Which of the following is an example of addition reaction?
- ((a))
Chlorination of methane
- ((b))
Hydrogenation of ethene
- ((c))
Hydrolysis of acetic acid
- ((d))
Dehydration of alcohol
Show Answer
Hydrogenation of ethene
The correct answer is Hydrogenation of ethene.

Key Points
- An addition reaction is a type of organic reaction where two or more molecules combine to form a single larger molecule, typically occurring in compounds with multiple bonds (double or triple bonds).
- Hydrogenation of ethene involves the addition of Hydrogen (H2) across the double bond of Ethene (C2H4) to form Ethane (C2H6) in the presence of a catalyst such as Nickel (Ni) or Palladium (Pd). Hence, the statement is correct.
- Chlorination of methane is a classic example of a substitution reaction, where a hydrogen atom in the Methane (CH4) molecule is replaced by a Chlorine (Cl) atom. Hence, the statement is incorrect.
- Dehydration of alcohol (e.g., ethanol to ethene) is an elimination reaction, where a molecule of water is removed from the substrate to form an alkene. Hence, the statement is incorrect.
- Hydrolysis of acetic acid (or reaction with water) generally refers to its dissociation into ions or its formation from an ester, but it does not represent a standard addition reaction across a carbon-carbon double bond. Hence, the statement is incorrect.

Additional Information
- Unsaturated Hydrocarbons: Compounds like alkenes and alkynes are classified as unsaturated because they contain double or triple bonds. These bonds serve as active sites for addition reactions.
- Saturated Hydrocarbons: Alkanes like methane and propane are saturated because they contain only single bonds. They typically undergo substitution reactions because there is no space to "add" more atoms without removing existing ones.
- Industrial Application: The hydrogenation process is widely used in the food industry to convert liquid vegetable oils (which are unsaturated) into solid fats (which are saturated), such as Vanaspati ghee.
- Role of Catalysts: Transition metals like Nickel, Platinum (Pt), and Palladium are essential in hydrogenation as they provide a surface for hydrogen gas to adsorb and react with the hydrocarbon, lowering the activation energy of the reaction.

Important Points
- Reaction Mechanism: The addition reaction specifically converts a pi bond into sigma bonds. In the case of ethene, the pi bond between the two carbon atoms breaks to accommodate two new Hydrogen atoms.
- Chlorination Conditions: For substitution to occur in methane, the presence of sunlight or ultraviolet (UV) light is usually required to break the Chlorine-Chlorine bond into free radicals.
- Health Context: While hydrogenation is useful for food stability, the process can sometimes lead to the formation of trans-fats, which are associated with health risks such as heart disease.
- Bromine Water Test: An addition reaction is often used to test for unsaturation. When bromine water is added to an alkene, the reddish-brown color disappears (decolorizes) as the bromine adds to the double bond.





























































