Official Paper

UPPSC LT Grade Assistant Teacher (Science) Official Paper (Held On: 29 Jul, 2018) (Previous Year Paper)

150 questions · 120 minutes · with answers · free

Part 1 (30 questions)

1

Which of the following census years is known as the 'Year of Great Divide' in India? 

  1. ((a))

    1911

  2. ((b))

    1921

  3. ((c))

    1951

  4. ((d))

    1991

Show Answer
Answer: ((b))

1921

The correct answer is 1921.

Key Points

  • The year 1921 is referred to as the 'Year of Great Divide' in India due to a significant demographic shift.
  • It marked the first recorded decline in India's population growth rate, primarily due to high mortality caused by pandemics like the Spanish Flu and famines.
  • Before 1921, India's population growth was largely stagnant or fluctuating due to lack of medical advancements and high death rates.
  • Post-1921, with gradual improvements in healthcare, sanitation, and living conditions, India's population began to steadily grow.
  • The 'Great Divide' signifies the transition from an era of fluctuating population growth to one of consistent and rapid growth.

Additional Information

  • Spanish Flu Pandemic (1918-1920):
  • It was one of the deadliest pandemics in history, claiming millions of lives globally, including a significant impact on India.
  • India was one of the worst-hit countries, with an estimated death toll of over 12-18 million.
  • Pre-1921 Mortality Factors:
  • Lack of medical facilities, frequent famines, and high infant mortality rates contributed to stagnant population growth.
  • Diseases such as plague, cholera, and malaria were widespread and uncontrolled.
  • Post-1921 Demographic Trends:
  • Gradual improvements in healthcare, vaccination programs, and sanitation led to a decline in death rates.
  • India's population began to grow exponentially due to a combination of high birth rates and reduced mortality.
  • Census in India:
  • The first Census of India was conducted in 1872 under British rule, but it was incomplete.
  • Starting from 1881, censuses were conducted every 10 years systematically.
2

SRI method is related to

  1. ((a))

    wheat

  2. ((b))

    cotton

  3. ((c))

    mustard

  4. ((d))

    paddy

Show Answer
Answer: ((d))

paddy

The correct answer is paddy.

Key Points

  • The System of Rice Intensification (SRI) is a method of cultivating paddy (rice) aimed at increasing yield and resource efficiency.
  • SRI involves planting younger seedlings (8-12 days old) with wider spacing to allow better root and canopy growth.
  • This method emphasizes reduced water usage by keeping the soil moist but not continuously flooded, unlike traditional paddy cultivation.
  • SRI promotes the use of organic fertilizers and discourages excessive chemical inputs, making it eco-friendly and sustainable.
  • Farmers using SRI have reported significant increases in yield with reduced costs, especially in water-scarce regions.

Additional Information

  • Key Principles of SRI:
  • Planting single seedlings instead of clumps to reduce competition for nutrients.
  • Wide spacing of plants in a grid pattern enhances sunlight exposure and airflow.
  • Intermittent irrigation (wetting and drying) rather than continuous flooding reduces water wastage.
  • Benefits of SRI:
  • Increased yields (up to 30-50% in some cases) due to better root and plant health.
  • Reduced water usage (by 25-50%) compared to traditional methods.
  • Minimized input costs by encouraging organic inputs and reducing dependency on chemical fertilizers.
  • Environmental Impact: SRI helps in reducing greenhouse gas emissions by limiting the decomposition of organic matter in flooded conditions, which releases methane.
  • Global Adoption: SRI has been successfully adopted in many countries, including India, Indonesia, Vietnam, and Madagascar, benefiting smallholder farmers.
  • Challenges: Adoption of SRI requires skill development and labor-intensive practices, which can be barriers for large-scale farming or regions with limited labor availability.
3

Which of the following pairs is not correctly matched?

Crop         :     Insect-pest

  1. ((a))

    Groundnut : Pod borer

  2. ((b))

    Gram : Pod borer

  3. ((c))

    Paddy : Banka 

  4. ((d))

    Maize : Stem borer 

Show Answer
Answer: ((a))

Groundnut : Pod borer

The correct answer is Groundnut : Pod borer.

Key Points

  • The Pod borer (Helicoverpa armigera) is primarily associated with crops like pulses and cotton, not groundnut.
  • Groundnut crops are more commonly affected by pests like red hairy caterpillar (Amsacta albistriga) and aphids, rather than pod borers.
  • In contrast, pod borers are known pests of gram (chickpea) and other leguminous crops.
  • The other pairs listed in the options, such as gram with pod borer, paddy with banka, and maize with stem borer, are correctly matched based on pest-crop associations.
  • Thus, the pair Groundnut : Pod borer is incorrectly matched in the given options.

Additional Information

  • Pod borer (Helicoverpa armigera):
  • A major pest affecting leguminous crops like chickpea, pigeon pea, and cotton.
  • It damages the pods and seeds, leading to significant yield loss.
  • Stem borer:
  • A common pest for cereals like maize, rice, and sorghum.
  • It bores into the stem, affecting nutrient and water transport in the plant.
  • Banka (Rice gall midge):
  • A pest associated with paddy (rice), causing the formation of silver shoots or gall-like structures.
  • It stunts plant growth and reduces grain yield.
  • Groundnut pests:
  • Common pests include aphids, red hairy caterpillars, and thrips.
  • Effective pest management includes cultural practices, crop rotation, and biological control methods.
  • Integrated Pest Management (IPM):
  • An approach combining biological, cultural, mechanical, and chemical methods to manage pests sustainably.
  • IPM minimizes environmental impact and promotes long-term pest control.
4

The rotation intensity of Maize-Potato-Mung bean is

  1. ((a))

    100%

  2. ((b))

    200%

  3. ((c))

    250%

  4. ((d))

    300%

Show Answer
Answer: ((d))

300%

The correct answer is 300%.

Key Points

  • Crop rotation intensity refers to the number of times crops are planted and harvested on the same piece of land within a year.
  • This specific rotation provides an effective balance of nutrients, improves soil health, and minimizes pest and disease buildup.
  • The Maize-Potato-Mung bean rotation is commonly practiced in regions where conditions support all three crops in a single agricultural calendar year.
  • Cropping intensity is calculated as the ratio of the total cropped area to the total cultivable area, expressed as a percentage. It indicates how intensively the land is being used for crop production over a year.
  • The cropping intensity can be calculated by using the following formula:

Cropping Intensity=(Total Cropped AreaTotal Cultivable Area)×100\text{Cropping Intensity} = \left( \frac{\text{Total Cropped Area}}{\text{Total Cultivable Area}} \right) \times 100

In the case of Maize-Potato-Mung bean:

  • Maize, Potato, and Mung bean are grown sequentially within a single year on the same field.
  • This means the field is being used three times in a year.

So, for a given area of land, the total cropped area over the year would be:

Total Cropped Area=(1 crop of Maize+1 crop of Potato+1 crop of Mung bean)×Total Cultivable Area \text{Total Cropped Area} = (1 \text{ crop of Maize} + 1 \text{ crop of Potato} + 1 \text{ crop of Mung bean}) \times \text{Total Cultivable Area}

Total Cropped Area=3×Total Cultivable Area \text{Total Cropped Area} = 3 \times \text{Total Cultivable Area}

Therefore, the cropping intensity would be

Cropping Intensity=(3×Total Cultivable AreaTotal Cultivable Area)×100\text{Cropping Intensity} = \left( \frac{3 \times \text{Total Cultivable Area}}{\text{Total Cultivable Area}} \right) \times 100

Cropping Intensity = 300%

Additional Information

  • Crop Rotation:
  • It is the practice of growing different types of crops sequentially on the same field to improve soil fertility and health.
  • It helps in breaking pest and disease cycles and optimizing the use of soil nutrients.
  • Maize:
  • A cereal crop known for its high carbohydrate content and suitability for various soil types.
  • Usually sown in the summer (Kharif) season in India.
  • Potato:
  • A tuber crop rich in carbohydrates, typically grown in the winter (Rabi) season in India.
  • It requires well-drained, sandy-loam soil with moderate temperatures.
  • Mung Bean:
  • A legume crop rich in protein, commonly grown in the summer or post-monsoon season.
  • It improves soil fertility by fixing atmospheric nitrogen into the soil.
  • Benefits of Crop Rotation:
  • Enhances soil structure and organic matter content.
  • Reduces reliance on chemical fertilizers and pesticides.
  • Improves overall farm productivity and sustainability.
5

Which of the following pairs is not correctly matched?

