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Question 1

BSF RO 2022• Chemistry

Glass is

  1. AOption (a)

    Supercooled liquid

  2. BOption (b)

    Crystalline solid

  3. COption (c)

    Liquid crystal

  4. DOption (d)

    None of the above

View answer & explanation

Correct answer

Answer: (a)A.

Supercooled liquid

Why this answer is correct

Explanation:

Glass:

As the material does not develop a crystalline structure, the amorphous solids are known as supercooled liquids because they allow molecules to continue to move within them for very very short periods of time. Because of this tendency to flow like liquids, they are also known as pseudo solids or supercooled liquids.

When silica is used to make glass, it is cooled from a liquid condition; yet, even at temperatures under freezing, silica does not solidify. Glass is therefore a super-cooled liquid.

Thus, Glass is considered a supercooled liquid.

Additional InformationCrystalline Solid:

  • Crystalline solids typically have sharp melting points, well-defined edges, and faces, and exhibit x-ray diffractive.
  • Amorphous solids, on the other hand, have wavy or uneven surfaces, poorly resolved x-ray diffraction patterns, and a wide temperature range for melting.
  • Due to the short-range order or the lack of regularity in the arrangement of its molecular constituents, glass is an amorphous solid material.

Liquid Crystal:

  • The phrase "liquid crystal" refers to a thermodynamically stable phase that is a process change, or between the solid and isotropic liquid phases, and is characterized by anisotropy of characteristics without the presence of a three-dimensional crystal lattice.
  • In essence, glass is an amorphous solid.
  • It does not take the shape of crystals.
  • The glass's component parts can therefore move.
  • Under normal circumstances, the constituent particles of ordinary solids do not move.

Question 2

BSF RO 2022• Chemistry

Preparation of 'Dalda or Vanaspati' ghee from vegetable oil utilizes the following process

  1. AOption (a)

    Hydrolysis

  2. BOption (b)

    Oxidation

  3. COption (c)

    Hydrogenation

  4. DOption (d)

    Ozonolysis

View answer & explanation

Correct answer

Answer: (c)C.

Hydrogenation

Why this answer is correct

Explanation:

Hydrogenation:

  • A chemical reaction known as hydrogenation occurs when molecular hydrogen interacts with another substance or element, typically in the presence of a catalyst made of nickel, palladium, or platinum.
  • The method is frequently used to saturate or decrease organic molecules.
  • A chemical reaction between a substance or element and molecular hydrogen usually takes place with the aid of a catalyst.
  • Vanaspati is solidified and hydrogenated vegetable ghee from India. It costs a lot less than desi ghee.
  • Palm or palm olein oil is used to make all varieties of Vanaspati.
  • Nickel is used as a catalyst in reactors operating at low to medium pressure to produce hydrogenation.

Additional Information

Hydrolysis:

  • The term "hydrolysis" refers to the breaking of chemical bonds by the addition of water and describes the reaction of an organic compound with water to produce two or more new chemicals.
  • Some instances of hydrolysis include the formation of hydronium and bisulfate compounds when sulphuric acid is dissolved in water or a salt of a weak acid or base is dissolved in water.

Oxidation:

  • A chemical process that occurs when an object comes into contact with oxygen or another oxidizer.
  • Rust and an apple's brown color are examples of oxidation.

Ozonolysis:

  • When ozone is used in an organic chemical reaction to break the unsaturated bonds in alkenes, alkynes, and azo compounds, this process is known as ozonolysis.
  • The reaction is an organic redox one.
  • The two phases of ozonolysis reactions are as follows: Alkene molecules are initially attacked by ozone to create ozonide, and after that, hydrolysis occurs, causing bond cleavage.

Question 3

BSF RO 2022• Chemistry

The quality of petrol is expressed in terms of

  1. AOption (a)

    Cetane number

  2. BOption (b)

    Gold number

  3. COption (c)

    Octane number

  4. DOption (d)

    Added unleaded compounds

View answer & explanation

Correct answer

Answer: (c)C.

Octane number

Why this answer is correct

Explanation:

Petrol:

  • Petroleum-derived clear flammable liquid known as gasoline or petrol is the main fuel for the majority of spark-ignited internal combustion engines.
  • It primarily comprises organic chemicals derived from petroleum fractional distillation, supplemented with a number of additions.

