Formula unit mass is defined as:
- AOption (a)
the molecular mass of a compound
- BOption (b)
the atomic mass of the lightest element
- COption (c)
the sum of atomic masses of all atoms in a formula unit of an ionic compound
- DOption (d)
the mass of one molecule
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Correct answer
the sum of atomic masses of all atoms in a formula unit of an ionic compound
Why this answer is correct
The correct answer is the sum of atomic masses of all atoms in a formula unit of an ionic compound.
Key Points
- The formula unit mass of a substance is the sum of the atomic masses of all atoms in a formula unit of a compound.
- This term is specifically used for substances whose constituent particles are ions rather than discrete molecules. Ionic compounds like Sodium Chloride (NaCl) do not exist as simple individual molecules but as crystalline lattices. Hence, statement 3 is correct.
- The calculation of formula unit mass is identical to the calculation of molecular mass; the only difference is the use of the term "formula unit" for ionic substances.
- The atomic mass of each element is multiplied by the number of atoms of that element present in the chemical formula, and then the results are summed.
- The unit used to express formula unit mass is the unified atomic mass unit, denoted by 'u'.
Additional Information
- Molecular Mass:
- It is the sum of the atomic masses of all the atoms in a molecule of a substance.
- It is used for covalent compounds like Water (H2O) or Methane (CH4), where atoms are bonded together in discrete units.
- For example, the molecular mass of H2O is calculated as (2 × 1.0 u) + (1 × 16.0 u) = 18.0 u.
- Atomic Mass:
- The atomic mass is the mass of a single atom of a chemical element, expressed in atomic mass units (u).
- It is approximately equivalent to the number of protons and neutrons in the nucleus.
- The standard reference for atomic mass is Carbon-12, where one atomic mass unit is defined as exactly 1/12th the mass of one atom of carbon-12.
- Calculation Example (Ionic Compound):
- To calculate the formula unit mass of Calcium Chloride (CaCl2):
- Atomic mass of Calcium (Ca) = 40 u.
- Atomic mass of Chlorine (Cl) = 35.5 u.
- Formula unit mass = 40 + (2 × 35.5) = 40 + 71 = 111 u.
Important Points
- Mole Concept: The molar mass of a substance is the mass of one mole (6.022 × 10^23 units) of that substance, usually expressed in grams per mole (g/mol).
- Distinction: While molecular mass refers to the mass of a single molecule, molar mass refers to the mass of a large collection of molecules or formula units.
- Ionic Lattice: In an ionic solid, there is no single "molecule." For instance, in NaCl, each Sodium ion (Na+) is surrounded by six Chloride ions (Cl-) and vice versa. Therefore, we use the simplest ratio (the formula unit) to define its mass.
- Unified Mass (u): In 1961, the IUPAC adopted the unified atomic mass unit to replace the older oxygen-based scale for better scientific precision across chemistry and physics.