 Crop               Variety

  1. ((a))

    Groundnut : Kaushal 

  2. ((b))

    Mustard : Vardan 

  3. ((c))

    Linseed : Chamatkar 

  4. ((d))

    Gram : Udai 

Show Answer
Answer: ((a))

Groundnut : Kaushal 

The correct answer is Groundnut : Kaushal.

Key Points

  • Kaushal is not a recognized or widely known variety of groundnut. It is incorrectly matched in the given list.
  • Recognized varieties of groundnut include TMV-2, JL-24, K-6, and TAG-24, which are commonly cultivated in India.
  • The other crop-variety pairs mentioned, such as Mustard : Vardan, Linseed : Chamatkar, and Gram : Udai, are correctly matched and are widely cultivated varieties.
  • Crop-variety matching is crucial for agricultural development as it ensures the selection of the right seeds for specific soil and climatic conditions.
  • Misidentification of crop varieties can lead to incorrect agricultural practices and lower productivity.

Additional Information

  • Groundnut:
  • Groundnut, also known as peanut, is a major oilseed crop grown in tropical and subtropical regions.
  • It is rich in protein and oil, making it an important part of the agricultural economy.
  • India is one of the largest producers of groundnut globally, with major cultivation in Gujarat, Andhra Pradesh, and Tamil Nadu.
  • Crop Varieties:
  • Crop varieties are developed through selective breeding and genetic improvement to enhance yield, disease resistance, and adaptability.
  • Popular mustard varieties include Pusa Bold, Vardan, and Rohini, which are known for their high oil content and resistance to pests.
  • Linseed varieties like Chamatkar are valued for their high oil and fiber content.
  • Importance of Correctly Matched Crop Varieties:
  • Ensures optimal yield and quality by matching crops with suitable soil types and climatic conditions.
  • Reduces risk of crop failure by using varieties resistant to local pests and diseases.
  • Promotes sustainable agricultural practices and contributes to food security.
  • Agricultural Research in India:
  • Organizations like the Indian Council of Agricultural Research (ICAR) play a key role in developing and disseminating improved crop varieties.
  • State Agricultural Universities and research institutes collaborate to ensure farmers have access to high-quality seeds.
6

Which of the following diseases cannot be cured by antibiotics? 

  1. ((a))

    Tuberculosis

  2. ((b))

    Tetanus

  3. ((c))

    Measles

  4. ((d))

    Cholera

Show Answer
Answer: ((c))

Measles

The correct answer is Measles.

Key Points

  • Measles is a viral disease caused by the Measles morbillivirus, which cannot be treated with antibiotics as they are effective only against bacterial infections.
  • Antibiotics target bacteria by disrupting their cell walls, protein synthesis, or DNA replication, but viruses like measles lack these structures, rendering antibiotics ineffective.
  • The best preventive measure against measles is vaccination, particularly the Measles-Mumps-Rubella (MMR) vaccine, which provides long-term immunity.
  • Management of measles focuses on supportive care, including hydration, antipyretics, and vitamin A supplementation to prevent complications like blindness and pneumonia.

Additional Information

  • Antibiotics vs. Viruses: Antibiotics are ineffective against viruses because viruses replicate inside host cells and lack the cellular machinery targeted by antibiotics.
  • Vaccination: Vaccines are the most effective way to prevent viral diseases. The MMR vaccine is highly effective against measles, with two doses providing around 97% immunity.
  • Complications of Measles: Severe complications include pneumonia, encephalitis, and subacute sclerosing panencephalitis (SSPE), a rare but fatal brain disorder.
  • Global Impact: Despite being preventable, measles remains a significant global health issue, causing over 140,000 deaths annually, primarily in unvaccinated children (WHO, 2022).
  • Other Diseases in the List: Tuberculosis, tetanus, and cholera are bacterial infections and can be treated with appropriate antibiotics, unlike measles.
7

Which of the following pairs is not correctly matched?

  1. ((a))

    Computer : Charles Babbage

  2. ((b))

    Radio : Karl Benz

  3. ((c))

    Barometer : E. Torricelli

  4. ((d))

    Dynamo : Michael Faraday

Show Answer
Answer: ((b))

Radio : Karl Benz

The correct answer is Radio : Karl Benz.

Key Points

  • Charles Babbage is regarded as the "Father of the Computer" for conceptualizing the first mechanical computer known as the Analytical Engine.
  • Radio was invented by Guglielmo Marconi, who successfully demonstrated wireless telegraphy and is often referred to as the "Father of Radio."
  • E. Torricelli invented the barometer in 1643, making significant contributions to the field of atmospheric pressure measurement.
  • Michael Faraday invented the dynamo, a device for converting mechanical energy into electrical energy, laying the foundation for modern electromagnetic technology.

Additional Information

  • Charles Babbage: His Analytical Engine was the precursor to modern computers, integrating concepts such as an arithmetic logic unit and control flow.
  • Guglielmo Marconi: He was awarded the Nobel Prize in Physics in 1909 for his pioneering work in wireless communication.
  • Evangelista Torricelli: An Italian physicist and mathematician, Torricelli's invention of the barometer was a breakthrough in studying atmospheric pressure.
  • Michael Faraday: Known for his discovery of electromagnetic induction, Faraday's work is fundamental to electrical engineering and physics.
  • Karl Benz: He was the inventor of the first automobile powered by an internal combustion engine, but he is not associated with the invention of the radio.
8

The communication satellites are invariably

  1. ((a))

    revolving at their own speed

  2. ((b))

    stationary

  3. ((c))

    geostationary

  4. ((d))

    changing their track and speed

Show Answer
Answer: ((c))

geostationary

The correct answer is geostationary.

Key Points

  • Communication satellites are placed in a geostationary orbit, which means they remain fixed relative to a specific location on Earth's surface.
  • A geostationary orbit is located at an altitude of approximately 35,786 kilometers (22,236 miles) above the equator.
  • These satellites revolve around the Earth at the same rotational speed as the Earth’s rotation, achieving a stationary position relative to the ground.
  • Geostationary satellites are essential for uninterrupted services such as telecommunications, television broadcasting, and weather forecasting.
  • Examples of communication satellites in geostationary orbit include the INSAT series (India) and Intelsat series (global).

Additional Information

  • Geostationary Orbit:
  • It is a type of geosynchronous orbit directly above the Earth’s equator.
  • Satellites in this orbit have an orbital period equal to the Earth’s rotational period (24 hours).
  • Advantages of Geostationary Satellites:
  • Continuous coverage of a specific area on Earth.
  • Ideal for real-time communication services, such as satellite TV and internet.
  • Other Satellite Orbits:
  • Low Earth Orbit (LEO): Used for Earth observation and remote sensing (e.g., the International Space Station).
  • Medium Earth Orbit (MEO): Primarily used for navigation systems like GPS.
  • Geostationary Satellite Launch:
  • These satellites are launched using powerful rockets to reach the required altitude.
  • Once in orbit, their position is maintained using onboard thrusters.
9

For which substance among the following, conductivity increases with temperature?

  1. ((a))

    Copper

  2. ((b))

    Germanium

  3. ((c))

    Silver

  4. ((d))

    Iron

Show Answer
Answer: ((b))

Germanium

The correct answer is Germanium.

Key Points

  • Germanium is a semiconductor material, and its electrical conductivity increases with temperature due to the generation of more charge carriers (electrons and holes).
  • In semiconductors like Germanium, the energy gap between the valence and conduction bands allows more electrons to jump to the conduction band at higher temperatures, enhancing conductivity.
  • Unlike metals, where conductivity decreases with temperature, semiconductors exhibit an inverse relationship because of their unique band structure.
  • Germanium is widely used in electronic devices such as transistors and diodes due to its temperature-dependent conductivity.
  • This property makes Germanium useful in temperature-sensitive applications, including infrared optics and thermistors.

