What is the typical oxide used along with aluminium in a thermite reaction?
- AOption (a)
Magnesium oxide
- BOption (b)
Copper oxide
- COption (c)
Zinc oxide
- DOption (d)
Iron (III) oxide
View answer & explanationHide answer & explanation
Correct answer
Iron (III) oxide
Why this answer is correct
The correct answer is Iron (III) oxide.
Key Points
- A thermite reaction is a highly exothermic chemical reaction between a metal powder and a metal oxide. The most common and typical version involves Aluminium powder and Iron (III) oxide (Fe2O3).
- In this process, Aluminium acts as a strong reducing agent because it has a higher affinity for oxygen than iron. It reduces the Iron (III) oxide to produce molten iron and Aluminium oxide (Al2O3).
- The reaction is represented by the chemical equation: Fe2O3 + 2Al → Al2O3 + 2Fe + Heat. The heat generated is so intense that the iron produced is in a liquid (molten) state.
- Because of the production of molten iron, this reaction is extensively used for welding broken railway tracks and heavy machinery parts on-site where traditional welding is difficult.
- While other metal oxides like Copper oxide or Chromium oxide can technically undergo similar reactions with aluminium, Iron (III) oxide is the standard "thermite" component used in industrial and civil engineering applications. Hence, the correct answer is Iron (III) oxide.
Additional Information
- History and Discovery: The thermite process was discovered and patented by the German chemist Hans Goldschmidt in the year 1893. It is often referred to as the Goldschmidt reaction or the aluminothermic process.
- Temperature: The reaction can reach temperatures of approximately 2500°C (4500°F), which is sufficient to melt almost any metal.
- Ignition: Thermite is stable at room temperature and requires a very high activation energy to start. Typically, a Magnesium ribbon or a mixture of Potassium Permanganate and Glycerin is used as a fuse to provide the initial heat required for ignition.
- Applications:
- Railway Industry: Used for Thermite Welding (or Exothermic Welding) to join rails together, ensuring a smooth surface for trains.
- Military: Used in incendiary weapons and grenades to destroy enemy equipment, as the molten iron can melt through thick armor or engine blocks.
- Metallurgy: Employed in the reduction of ores for metals that are difficult to extract using carbon, such as Chromium and Manganese.
Important Points
- Redox Nature: The thermite reaction is a classic example of a Redox (Reduction-Oxidation) reaction and a displacement reaction, where a more reactive metal (Aluminium) displaces a less reactive metal (Iron) from its oxide.
- Reactivity Series: The success of the reaction depends on Aluminium being positioned higher than Iron in the reactivity series of metals.
- Safety: Due to the extreme temperatures and the fact that it is nearly impossible to extinguish once started (as it carries its own supply of oxygen within the metal oxide), it poses significant fire hazards and requires specialized safety protocols.
- States of Matter: The reactants are usually in powdered form to increase the surface area, ensuring a faster and more consistent reaction rate upon ignition.