Types of Petrol:

  • Regular unleaded has the lowest octane level of the three categories with a RON of 91.
  • When comparing gasoline prices liter for liter, it is frequently the least expensive.
  • The majority of locally made and Japanese automobiles are built to run on normal unleaded fuel.
  • The lowest RON rating for premium fuels is Premium 95, which is often in the center of the pricing range.
  • The majority of European automobiles demand at least 95RON.
  • The fuel with the highest octane rating, premium 98, is typically the most expensive.
  • This gasoline, according to some experts, is the most fuel-efficient.

Quality of Petrol:

  • The octane number is used to measure gasoline's ignition quality and the cetane number is used to measure diesel's.
  • The ignition quality of gas is typically measured by the octane rating or octane number (gasoline or petrol).
  • The higher this value, the less likely it is that the gas would "knock"—an explosion brought on by its early burning in the combustion chamber.
  • When burned in a typical internal combustion engine with spark ignition.

Question 4

BSF RO 2022• Chemistry

Which of the following is responsible for the conduction of electricity through the electrolytic solution?

  1. AOption (a)

    Movement of ions of electrolyte

  2. BOption (b)

    Movement of only positive charges

  3. COption (c)

    Movement of particles

  4. DOption (d)

    Movement of molecules

View answer & explanation

Correct answer

Answer: (a)A.

Movement of ions of electrolyte

Why this answer is correct

Explanation:

Electrolytic Solution:

The electrolyte solution is made up of an ionizable material, such as a salt or an acid, which is referred to as the electrolyte, and a liquid or solid phase that contains at least one component, such as water.

Factors responsible for the conduction of electricity in an electrolytic solution:

  • The ions that are present in electrolytes are the only factors contributing to their conductivity.
  • As there are more charge carriers if the ion concentration is higher, the conductivity of electrolytes will be high.
  • This is because the conductivity of electrolytes increases with an increase in ion concentration.
  • The electrolytic solution's ability to conduct electricity is due to the solvent's particle mobility.
  • The concentration of ions, the kind of ions present, and the solution's temperature are the three key variables that influence a solution's conductivity.

Question 5

BSF RO 2022• Chemistry

Which one of the following pairs of materials serves as electrodes in chargeable batteries commonly used in devices such as torch lights, electric shavers, etc.?

  1. AOption (a)

    Nickel and cadmium

  2. BOption (b)

    Zinc and carbon

  3. COption (c)

    Lead peroxide and lead

  4. DOption (d)

    Iron and cadmium

View answer & explanation

Correct answer

Answer: (a)A.

Nickel and cadmium

Why this answer is correct

Explanation:

Chargeable Batteries: 

In contrast to a disposable or main battery, which is delivered fully charged and thrown away after use, a rechargeable battery, storage battery, or secondary cell can be charged, discharged into a load, and recharged numerous times.

Electrodes:

  • Conductors used to make electrical contact with a non-metallic component of the circuit are known as electrodes.
  • An electrode is a conductor that establishes electrical contact with nonmetallic circuit components such as an electrolyte, a semiconductor, or a vacuum.
  • This can also be referred to as an anode or a cathode if it is in an electrochemical cell.
  • In rechargeable batteries, the negative electrode functions as the cathode during discharge and as the anode during charge.
  • Lead-acid, zinc-air, nickel-cadmium (NiCd), nickel-metal hydride (NiMH), lithium-ion (Li-ion), lithium iron phosphate (LiFePO4), and lithium-ion polymer are among the several electrode materials and electrolytes that are utilized (Li-ion polymer).
  • In contrast to other varieties of rechargeable cells the ability to deliver almost their entire rated capacity at high discharge rates is a key benefit of nickel-cadmium cells, which also have fair cycle life and performance at low temperatures (discharging in one hour or less).

Question 6

BSF RO 2022• Chemistry

Atomic theory of matter was given by

  1. AOption (a)

    Avogadro

  2. BOption (b)

    Dalton

  3. COption (c)

    Newton

  4. DOption (d)

    Pascal

View answer & explanation

Correct answer

Answer: (b)B.