Additional Information

  • Semiconductors:
  • These are materials with a conductivity level between that of conductors and insulators, such as Germanium and Silicon.
  • Their conductivity is highly dependent on temperature and doping (addition of impurities).
  • Temperature Effect on Metals vs Semiconductors:
  • In metals, conductivity decreases with temperature due to increased lattice vibrations causing electron scattering.
  • In semiconductors, conductivity increases with temperature as more electrons gain energy to cross the energy gap into the conduction band.
  • Energy Bands:
  • The valence band contains electrons involved in bonding, while the conduction band contains free electrons that contribute to conductivity.
  • The energy gap between these bands determines the material's electrical properties.
  • Applications of Germanium:
  • Germanium is used in electronics, infrared devices, fiber optics, and detectors due to its excellent semiconductor properties.
  • Its temperature-dependent conductivity also makes it suitable for thermistors and temperature sensors.
  • Other Semiconductors:
  • Silicon is another widely used semiconductor, but it has a higher bandgap compared to Germanium, making it more suitable for high-temperature applications.
10

The area of a regular hexagon of side 232\sqrt{3} cm is

  1. ((a))

    12312\sqrt{3} cm2

  2. ((b))

    18218\sqrt{2} cm2

  3. ((c))

    18 cm2

  4. ((d))

    18318\sqrt{3} cm2

Show Answer
Answer: ((d))

18318\sqrt{3} cm2

Given:

Side of hexagon (a) = 2√3 cm

Formula used:

Area of hexagon = (3√3/2) × a2

Calculation:

Area = (3√3/2) × (2√3)2

⇒ Area = (3√3/2) × (4 × 3)

⇒ Area = (3√3/2) × 12

⇒ Area = 18√3 cm2

∴ The correct answer is option (4).

11

If  2x+2x=3,2x+\frac{2}{x}=3, then the value of x3+1x3+2x^3+\frac{1}{x^3}+2

  1. ((a))

    38\frac{3}{8}

  2. ((b))

    198\frac{19}{8}

  3. ((c))

    218\frac{21}{8}

  4. ((d))

    78\frac{7}{8}

Show Answer
Answer: ((d))

78\frac{7}{8}

Given:

2x + (2/x) = 3

Formula Used:

To find the value of x3 + (1/x3) + 2, we use the following identity:

[x + (1/x)]3 = x3 + (1/x3) + 3[x + (1/x)]

Calculations:

2x + (2/x) = 3

x + (1/x) = 3/2

⇒ Use the identity:

[x + (1/x)]3 = x3 + (1/x3) + 3[x + (1/x)]

⇒ (3/2)3 = x3 + (1/x3) + 3 × (3/2)

⇒ 27/8 = x3 + (1/x3) + 9/2

⇒ x3 + (1/x3) = (27/8) - (9/2)

⇒ x3 + (1/x3) = -9/8

⇒ Add 2 to the result:

x3 + (1/x3) + 2 = (-9/8) + 2

⇒ x3 + (1/x3) + 2 = 7/8

∴ The correct answer is option (4).

12

If one of the roots of the quadratic equation 2x2+px+4=0 is 2, then the other root is

  1. ((a))

    -2

  2. ((b))

    -1

  3. ((c))

    +1

  4. ((d))

    +2

Show Answer
Answer: ((c))

+1

Given:

Quadratic equation: 2x2 + px + 4 = 0

One root (x₁) = 2

Formula used:

If the roots of a quadratic equation are x₁ and x₂, then:

Sum of roots = -b/a

Product of roots = c/a

Calculations:

Given that one root is x₁ = 2, let the other root be x₂.

Using the formula for product of roots:

⇒ x₁ × x₂ = c/a

⇒ 2 × x₂ = 4/2

⇒ x₂ = 2 / 2

⇒ x₂ = 1

∴ The other root is 1, and the correct answer is option (3).

13

In which State was the military exercise 'Vijay Prahar' held in May 2018?

  1. ((a))

    Maharashtra

  2. ((b))

    Gujarat

  3. ((c))

    Rajasthan

  4. ((d))

    Madhya Pradesh

Show Answer
Answer: ((c))

Rajasthan

The correct answer is Rajasthan.

Key Points

  • The military exercise 'Vijay Prahar' was conducted by the Indian Army in May 2018 in Rajasthan, specifically in the Mahajan Field Firing Range.
  • This exercise involved over 25,000 troops of the South Western Command, showcasing advanced combat strategies and readiness.
  • 'Vijay Prahar' focused on testing integrated firepower and maneuverability in a joint operational scenario involving infantry, artillery, armored units, and air support.
  • The exercise aimed to validate offensive strategies to ensure preparedness for future conflicts.
  • It also emphasized the use of modern warfare techniques and technologies such as precision targeting and network-centric operations.

Additional Information

  • South Western Command:
  • One of the seven operational commands of the Indian Army, headquartered in Jaipur, Rajasthan.
  • Responsible for securing India's western borders and conducting strategic military exercises.
  • Military Exercises:
  • India conducts various military exercises, both domestic and international, to enhance combat readiness and foster cooperation with other nations.
  • Examples include 'Operation Gagan Strike,' 'Yudh Abhyas,' and 'Indra' among others.
  • Precision Targeting:
  • A modern warfare technique that uses advanced technologies like drones, satellite imagery, and precision-guided munitions.
  • Helps in minimizing collateral damage and increasing operational efficiency.
  • Network-Centric Operations:
  • A military strategy that leverages information technology to link forces, enabling real-time data sharing and enhanced decision-making.
  • It plays a crucial role in modern warfare for achieving faster and more coordinated responses.
14

Who has won the Women Singles Title of Badminton in Commonwealth Games, 2018?

  1. ((a))

    Saina Nehwal

  2. ((b))

    P. V. Sindhu

  3. ((c))

    K. Gilmour

  4. ((d))

    Michelle Li

Show Answer
Answer: ((a))

Saina Nehwal

The correct answer is Saina Nehwal.

Key Points

  • Saina Nehwal won the Women Singles Title in Badminton at the Commonwealth Games 2018 held in Gold Coast, Australia.
  • She defeated fellow Indian shuttler P. V. Sindhu in the finals with a score of 21-18, 23-21.
  • It was a historic moment as it marked an all-Indian final in the Women’s Singles event of Badminton at the Commonwealth Games.
  • This victory added to Saina Nehwal's illustrious career, making her one of the most celebrated badminton players in India.
  • Saina had previously won the same title at the 2010 Commonwealth Games in New Delhi, making her a two-time Commonwealth Games gold medalist in this category.

Additional Information

  • Commonwealth Games 2018:
  • The 2018 Commonwealth Games were held in Gold Coast, Australia, from April 4 to April 15, 2018.
  • India secured an impressive tally of 66 medals, including 26 gold, 20 silver, and 20 bronze, finishing 3rd in the overall medal rankings.
  • Badminton contributed significantly to India’s medal count, with players like Saina Nehwal, P. V. Sindhu, and Kidambi Srikanth excelling.
  • Badminton in Commonwealth Games:
  • Badminton has been a part of the Commonwealth Games since 1966.
  • India has consistently been one of the top-performing nations in badminton at the Commonwealth Games.
  • Saina Nehwal's Career Highlights:
  • She is the first Indian shuttler to win an Olympic medal (bronze at the London 2012 Olympics).
  • She became the first Indian woman to achieve the World No. 1 ranking in badminton in 2015.
  • Saina has won numerous BWF titles, including the prestigious All England Open runner-up position in 2015.
  • Women's Singles Final (2018 CWG):
  • The final match between Saina Nehwal and P. V. Sindhu was closely contested, showcasing the high level of talent in Indian badminton.
  • Saina's experience and aggressive gameplay were key factors in her victory over Sindhu.
15

In the World Press Freedom Index, 2018, India is placed at

  1. ((a))

    135th

  2. ((b))

    136th

  3. ((c))

    138th

  4. ((d))

    137th

Show Answer
Answer: ((c))

138th

The correct answer is 138th

  • India’s rank in the 2018 World Press Freedom Index 138th.

