. If there are more hydrogen ions present in a solution than hydroxide ions, it is said to be acidic.

Question 20

BSF RO 2022• Chemistry

Complete the following chemical reaction:

Al2O3 + NaOH → ______ +H2O

  1. AOption (a)

    Al(OH)3

  2. BOption (b)

    Na2O

  3. COption (c)

    NaAlO2

  4. DOption (d)

    AlNaO2

View answer & explanation

Correct answer

Answer: (c)C.

NaAlO2

Why this answer is correct

Explanation:

  • Sodium aluminate and water are produced when aluminum oxide Al2O3 interacts with sodium hydroxide solution.
  • Between 900 and 1100 °C is the temperature at which this reaction occurs.
  • Aluminum oxide behaves as an acid in this reaction.

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