Dalton

Why this answer is correct

Explanation:

The atomic theory of matter:

  • The atomic theory of matter, first proposed by JOHN DALTON, holds that each chemical element is composed of basic building blocks termed ATOMS.
  • An element's atoms are identical in every way.
  • All of these distinct elements—gold, copper, iron, and zinc—are composed of the same atoms.
  • The English chemist John Dalton put forward the modern atomic theory in about 1803.
  • The idea that all elements are made up of atoms is a fundamental one.

Postulates:

  1. Atoms make up all matter.
  2. Atoms are unbreakable and undividable.
  3. Two or more different types of atoms combine to create compounds.
  4. Atoms are rearranged during a chemical process.

Additional Information

  • The laws of motion were created by Newton.
  • According to the first law, until a force acts on an item, it will not alter its motion.
  • According to the second law, an object's force is determined by multiplying its mass by its acceleration.
  • According to the third law, when two objects interact, they exert equal-sized and opposite-direction pressures upon one another.
  • According to Avogadro's law, equal volumes of various gases each contain an equal number of molecules at the same temperature and pressure.
  • Under the presumption of an ideal (perfect) gas, this empirical relation can be deduced from the kinetic theory of gases.
  • Pascal's principle or the fluid pressure transfer principle are other names for Pascal's law.
  • Blaise Pascal, a French mathematician, formulated Pascal's law in 1653.
  • According to Pascal's law, pressure applied to a fluid inside of a container will be transmitted without a change in magnitude to every point within the fluid as well as the container's walls.
  • Any spot in the fluid experiences equal pressure in all directions.

Question 7

BSF RO 2022• Chemistry

Consider the following statements,

I. Atom consists of nucleus and shell.

II. Nucleus consists of protons and electrons.

III. Neutrons are present in atoms.

Which of the above statement(s) is/are correct?

  1. AOption (a)

    I and II

  2. BOption (b)

    I and III

  3. COption (c)

    Only II

  4. DOption (d)

    I, II and III

View answer & explanation

Correct answer

Answer: (b)B.

I and III

Why this answer is correct

Explanation:

Atoms:

  • A chemical element is uniquely defined by its atoms, which are tiny pieces of substance.
  • An atom is made up of a core nucleus and one or more negatively charged electrons that orbit it.

Atomic Structure:

  • An atom is a complicated configuration of negatively charged electrons grouped around a positively charged nucleus in certain shells.
  • Protons and neutrons make up the majority of the atom's mass in this nucleus (except for common hydrogen which has only one proton).
  • For instance, the nucleus of hydrogen is made up of a positively charged proton and a negatively charged electron.
  • On the periodic table of elements, the atomic structure is also depicted.
  • Every atom's nucleus has a neutron, with the exception of plain hydrogen, which does not.
  • The fact that the particle has no electrical charge—it is neutral—gives it its name.
  • Neutrons have a very high density.

Question 8

BSF RO 2022• Chemistry

Which of the following theory said that bond is formed between two atoms either by sharing or transfer of valence electrons?

  1. AOption (a)

    Valence shell electron pair repulsion.

  2. BOption (b)

    Molecular orbital theory

  3. COption (c)

    Valence bond theory

  4. DOption (d)

    Electronic theory of chemical bonding

View answer & explanation

Correct answer

Answer: (d)D.

Electronic theory of chemical bonding

Why this answer is correct

Explanation:

Valency:

The valence or valency of an element in chemistry is a measurement of how well it can combine with other atoms to form chemical compounds or molecules.

Types of Bonds:

Chemical bonds, also known as electrical forces, can be categorized into five different groups: ionic, covalent, metallic, van der Waals, and hydrogen bonds.

Valence Shell Electron Pair Repulsion Theory:

  • Based on the number of valence shell electron bond pairs between the atoms in a molecule or ion, the valence shell electron pair repulsion (VSEPR) theory is a model used to predict 3-D molecular shape.
  • According to this hypothesis, electron pairs will position themselves to reduce the consequences of their mutual repulsion.
  • In a molecule, electrons remain as far away from one another. Covalent bonds also contain electrons in addition to lone pairs.
  • To reduce repulsion and increase molecular stability, electron pairs will repel away from one another.