Key Points

  • The Index is compiled and published by Reporters without borders.
  • Reporters without borders is a Paris based non-profit organisation.
  • India ranked 142nd in the 2020 World Press Freedom Index
  • Around 180 countries were ranked in the index.
  • The World Press Freedom Index 2018 was topped by Norway followed by Finland, Sweden, Netherlands and Denmark.

Additional Information

  • According to the 2020 World Press Freedom Index, Pakistan ranked 145 dropping three places, Bangladesh ranked 151, North Korea was at 180th
16

In which of the following texts, it is stated that those who could not speak Sanskrit language correctly were called 'Mlecchas'?

  1. ((a))

    Shvetashvatara Upanishad

  2. ((b))

    Gopaths Brahmana

  3. ((c))

    Brihadaranyaka Upanishad

  4. ((d))

    Shatapatha Brahmana

Show Answer
Answer: ((d))

Shatapatha Brahmana

The correct answer is Shatapatha Brahmana.

Key Points

  • The term 'Mleccha' was used in ancient Indian texts to describe people who could not speak Sanskrit properly or adhered to non-Vedic practices.
  • The Shatapatha Brahmana, a prose text associated with the Shukla Yajurveda, provides references to the term 'Mleccha' in the context of linguistic and cultural distinctions.
  • The Shatapatha Brahmana categorizes those outside the Vedic cultural framework, including those with different linguistic practices, as 'Mlecchas.'
  • This text highlights the importance of Sanskrit as the language of Vedic rituals and knowledge, often contrasting it with non-Sanskrit speakers.
  • The term 'Mleccha' was not necessarily derogatory but was used to mark linguistic and cultural differences.

Additional Information

  • Shatapatha Brahmana:
  • One of the most significant Brahmana texts associated with the Shukla Yajurveda.
  • It provides detailed explanations of Vedic rituals, ceremonies, and their symbolic meanings.
  • The text is divided into several chapters (Adhyayas) and sections (Kandas).
  • Mleccha:
  • A term used in ancient India to denote people outside the Vedic cultural sphere.
  • It was often associated with non-Sanskrit speakers or those who did not follow Vedic practices.
  • Sanskrit Language:
  • Considered the sacred language of the Vedas and Vedic rituals.
  • Proficiency in Sanskrit was seen as a marker of adherence to Vedic traditions.
  • Vedic Literature:
  • Comprises four Vedas (Rigveda, Yajurveda, Samaveda, Atharvaveda), Brahmanas, Aranyakas, and Upanishads.
  • Brahmanas like the Shatapatha Brahmana provide explanations and instructions for Vedic rituals.
  • Cultural Significance:
  • The distinction between 'Arya' (followers of Vedic culture) and 'Mleccha' reflects the cultural and linguistic diversity of ancient India.
  • These categorizations were used to understand and organize the complex social fabric of the time.
17

Match List-I with List-II and select the correct answer using the codes given below the Lists:

List-I (King)List-II (Spouse)
A. Chandragupta I1. Dutta Devi
B. Samudragupta2. Kuberanaga
C. Chandragupta II3. Kumara Devi
D. Kumaragupta I4. Ananta Devi

Codes:

  1. ((a))

    A-2, B-3, C-4, D-1

  2. ((b))

    A-3, B-2, C-4, D-1

  3. ((c))

    A-3, B-1, C-2, D-4

  4. ((d))

    A-4, B-3, C-1, D-2

Show Answer
Answer: ((c))

A-3, B-1, C-2, D-4

The correct answer is A-3, B-1, C-2, D-4.

Key Points

  • Chandragupta I was married to Kumara Devi, a princess of the Lichchhavi dynasty, which helped establish the Gupta Empire.
  • Samudragupta was married to Dutta Devi, who is mentioned in inscriptions as his queen.
  • Chandragupta II was married to Kuberanaga, a Naga princess, which strengthened alliances and expanded the empire.
  • Kumaragupta I was married to Ananta Devi, as per historical records and inscriptions from the Gupta period.

Additional Information

  • Gupta Empire: The Gupta dynasty is considered one of the golden ages of Indian history, marked by advancements in art, science, and culture.
  • Samudragupta: Known as the "Napoleon of India," Samudragupta expanded the empire significantly and was an accomplished poet and musician.
  • Chandragupta I's marriage: His marriage to Kumara Devi of the Lichchhavi dynasty played a crucial role in the Gupta Empire's rise to power.
  • Gupta inscriptions: Many details about Gupta rulers and their spouses are derived from inscriptions, such as the Allahabad Pillar Inscription.
  • Political alliances: Marriages in the Gupta era were often used to strengthen political alliances and consolidate power within and outside the empire.
18

With reference to the book Arthashastra, which of the following statements is/are correct?

  1. It is the oldest masterpiece on Indian State Policy.
  2. There is no description of Mauryan empire and administration in this book. Select the correct answer using the codes given below.

Codes:

  1. ((a))

    1 only

  2. ((b))

    2 only

  3. ((c))

    Both 1 and 2

  4. ((d))

    Neither 1 nor 2

Show Answer
Answer: ((a))

1 only

The correct answer is 1 only.

Key Points

  • The Arthashastra, authored by Kautilya (Chanakya), is considered the oldest known treatise on Indian State Policy, providing insights into governance, administration, and economics.
  • It was composed during the Mauryan period, around the 3rd century BCE, and is regarded as a masterpiece in ancient political and economic thought.
  • The book extensively describes the Mauryan empire's administrative structure, including the duties of the king, ministers, and other officials, as well as strategies for internal and external security.
  • Statement 2 is incorrect as the Arthashastra does provide a detailed description of the Mauryan empire and its administration, which aligns closely with historical accounts of the period.
  • Thus, only statement 1 is correct, making the correct answer 1 only.

Additional Information

  • Kautilya (Chanakya): A key figure in Indian history who served as an advisor and prime minister to Chandragupta Maurya. His ideas laid the foundation for the Mauryan Empire's administration.
  • Structure of Arthashastra: The book is divided into 15 sections (adhikaranas) and covers topics such as statecraft, military strategy, economic policy, and social welfare.
  • Core Concepts: The Arthashastra emphasizes concepts like dharma (moral duty), danda (punishment or enforcement), and niti (policy or strategy) as the pillars of governance.
  • Comparison with Other Texts: Unlike religious texts like the Vedas or epics like the Mahabharata, the Arthashastra is a secular and pragmatic guide to governance and administration.
  • Rediscovery: The text was lost for centuries and was rediscovered in 1905 by R. Shamasastry, who translated and published it, bringing it back to prominence in modern times.
19

Who among the following addressed Delhi as one of the greatest cities in the world?

  1. ((a))

    Ibn Batuta

  2. ((b))

    Alberuni

  3. ((c))

    Farishta

  4. ((d))

    Abul Fazl

Show Answer
Answer: ((a))

Ibn Batuta

The correct answer is Ibn Batuta.

Key Points

  • Ibn Batuta, a Moroccan traveler and scholar, visited India during the reign of Muhammad bin Tughlaq (14th century).
  • He served as the Qadi (judge) in the court of Muhammad bin Tughlaq and documented his travels in his work, "Rihla" (The Journey).
  • In his writings, Ibn Batuta described Delhi as one of the greatest and most magnificent cities of the world during that period.
  • He marveled at the city’s architectural brilliance, bustling markets, and the grandeur of the Sultan’s court.
  • Ibn Batuta's account remains a valuable source of information about the socio-economic and cultural life of medieval India.

Additional Information

  • Rihla (The Journey): This is the travelogue of Ibn Batuta, documenting his travels across the Islamic world, including North Africa, the Middle East, India, and China.
  • Delhi under Muhammad bin Tughlaq: The city was an important cultural and political hub during the Tughlaq Dynasty, known for its ambitious projects and administrative reforms.
  • Medieval Travelers: Along with Ibn Batuta, other notable travelers to India include Marco Polo, Al-Biruni, and Niccolò de' Conti, who documented various aspects of Indian life.
  • Qadi Role: A Qadi is a judge ruling in accordance with Islamic law (Sharia). Ibn Batuta’s appointment as Qadi signifies his deep understanding of Islamic jurisprudence.
  • Architectural Brilliance of Delhi: During the medieval period, Delhi was adorned with iconic structures like the Qutub Minar, Alai Darwaza, and tombs, showcasing Indo-Islamic architecture.
20

Who is known as the Father of India's Local Self-Government?

