During the process of electrolytic refining of metals, on passing the current through the electrolyte, the impure metal from the _____________ dissolves into the electrolyte.
- AOption (a)
both anode and cathode
- BOption (b)
cathode
- COption (c)
salt bridge
- DOption (d)
anode
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Correct answer
anode
Why this answer is correct
The correct answer is anode.
Key Points
- In the process of electrolytic refining, the impure metal is used as the anode, while a pure metal strip is used as the cathode. The electrolyte is a solution containing a salt of the metal being refined.
- When an electric current is passed through the electrolyte, the impure metal from the anode dissolves into the solution. This is due to the oxidation reaction occurring at the anode.
- The dissolved metal ions travel through the electrolyte and are deposited on the cathode, where they undergo a reduction reaction, forming a layer of pure metal.
- Impurities that are more reactive than the metal remain in the solution, while less reactive impurities settle at the bottom of the electrolytic cell as anode mud.
- This process ensures that the final metal obtained at the cathode is of high purity, often used in industries requiring precise and high-quality materials.
Additional Information
- Electrolytic Refining:
- This technique is commonly used to refine metals such as copper, zinc, aluminum, gold, and silver.
- The process involves oxidation at the anode (loss of electrons) and reduction at the cathode (gain of electrons).
- The electrolyte generally contains a solution of a salt of the metal being refined, such as copper sulfate (CuSO4) for copper refining.
- Anode Mud:
- During electrolytic refining, impurities that do not dissolve in the electrolyte or react remain as residue at the bottom of the cell, termed as anode mud.
- Anode mud may contain valuable metals like gold, silver, and platinum, which are recovered separately.
- Applications:
- Electrolytic refining is essential in producing metals for electrical wiring, where high purity is critical for efficient conductivity.
- It is also used in the jewelry industry to refine precious metals like gold and silver.
- Important Terminologies:
- Oxidation: Loss of electrons; occurs at the anode.
- Reduction: Gain of electrons; occurs at the cathode.
- Electrolyte: A medium that allows the movement of ions, facilitating the electrochemical reactions.
Important Points
- Anode vs. Cathode:
- The anode is the positive electrode where oxidation occurs, and the impure metal dissolves into the electrolyte.
- The cathode is the negative electrode where reduction occurs, and the pure metal is deposited.
- Efficiency:
- The process ensures up to 99.99% purity, making it suitable for industrial applications.
- Environmental Considerations:
- Proper disposal of anode mud and waste electrolyte is crucial to minimize environmental hazards.
