When \( \text{OH}^- \) ions are added to an acidic solution, the pH:
- AOption (a)
increases
- BOption (b)
decreases
- COption (c)
becomes zero
- DOption (d)
stays the same
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Correct answer
increases
Why this answer is correct
The correct answer is increases.
Key Points
- In chemistry, the pH level of a solution is a measure of the molar concentration of hydrogen ions (H+) in the solution and as such is a measure of the acidity or basicity of the solution.
- When hydroxide ions (OH-) are added to an acidic solution, they react with the existing hydrogen ions (H+) to form water molecules (H2O). This chemical process is known as neutralization.
- The concentration of hydrogen ions (H+) decreases as they are consumed by the OH- ions. Since the pH scale is calculated as the negative logarithm of the H+ ion concentration (pH = -log[H+]), a reduction in H+ ions mathematically leads to a higher pH value. Hence, the statement that the pH increases is correct.
- An acidic solution typically has a pH value ranging from 0 to 6.9. As more OH- ions are introduced, the solution moves closer to pH 7.0, which is the neutral point on the scale.
- If the addition of OH- ions continues beyond the point of neutralization, the solution will eventually become basic (alkaline), resulting in a pH value greater than 7. Hence, the correct answer is increases.
Additional Information
- The pH Scale:
- The pH scale was introduced by the Danish biochemist S.P.L. Sorensen in the year 1909. It is used to express the acidity or alkalinity of a solution on a scale of 0 to 14.
- A pH of 7 represents a neutral solution, such as pure water at 25 degrees Celsius.
- Solutions with a pH less than 7 are considered acidic (e.g., gastric juice, lemon juice, and vinegar), while those with a pH greater than 7 are basic or alkaline (e.g., baking soda, milk of magnesia, and ammonia).
- Mathematical Relationship:
- The relationship between pH and pOH is defined by the equation pH + pOH = 14 at a temperature of 25 degrees Celsius.
- The ionic product of water (Kw) is a constant value of 1.0 x 10^-14 at standard temperature. This equilibrium ensures that as OH- concentration rises, the H+ concentration must fall proportionally.
- Logarithmic Nature:
- The pH scale is logarithmic, meaning each whole pH value below 7 is ten times more acidic than the next higher value. For example, a solution with pH 3 is 10 times more acidic than a solution with pH 4 and 100 times more acidic than a solution with pH 5.
Important Points
- Indicators and Measurement:
- The pH of a solution can be measured using litmus paper, universal indicators, or electronic pH meters. Blue litmus paper turns red under acidic conditions, while red litmus paper turns blue under basic conditions.
- Phenolphthalein is a common indicator that remains colorless in acidic solutions but turns pink when the solution becomes basic (around pH 8.2 to 10).
- Common pH Values:
- The pH of human blood is slightly basic, typically maintained within a narrow range of 7.35 to 7.45 for healthy physiological functioning.
- Acid rain usually has a pH value of less than 5.6, which can cause significant damage to aquatic ecosystems and limestone structures.
- Sodium Hydroxide (NaOH), a strong base, can have a pH as high as 14, whereas Hydrochloric Acid (HCl), a strong acid, can have a pH as low as 0.