  1. ((a))

    Lord Lytton

  2. ((b))

    Lord Ripon

  3. ((c))

    Lord Curzon

  4. ((d))

    Lord Dalhousie

Show Answer
Answer: ((b))

Lord Ripon

The correct answer is Lord Ripon.

Key Points

  • Lord Ripon is known as the Father of Local Self-Government in India due to his significant reforms in the local governance system.
  • In 1882, Lord Ripon introduced the Local Self-Government Resolution, which laid the foundation for democratic decentralization in India.
  • His reforms aimed at empowering local bodies like municipalities and district boards, making them responsible for public services such as education, health, and sanitation.
  • He emphasized the importance of local participation in governance and entrusted local bodies with financial and administrative autonomy.
  • The resolution is considered a landmark in Indian administrative history, as it promoted the idea of grassroots-level governance.

Additional Information

  • Lord Ripon's Governance:
  • He served as the Viceroy of India from 1880 to 1884 under Queen Victoria's reign.
  • He is also known for repealing the Vernacular Press Act, which was seen as oppressive by Indians.
  • Local Self-Government:
  • It refers to the administration of local areas by locally elected representatives, ensuring decentralization of power.
  • This concept is crucial for grassroots democracy and promoting citizen participation in governance.
  • Historical Context:
  • Before Lord Ripon, local governance was largely controlled by colonial officials, with minimal participation from Indians.
  • Ripon's reforms were a step towards self-rule and inspired future movements for independence.
  • Impact of Ripon's Reforms:
  • The resolution laid the foundation for the current Panchayati Raj system in rural areas and municipal governance in urban areas.
  • It also emphasized the need for financial independence of local bodies, which remains a key aspect of local governance today.
21

At least how many days are required to give the prior notice for the impeachment of the President of India?

  1. ((a))

    7 days

  2. ((b))

    14 days

  3. ((c))

    21 days

  4. ((d))

    30 days

Show Answer
Answer: ((b))

14 days

The correct answer is Option 2 (14 days).

Key Points

  • The impeachment process of the President of India requires a prior notice of at least 14 days.
  • The notice must be signed by one-fourth of the total members of the house initiating the motion.
  • The impeachment motion is based on the grounds of violation of the Constitution.
  • After the notice is given, the motion must be supported by a two-thirds majority of the total membership of both houses of Parliament.
  • The process for impeachment is detailed under Article 61 of the Indian Constitution.

Additional Information

  • Impeachment: The President of India can be removed from office through impeachment for the violation of the Constitution.
  • Article 61: This article outlines the procedure for impeachment, which includes investigation and voting by Parliament.
  • Grounds for Impeachment: Violation of the Constitution is the only explicit ground for impeachment mentioned in the Indian Constitution.
  • Two-thirds Majority: The motion for impeachment must be passed by a two-thirds majority of the total membership of each house of Parliament.
  • Role of Judiciary: The charges against the President are investigated by a committee formed for this purpose before the voting process in Parliament takes place.
22

Who administers the oath of office and secrecy to the Governor of a State in India?

  1. ((a))

    The President of India

  2. ((b))

    The Vice President of India

  3. ((c))

    The Chief Justice of the High Court of the State

  4. ((d))

    The Speaker of the Legislative Assembly of the State

Show Answer
Answer: ((c))

The Chief Justice of the High Court of the State

The correct answer is The Chief Justice of the High Court of the State.

Key Points

  • The Governor of a State in India takes the oath of office and secrecy administered by the Chief Justice of the High Court of the State.
  • The oath is in accordance with the provisions of Article 159 of the Indian Constitution.
  • The oath includes allegiance to the Constitution of India, upholding sovereignty and integrity, and performing duties faithfully.
  • If the Chief Justice of the High Court is unavailable, the senior-most judge of the High Court administers the oath.
  • The process ensures the Governor's constitutional role and accountability as the nominal head of the state.

Additional Information

  • Article 159 of the Indian Constitution: It specifies the oath or affirmation taken by the Governor while entering office.
  • Governor's Role: The Governor serves as the constitutional head of a state and exercises powers as per the Constitution.
  • Appointment of Governor: The Governor is appointed by the President of India under Article 155.
  • Tenure: The Governor holds office for a term of five years but can be removed earlier by the President or resign voluntarily.
  • High Court Structure: Each state has a High Court, and its Chief Justice is the senior-most judicial authority in the state.
23

Which part of our Constitution envisages a three-tier system of Panchayati Raj?

  1. ((a))

    Part IX

  2. ((b))

    Part X

  3. ((c))

    Part XI

  4. ((d))

    Part XII

Show Answer
Answer: ((a))

Part IX

The correct answer is Part IX.

Key Points

  • Part IX of the Indian Constitution is titled "The Panchayats" and provides for a three-tier system of Panchayati Raj for rural self-governance.
  • It was added to the Constitution through the 73rd Constitutional Amendment Act, 1992, which came into effect on April 24, 1993.
  • The three tiers include Gram Panchayat (village level), Panchayat Samiti (block level), and Zila Parishad (district level).
  • The Panchayati Raj system is aimed at decentralization of power to ensure greater participation of people in governance at the grassroots level.
  • Articles 243 to 243-O under Part IX deal with the structure, powers, and functioning of Panchayati Raj institutions (PRIs).

Additional Information

  • 73rd Constitutional Amendment Act, 1992: This amendment provided a constitutional status to Panchayati Raj institutions and aimed at strengthening local self-governance in rural areas.
  • Eleventh Schedule: This schedule of the Constitution contains 29 subjects that are to be devolved to Panchayati Raj institutions, such as agriculture, rural housing, health, and education.
  • Gram Sabha: It is a body consisting of persons registered in the electoral rolls of a village within the area of a Gram Panchayat. It acts as the foundation of the Panchayati Raj system.
  • State Election Commission: The 73rd Amendment mandates the establishment of a State Election Commission to conduct free and fair elections to Panchayati Raj institutions.
  • Reservation of Seats: The Act provides for the reservation of seats for Scheduled Castes (SCs), Scheduled Tribes (STs), and women (not less than one-third of the total seats) in every Panchayat.
24

Which of the following States has no oil refinery?

  1. ((a))

    Gujarat

  2. ((b))

    Kerala

  3. ((c))

    Chhattisgarh

  4. ((d))

    West Bengal

Show Answer
Answer: ((c))

Chhattisgarh

The correct answer is Chhattisgarh.

Key Points

  • Chhattisgarh does not have any operational oil refinery as of now, while states like Gujarat, Kerala, and West Bengal have established refineries.
  • Gujarat hosts major refineries like the Reliance Jamnagar Refinery, which is the largest refinery in the world.
  • Kerala has the Kochi Refinery, a major petroleum refinery in southern India.
  • West Bengal has the Haldia Refinery, which is a key facility under the Indian Oil Corporation.

Additional Information

  • Oil Refinery: An industrial facility that processes crude oil into usable petroleum products like gasoline, diesel, jet fuel, and other petrochemicals.
  • Major Oil Refining States in India: States like Gujarat, Maharashtra, Tamil Nadu, and Assam are home to significant refinery operations.
  • Jamnagar Refinery: Located in Gujarat, it is the largest oil refinery complex in the world, operated by Reliance Industries.
  • Strategic Importance: Oil refineries are critical for energy security and economic growth as they cater to domestic and industrial fuel needs.
  • Indian Oil Corporation (IOC): A leading public sector company in India that operates many refineries across the country, including the Haldia Refinery in West Bengal.
25

Which of the following rivers does not flow in Australia?

  1. ((a))

    Hunter River

  2. ((b))

    Flinders River

  3. ((c))

    Orange River

  4. ((d))

    Gilbert River

Show Answer
Answer: ((c))

Orange River

The correct answer is Orange River.

