Select the correct option regarding the given statements.
Statement 1: The compound CH₃–CH₂–CHO is propanone.
Statement 2: Aldehydes are named using the suffix '–al'.
- AOption (a)
Statement 1 is true but Statement 2 is false.
- BOption (b)
Both statements are true but Statement 2 is not the correct explanation of Statement 1.
- COption (c)
Statement 1 is false but Statement 2 is true.
- DOption (d)
Both statements are true and Statement 2 is the correct explanation of Statement 1.
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Correct answer
Statement 1 is false but Statement 2 is true.
Why this answer is correct
The correct answer is Statement 1 is false but Statement 2 is true.
Key Points
- The chemical structure CH3−CH2−CHO consists of a three-carbon chain with a terminal carbonyl group bonded to a hydrogen atom, identifying it as an aldehyde. Under IUPAC nomenclature, a three-carbon aldehyde is named propanal, whereas propanone is a ketone with the formula CH3−CO−CH3. Hence, statement 1 is incorrect.
- The IUPAC system for naming organic compounds dictates that the presence of an aldehyde functional group is indicated by replacing the terminal '-e' of the parent alkane name with the suffix -al. For instance, ethane becomes ethanal and propane becomes propanal. Hence, statement 2 is correct.
Additional Information
- Aldehydes:
- These are compounds containing the −CHO functional group, where the carbon atom is double-bonded to oxygen and single-bonded to hydrogen.
- The aldehyde group is always located at the terminal position (end) of a carbon chain, meaning the carbon in this group is always assigned carbon-1 in numbering.
- Common examples include methanal (formaldehyde) and ethanal (acetaldehyde), which are used extensively in industrial synthesis.
- Ketones:
- These feature a carbonyl group (C=O) located at a non-terminal position, meaning it is bonded to two other carbon atoms.
- They are named using the suffix -one.
- Propanone, also known as acetone, is the simplest ketone and is widely used as a solvent in laboratory and industrial applications.