Which property most definitively distinguishes a suspension from a colloid?
- AOption (a)
Homogeneity of the mixture
- BOption (b)
Absence of light scattering under illumination
- COption (c)
Settling of particulates under gravitational force
- DOption (d)
Formation of covalent solute-solvent bonds
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Correct answer
Settling of particulates under gravitational force
Why this answer is correct
The correct answer is Settling of particulates under gravitational force.
Key Points
- A suspension is a heterogeneous mixture in which the solute-like particles settle out of the solvent-like phase some time after their introduction.
- The most definitive distinction is that the particles in a suspension will eventually settle at the bottom of the container due to gravitational force (sedimentation) if left undisturbed. In contrast, colloidal particles are small enough that Brownian motion counteracts gravity, keeping them suspended indefinitely. Hence, statement 3 is correct.
- Both suspensions and colloids are technically heterogeneous mixtures. While a colloid might appear homogeneous to the naked eye, it consists of distinct phases at the microscopic level. Therefore, homogeneity does not definitively distinguish them. Hence, statement 1 is incorrect.
- The Tyndall effect, or the scattering of light by particles, is a property shared by both colloids and suspensions (though very dense suspensions might simply block light). Since both can scatter light, the absence of scattering is not a distinguishing feature of a suspension. Hence, statement 2 is incorrect.
- The formation of covalent solute-solvent bonds describes a chemical reaction rather than a physical mixture. Both suspensions and colloids are physical mixtures where components are held by physical interactions, not covalent bonds. Hence, statement 4 is incorrect.
Additional Information
- Particle Size:
- In a true solution, the particle size is less than 1 nm.
- In a colloid, the particle size ranges between 1 nm and 1000 nm.
- In a suspension, the particle size is generally greater than 1000 nm (or 1 micrometer), making them visible to the naked eye.
- Filtration:
- Particles of a suspension are large enough to be trapped by ordinary filter paper.
- Colloidal particles pass through standard filter paper but can be separated using ultrafilters or semi-permeable membranes.
- Stability:
- A suspension is considered unstable because its phases separate over time.
- A colloid is relatively stable; the particles do not settle down even when left undisturbed for a long period.
- Examples:
- Common examples of suspensions include muddy water, a mixture of chalk and water, or flour in water.
- Common examples of colloids include milk, fog, blood, and mayonnaise.
Important Points
- Brownian Motion: This is the random, zigzag motion of colloidal particles resulting from collisions with molecules of the dispersion medium. This motion is a key reason why colloids do not settle under gravity.
- Tyndall Effect: Named after John Tyndall, this effect allows us to see the path of a light beam as it passes through a colloid or suspension. It is a widely used test in laboratories to differentiate a true solution from a colloid.
- Centrifugation: While colloidal particles do not settle under normal gravitational force, they can be forced to settle using a centrifuge, which applies a much higher force. This is how cream is separated from milk.
- Classification: Colloids are classified based on the state of the dispersed phase and the dispersion medium into categories such as aerosols, foams, emulsions, sols, and gels.