Key Points

  • The Orange River is located in southern Africa and does not flow in Australia.
  • It is one of the longest rivers in Africa, originating in the Drakensberg Mountains of Lesotho and flowing westward into the Atlantic Ocean.
  • Rivers such as the Hunter River, Flinders River, and Gilbert River are located in Australia, making them incorrect options.
  • The Orange River is vital for water supply and irrigation in the region but is geographically limited to the African continent.
  • This exclusion of the Orange River highlights its distinct location compared to the rivers mentioned in the question.

Additional Information

  • Hunter River: Located in New South Wales, Australia, it is known for its significance in agriculture and coal mining.
  • Flinders River: The longest river in Queensland, Australia, it flows into the Gulf of Carpentaria and is critical for regional ecosystems.
  • Gilbert River: Also located in Queensland, Australia, it contributes to the Gulf Country’s water systems and supports cattle grazing industries.
  • Orange River Basin: Covers regions in South Africa, Namibia, and Botswana, providing water resources for mining, agriculture, and energy production.
  • River Classification: Rivers are classified based on geography, ecosystem roles, and their contribution to human activities such as irrigation, transportation, and energy generation.
26

Which of the following States recorded decrease in its population in 2011 Census?

  1. ((a))

    Kerala

  2. ((b))

    Sikkim

  3. ((c))

    Nagaland

  4. ((d))

    Manipur

Show Answer
Answer: ((c))

Nagaland

The correct answer is Nagaland.

Key Points

  • Nagaland was the only Indian state to record a decrease in its population according to the 2011 Census data.
  • The population of Nagaland declined from 1,988,636 in 2001 to 1,978,502 in 2011, marking a negative growth rate of -0.58%.
  • The decline was attributed to migration, discrepancies in earlier census data, and other socio-economic factors.
  • Population changes in Nagaland raised concerns about the accuracy of enumeration processes in the region.
  • This negative population growth is a unique case among Indian states during the 2011 Census.

Additional Information

  • Census of India:
  • The Census of India is conducted every 10 years and is the most comprehensive source of demographic data in the country.
  • The 2011 Census was the 15th National Census since 1872 and covered all states and union territories.
  • It provides data on population size, density, literacy rate, sex ratio, and other socio-economic indicators.
  • Population Growth Rate:
  • Population growth rate refers to the percentage change in the population over a specific time period.
  • A negative growth rate indicates a decline in the population size during the period.
  • Factors Affecting Population Decline:
  • Migration: Movement of people to other regions for better opportunities can lead to population decline.
  • Errors in census enumeration can also affect population data accuracy.
  • Socio-political factors, such as conflicts, may influence demographic trends.
  • Significance of Census Data:
  • Census data is crucial for policy-making, development planning, and resource allocation.
  • It helps identify trends in population dynamics and socio-economic changes over time.
27

Which of the following is the most effective measure of population control according to Malthus?

  1. ((a))

    War

  2. ((b))

    Disaster

  3. ((c))

    Birth control

  4. ((d))

    Social evils

Show Answer
Answer: ((a))

War

The correct answer is War.

Key Points

  • According to Thomas Malthus, war is one of the key "positive checks" that limits population growth by reducing the population through mortality.
  • Malthus categorized population control measures into two types: preventive checks (e.g., moral restraint, delayed marriage) and positive checks (e.g., famine, disease, war).
  • War was emphasized as a natural and inevitable mechanism to bring population levels back in alignment with the available resources.
  • Malthus argued that without such "positive checks," human population growth would outpace food production, leading to widespread scarcity and suffering.
  • His theory is based on the principle that population grows geometrically while food supply grows arithmetically, creating a gap that needs to be corrected by such checks.

Additional Information

  • Thomas Malthus and his Theory:
  • Thomas Robert Malthus was an 18th-century British economist and demographer.
  • In his famous work, An Essay on the Principle of Population (1798), he proposed that population growth, if unchecked, would lead to resource depletion.
  • He introduced the concepts of "preventive checks" and "positive checks" to manage population growth.
  • Preventive Checks:
  • These are measures to reduce birth rates, such as moral restraint, delayed marriage, and birth control.
  • Malthus supported moral restraint as the most ethical preventive measure.
  • Positive Checks:
  • These are natural and man-made factors that increase death rates, including famine, disease, and war.
  • Malthus believed these checks were necessary to prevent overpopulation and maintain the balance between population and resources.
  • Criticism of Malthusian Theory:
  • Modern economists argue that technological advancements in agriculture and resource management have disproved Malthus's dire predictions of widespread famine and resource scarcity.
  • Critics also highlight that social, economic, and political factors greatly influence population dynamics beyond Malthus's simplistic model.
28

Which of the following is not a biome?

  1. ((a))

    Desert

  2. ((b))

    Grassland

  3. ((c))

    Ecosystem

  4. ((d))

    Tundra

Show Answer
Answer: ((c))

Ecosystem

The correct answer is Ecosystem.

Key Points

  • A biome is a large ecological area on the Earth's surface, classified based on its climate, flora, and fauna. Examples include desert, tundra, and grassland.
  • An ecosystem, on the other hand, refers to a community of living organisms interacting with their physical environment, such as a pond or forest.
  • Ecosystem is not a biome; it is a smaller functional unit within a biome where biotic (living) and abiotic (non-living) components interact.
  • Biomes are broader classifications, encompassing multiple ecosystems. For example, the desert biome includes various ecosystems such as sand dunes, oases, and rocky deserts.

Additional Information

  • Definition of Biome: A biome is characterized by specific climate conditions and distinct types of plants and animals adapted to it. Common examples include forests, grasslands, deserts, and tundras.
  • Definition of Ecosystem: An ecosystem includes all living organisms and their interactions with the non-living environment within a specific location. It can vary in size, from a small pond to a large forest.
  • Difference Between Biome and Ecosystem: Biomes are larger geographical areas with similar climatic conditions, while ecosystems are smaller units within biomes where organisms interact with their environment.
  • Major Biomes: Earth’s major biomes include tropical rainforests, savannas, deserts, grasslands, tundras, and aquatic biomes like freshwater and marine ecosystems.
  • Examples of Ecosystems: Examples include coral reefs, mangroves, wetlands, and urban ecosystems, each functioning uniquely within a biome.
29

Dudhwa National Park is situated in which of the following States?

  1. ((a))

    Assam

  2. ((b))

    Uttarakhand

  3. ((c))

    Rajasthan

  4. ((d))

    Uttar Pradesh

Show Answer
Answer: ((d))

Uttar Pradesh

The correct answer is Uttar Pradesh.

Key Points

  • Dudhwa National Park is located in the Lakhimpur Kheri district of Uttar Pradesh, India.
  • It was established in 1977 and later designated as a tiger reserve in 1987 under Project Tiger.
  • The park spans an area of approximately 490 square kilometers and is part of the Terai ecosystem.
  • Dudhwa is renowned for its population of Bengal tigers, swamp deer (Barasingha), and Indian rhinoceros.
  • The park is also a haven for birdwatchers, with over 400 species of resident and migratory birds recorded.

Additional Information

  • Terai Ecosystem: The park is part of the Terai belt, a marshy grassland ecosystem found in the foothills of the Himalayas, known for its rich biodiversity.
  • Fauna: Key species include the Bengal tiger, Indian rhinoceros, Asian elephant, Barasingha, and Gangetic dolphin (in nearby rivers).
  • Flora: The park consists of dense sal forests, grasslands, and wetlands, providing a diverse habitat for wildlife.
  • Conservation Challenges: The park faces threats such as habitat destruction, human-wildlife conflict, and poaching, prompting ongoing conservation efforts.
  • Tourism: Dudhwa National Park attracts eco-tourists and wildlife enthusiasts, with safaris and guided tours offered to explore its unique biodiversity.
30

According to the Fourth Round of National Family Health Survey, the current TFR (Total Fertility Rate-children per woman) is

  1. ((a))

    2.2

  2. ((b))

    3.2

  3. ((c))

    4.2

  4. ((d))

    4.5

Show Answer
Answer: ((a))

2.2

The correct answer is 2.2.