Valance Bond Theory:

  • The electrical structure of molecules is described by the valence bond theory.
  • According to the hypothesis, electrons fill each of an atom's atomic orbitals inside a molecule, and the nucleus of one atom is drawn to the electrons of another atom.

Molecular Orbital Theory:

  • According to the molecular orbital hypothesis, every atom has a tendency to group together to create molecular orbitals.
  • As a result of this configuration, electrons can be found in a variety of atomic orbitals and are frequently linked to diverse nuclei.

Electronic Theory of Chemical Bonding:

  • The electronic theory of valence was created by Kossel and Lewis to explain how chemical bonds are formed between two atoms.
  • By losing, acquiring, or sharing electrons, every atom strives to achieve octet configuration (the presence of eight electrons in its valence shell).

Question 9

BSF RO 2022• Chemistry

Which one among the following statements about an atom is not correct?

  1. AOption (a)

    Atoms always combine to form molecules.

  2. BOption (b)

    Atoms are the basic units from which molecules and ions are formed.

  3. COption (c)

    Atoms are always neutral in nature.

  4. DOption (d)

    Atoms aggregate in large numbers to form the matter that we can see, feel and touch.

View answer & explanation

Correct answer

Answer: (a)A.

Atoms always combine to form molecules.

Why this answer is correct

The correct answer is Atoms always combine to form molecules.

Key Points

  • Atoms are the smallest units of an element that retain its chemical properties.
  • The statement “Atoms always combine to form molecules” is not correct because some atoms can exist independently without forming molecules.
  • Noble gases such as Helium (He), Neon (Ne), and Argon (Ar) exist as single atoms due to their stable electronic configuration.
  • Atoms are the basic units from which molecules and ions are formed. Hence, statement 2 is correct.
  • Atoms are electrically neutral because they contain equal numbers of protons and electrons. Hence, statement 3 is correct.
  • Large numbers of atoms combine to form substances or matter that can be seen and touched. Hence, statement 4 is correct.
  • Statement-wise Analysis:
  • Atoms always combine to form molecules – Incorrect.
  • Atoms are the basic units from which molecules and ions are formed – Correct.
  • Atoms are always neutral in nature – Correct.
  • Atoms aggregate in large numbers to form matter – Correct.
  • Hence, the correct answer is Atoms always combine to form molecules.

Additional Information

  • Atom: Consists of protons, neutrons, and electrons.
  • Molecule: Formed when two or more atoms chemically combine together.
  • Ion: A charged particle formed by gain or loss of electrons.
  • Noble Gases: Known as inert gases because they are chemically less reactive.
  • John Dalton proposed the modern atomic theory in the early 19th century.

Important Points

  • Examples of Molecules:
  • O₂ – Oxygen molecule
  • H₂O – Water molecule
  • CO₂ – Carbon dioxide molecule
  • Examples of Monatomic Elements:
  • Helium (He)
  • Neon (Ne)
  • Argon (Ar)

Question 10

BSF RO 2022• Chemistry

In deep-sea diving, divers use a mixture of gases consisting of oxygen and

  1. AOption (a)

    Hydrogen

  2. BOption (b)

    Nitrogen

  3. COption (c)

    Argon

  4. DOption (d)

    Helium

View answer & explanation

Correct answer

Answer: (d)D.

Helium

Why this answer is correct

Explanation:

Deep-Sea Diving:

  • The act of going below the water's surface to engage with the environment is known as underwater diving.
  • It is also frequently referred to as "diving," a word that can indicate many things depending on the context.
  • Since deep sea diving permits divers to dive deeper than the 40-meter limit of scuba diving, it necessitates specialized training from diving professionals.
  • It is crucial to check that your oxygen analyzers are fully functional and equipped for dives deeper than you had planned.
  • Divers occasionally utilize heliox, a mixture of helium and oxygen, or trimix, which combines all three gases, in place of nitrox.
  • Both nitrogen and oxygen can sometimes cause a state that is akin to intoxication during dives.

Concept:

  1. Helium is added to the mixture to lessen the toxication, allowing divers to think more clearly.
  2. Additionally, using helium may allow divers to surface more quickly and without experiencing decompression sickness.
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