Hardening of lime under water is due to:
- AOption (a)
Alumina
- BOption (b)
Iron oxide
- COption (c)
Calcium oxide
- DOption (d)
None of these
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Correct answer
Alumina
Why this answer is correct
Explanation:
Hardening of Lime under Water:
- Hydraulic lime consists of calcium oxide, magnesium oxide, calcium silicates, and aluminum silicates.
- On hydration, it forms hydroxides of calcium and magnesium.
- When sand is added to lime for the preparation of mortars, complicated chemical reactions take place.
- The chief reaction is the decomposition of complex aluminum-calcium silicate into hydrated calcium silicate and hydrated calcium aluminates.
- Also calcium hydrate is formed due to the hydration of free lime. To some extent, calcium oxide remains unslaked.
- All these reactions take place in the presence of water.
- Calcium silicates and calcium aluminates crystallize and form a hard substance that has great strength.
- The calcium hydrate formed is highly soluble in water, rises to the surface in the form of a solution, gets the free supply of carbon dioxide, and hardens in the same way as fat lime.
- It crystallizes to form calcium carbonate. Thus the setting of hydraulic lime depends upon water because reactions take place only when water is added.
- It is due to this reason that hydraulic lime is most suitable for use in structures underwater.
- Hardening of lime does not depend on air and therefore, should not be slaked immediately after burning. Water should be added just before use.