Key Points

  • The Total Fertility Rate (TFR) in India according to the Fourth Round of the National Family Health Survey (NFHS-4) was reported to be 2.2 children per woman.
  • A TFR of 2.2 indicates that India is moving towards achieving replacement-level fertility (2.1 children per woman).
  • The decline in TFR is attributed to increased awareness of family planning, better access to contraception, and socio-economic improvements.
  • The TFR varies significantly across states, with some states like Kerala and Tamil Nadu having a TFR below 2, while others like Bihar and Uttar Pradesh report higher rates.
  • The reduction in TFR is a critical factor in stabilizing population growth and achieving sustainable development goals (SDGs).

Additional Information

  • Total Fertility Rate (TFR):
  • TFR is the average number of children that would be born to a woman over her lifetime, based on current birth rates.
  • A TFR of 2.1 is considered the replacement level, where the population remains stable without migration.
  • National Family Health Survey (NFHS):
  • NFHS is a large-scale, multi-round survey conducted in a representative sample of households across India.
  • It provides essential data on health, nutrition, fertility, family planning, and mortality.
  • Factors Influencing TFR Decline:
  • Improved access to education, particularly for women.
  • Increased availability and use of contraceptives.
  • Rising urbanization and economic development.
  • Government initiatives promoting family planning and awareness campaigns.
  • Implications of Low TFR:
  • Lower TFR leads to slower population growth, reducing the strain on resources and public services.
  • However, prolonged low TFR can result in an aging population, leading to a higher dependency ratio in the future.

Part 2 (120 questions)

31

Two long current-carrying wires are kept parallel at a distance 2r between them and if currents I and 2I respectively are flowing in these in same direction, the resultant magnetic field B at the mid-point between two wires is

  1. ((a))

    3Iμ02πr3I \frac{\mu_0}{2\pi r}

  2. ((b))

    2Iμ02πr2I \frac{\mu_0}{2\pi r}

  3. ((c))

    Iμ04πrI \frac{\mu_0}{4\pi r}

  4. ((d))

    Iμ02πrI \frac{\mu_0}{2\pi r}

Show Answer
Answer: ((d))

Iμ02πrI \frac{\mu_0}{2\pi r}

Concept Used:

  • The magnetic field due to a long straight current-carrying wire at a distance r is given by: B = (μ0 / 2π) × (I / r)
  • At the midpoint between two wires, the distance from each wire is r.
  • The net magnetic field is the vector sum of the fields produced by both wires.
  • Since the currents flow in the same direction, the magnitude of magnetic fields at the midpoint will subtract using thumb rule.

Here, dot represent the direction of magnetic field into the page and cross represent the direction of magnetic field out of the page

Calculation:

Magnetic field due to the first wire at the midpoint:

B1 = (μ0 / 2π) × (I / r)

Magnetic field due to the second wire at the midpoint:

B2 = (μ0 / 2π) × (2I / r)

Net magnetic field at the midpoint:

Bnet = B1 - B2

⇒ Bnet = [(μ0 / 2π) × (I / r)] - [(μ0 / 2π) × (2I / r)]

∴ Bnet = I × (μ0 / 2πr)

Hence, the correct answer is Option 4: I (μ0 / 2πr).

32

Arrange in decreasing order of power consumption for same light output:

  1. Tubelight
  2. Filament bulb
  3. CFL
  4. LED

Give correct answer from the following.

  1. ((a))

    2, 1, 3, 4

  2. ((b))

    1, 2, 4, 3

  3. ((c))

    1, 2, 3, 4

  4. ((d))

    4, 3, 1, 2

Show Answer
Answer: ((a))

2, 1, 3, 4

Explanation:

The power consumption of different light sources varies based on technology:

Filament Bulb: Highest power consumption as it relies on heating a filament.

Tubelight: Moderate power consumption but higher than CFL and LED.

CFL (Compact Fluorescent Lamp): Lower power consumption compared to Tubelight and Filament Bulb.

LED (Light Emitting Diode): Lowest power consumption with high efficiency.

Order of power consumption (highest to lowest):

⇒ Filament Bulb > Tubelight > CFL > LED

⇒ The correct order matches Option 1: 2, 1, 3, 4

∴ The correct answer is Option 1.

33

A 220 V alternating source is connected across a pure 0-75 H inductor. What is the power loss in it, if the frequency of the source is 50 Hz?

  1. ((a))

    220 W

  2. ((b))

    zero

  3. ((c))

    110 W

  4. ((d))

    55 W

Show Answer
Answer: ((b))

zero

Calculation:

Given:

Voltage, Vrms = 220 V

Inductance, L = 0.75 H

Frequency, f = 50 Hz

The inductive reactance (XL):

XL = 2πfL

⇒ XL = 2 × 3.1416 × 50 × 0.75

⇒ XL = 235.62 Ω

The RMS current (Irms):

Irms = Vrms / XL

⇒ Irms = 220 / 235.62

⇒ Irms ≈ 0.933 A

The power loss:

P = Vrms × Irms × cos(φ)

⇒ P = 220 × 0.933 × cos(90°)

⇒ P = 0 W

∴ The power loss in the inductor is zero.

34

Which one of the following is not correctly matched?

  1. ((a))

    Faraday's law of electromagnetic induction - ×E=Bt\vec{\nabla} \times \vec{E} = - \frac{\partial \vec{B}}{\partial t}

  2. ((b))

    Idea displace current was given by of Maxwell

  3. ((c))

    Lenz's law is a consequence of the law of conservation of Energy

  4. ((d))

    .B\vec{\nabla} . \vec{B} is never - Zero

Show Answer
Answer: ((d))

.B\vec{\nabla} . \vec{B} is never - Zero

Concept:

∇ × E = - ∂B/∂t

Faraday's Law of Electromagnetic Induction: Describes how a time-varying magnetic field induces an electric field. It is mathematically expressed as:

Displacement Current: Introduced by Maxwell to account for the continuity of current in Ampere's circuital law. Displacement current arises in a time-varying electric field.

Lenz's Law: States that the direction of the induced current opposes the change in magnetic flux. It follows from the law of conservation of energy.

Divergence of Magnetic Field (∇ · B): The divergence of a magnetic field is always zero, as there are no magnetic monopoles in nature.

∴ The incorrect statement is Option 4.

35

Which one of the following particles does not obey the Pauli's exclusion principle?

  1. ((a))

    Electrons

  2. ((b))

    Neutrons

  3. ((c))

    Photons

  4. ((d))

    Protons

Show Answer
Answer: ((c))

Photons

Concept Used:

Pauli's Exclusion Principle:

The principle states that no two fermions (particles with half-integer spin) can occupy the same quantum state simultaneously.

Fermions include electrons, neutrons, and protons, which obey this principle.

Photons, on the other hand, are bosons (particles with integer spin) and do not obey Pauli's exclusion principle.

Bosons can occupy the same quantum state without restriction.

Explanation:

Electrons, neutrons, and protons are fermions with half-integer spins (e.g., spin = 1/2).

These particles obey Pauli's exclusion principle.

Photons, being bosons, have an integer spin (e.g., spin = 1).

Since photons are bosons, they do not obey Pauli's exclusion principle and can occupy the same quantum state.

∴ The correct answer is Option 3: Photons.

36

If we take E=12m0v2E = \frac{1}{2} m_0 v^2 and p=m0vp = m_0 v then the phase velocity of the corresponding wave packet is

  1. ((a))

    v2\frac{v}{2}

  2. ((b))

    vv

  3. ((c))

    c2v\frac{c^2}{v}

  4. ((d))

    v2c\frac{v^2}{c}

Show Answer
Answer: ((a))

v2\frac{v}{2}

Concept Used:

  • The phase velocity (vphase) of a wave is defined as the ratio of energy (E) to momentum (p):
  • Formula: vphase = E / p

Calculation:

Using the formula for phase velocity:

vphase = E / p

⇒ vphase = [(1/2) × m0 × v2] / [m0 × v]

⇒ vphase = (1/2) × v

⇒ vphase = v / 2

∴ The phase velocity of the corresponding wave packet is v / 2.

Correct Answer: Option 1

37

The maximum rectification efficiency of a half-wave rectifier is

  1. ((a))

    100%

  2. ((b))

    91%

  3. ((c))

    81.2%

  4. ((d))

     40.6%

Show Answer
Answer: ((d))

 40.6%

Concept:

The efficiency of a rectifier is defined as the ratio of DC output power to input power.

The efficiency of a half-wave rectifier will be:

η = Pdc / Pac

η = (Vdc2 / RL) / (Vrms2 / RL)

Where:

  • VDC = DC or average output voltage
  • RL = Load resistance

For a half-wave rectifier, the output DC voltage or the average voltage is:

VDC = Vm / π

Also, the RMS voltage for a half-wave rectifier is:

Vrms = Vm / 2

Calculation:

η = [(Vm / π)2] / [(Vm / 2)2] = 40.6%

For Half-wave rectifier: Maximum efficiency = 40.6%

Note: For Full-wave rectifier, maximum efficiency = 81.2%

38

A beam of light of frequency v and of intensity 10 lumen falls on a metal surface of work function ϕ\phi. In which of the following conditions, there shall be no emission of electrons?

  1. ((a))

    For v>ϕhv > \frac{\phi}{h}

  2. ((b))

    For v<ϕhv < \frac{\phi}{h}

  3. ((c))

    For vϕhv \ge \frac{\phi}{h}

  4. ((d))

    For v=10ϕhv = \frac{10\phi}{h}

Show Answer
Answer: ((b))

For v<ϕhv < \frac{\phi}{h}

Explanation:

  • According to the photoelectric effect, electrons are emitted from a metal surface when the energy of incident light (photon energy) is greater than or equal to the work function (φ) of the metal.
  • Photon Energy (E): E = h × v
  • Work Function (φ): The minimum energy required to release an electron from the surface of a metal.
  • One photon with frequency 5.16xx10^(15) s^(-1)
  • Condition for emission:
  • If hv ≥ φ, electrons are emitted.
  • If hv < φ, no electrons are emitted.

∴ The correct condition where no electrons are emitted is Option 2: For v < φ / h.

39

234 90Th decays finally to 82 206 Pb How many α\alpha and β\beta particles are emitted in this process?

  1. ((a))

    α=28,β=8\alpha = 28, \beta = 8

  2. ((b))

    α=14,β=14\alpha = 14, \beta = 14

  3. ((c))

    α=7,β=6\alpha = 7, \beta = 6

  4. ((d))

    α=6,β=7\alpha = 6, \beta = 7

Show Answer
Answer: ((c))

α=7,β=6\alpha = 7, \beta = 6

Concept:

Each alpha (α) particle emission reduces the mass number (A) by 4 and the atomic number (Z) by 2 because an alpha particle is a helium nucleus (42He).

Each beta (β) particle emission increases the atomic number (Z) by 1, with no change in the mass number (A).

Calculation:

The total decrease in mass number (A).

Initial A = 234, Final A = 206

⇒ Decrease in A = 234 - 206 = 28

The number of alpha particles emitted.

Each alpha particle reduces A by 4.

⇒ Number of alpha particles = 28 / 4 = 7

The total decrease in atomic number (Z).

Initial Z = 90, Final Z = 82

⇒ Decrease in Z = 90 - 82 = 8

Adjust for beta particle emissions.

Each alpha particle reduces Z by 2. For 7 alpha particles:

⇒ Z reduction due to alpha particles = 7 × 2 = 14

⇒ Number of beta particles = 14 - 8 = 6

∴ The number of alpha particles emitted is 7, and the number of beta particles emitted is 6.

40

The mass of a photon of frequency v is

  1. ((a))

    00

  2. ((b))

    hνc\frac{h\nu}{c}

  3. ((c))

    hν2c2\frac{h\nu}{2c^2}

  4. ((d))

    hνc2\frac{h\nu}{c^2}

Show Answer
Answer: ((a))

00

Concept:

Photon: A quantum of electromagnetic energy that has no rest mass but has momentum.

The energy of a photon is given by: E = hν, where:

h: Planck's constant (6.626 × 10-34 J·s)

ν: Frequency of the photon

∴ The mass of a photon of frequency v is 0, which corresponds to Option 1.

41

. The energy of an atom (or ion) in its ground state is -54-4 eV. It should be

  1. ((a))

    hydrogen

  2. ((b))

    deuterium

  3. ((c))

    He+

  4. ((d))

    L i++

Show Answer
Answer: ((c))

He+

Calculation:

Using E = -13.6 Z2 / n2:

For Hydrogen (Z = 1, n = 1):

⇒ E = -13.6 × (1)2 / (1)2

⇒ E = -13.6 eV

For He+ (Z = 2, n = 1):

⇒ E = -13.6 × (2)2 / (1)2

⇒ E = -13.6 × 4

⇒ E = -54.4 eV

For Li++ (Z = 3, n = 1):

⇒ E = -13.6 × (3)2 / (1)2

⇒ E = -13.6 × 9

⇒ E = -122.4 eV

The energy of -54.4 eV corresponds to He+ (Option 3).

42

Which one of the following is not correctly matched?

  1. ((a))

    P-N junction - Rectifier diode

  2. ((b))

    Zener diode - Production of carrier waves

  3. ((c))

    Transistor - Amplifier

  4. ((d))

    Photodiode - Intensity of light

Show Answer
Answer: ((b))

Zener diode - Production of carrier waves

Explanation:

Incorrect Matching:

Zener Diode – Voltage Regulation

Carrier Wave Production – Oscillator (e.g., LC Oscillator, Crystal Oscillator)

Incorrect Matching: Zener Diode – Production of Carrier Waves

This is incorrect because a Zener diode is not used to produce carrier waves; it is used to regulate voltage across circuits.

43

An X-ray tube is operated at 20000 V; which of the following statements is correct?

  1. 0.2 A wavelength will be absent.
  2. 0.5 A wavelength will be absent.
  1. ((a))

    1 only

  2. ((b))

    2 only

  3. ((c))

    Both 1 and 2

  4. ((d))

    Neither 1 nor 2

Show Answer
Answer: ((d))

Neither 1 nor 2

Calculation:

Using λmin = (hc) / (e × V):

λmin = [(6.626 × 10-34) × (3 × 108)] / [(1.6 × 10-19) × (20000)]

⇒ λmin = (1.9878 × 10-25) / (3.2 × 10-15)

⇒ λmin = 0.621 Å

∴ The correct answer is Option 4.

44

Consider the following Assertion (A) and Reason (R):

Assertion (A):

NOR and NAND gates are universal gates.

Reason (R):

Digital circuits can be made by repetitive use of these.

Which one of the following statements is correct?

  1. ((a))

    Both A and R are true and R is the explanation of A.

  2. ((b))

    Both A and R are true but R is not the correct explanation of A.

  3. ((c))

    A is true but R is false.

  4. ((d))

    A is false but R is true.

Show Answer
Answer: ((a))

Both A and R are true and R is the explanation of A.

Explanation;

Universal Gates:

A logic gate is called a universal gate if it can implement any Boolean function using only that gate (and its combinations).

NOR and NAND gates are universal gates, as they can be used to construct all basic gates (AND, OR, NOT, etc.).

Reason:

Digital circuits are built using logic gates, and since NOR and NAND gates can be combined to form any other gate, it is possible to create entire digital circuits using just these gates repetitively.

From the above:

The Assertion (A) is true because NOR and NAND gates are indeed universal gates.

The Reason (R) is also true because digital circuits can be constructed using repetitive use of these gates.

Correct Answer: Option 1

45

If the wave function of ψ(r,t)\psi (\vec{r}, t) of a particle

is Aexpi(krωt)A \exp { i (\vec{k} \cdot \vec{r} - \omega t) }, then the value of 

22m2ψ(r,t)-\frac{\hbar^2}{2m} \nabla^2 \psi (\vec{r}, t)

  1. ((a))

    P2mψ(r,t)\frac{P}{2m} \psi (\vec{r}, t)

  2. ((b))

    P22mψ(r,t)\frac{P^2}{2m} \psi (\vec{r}, t)

  3. ((c))

    k22mψ(r,t)\frac{\hbar k^2}{2m} \psi (\vec{r}, t)

  4. ((d))

    2k2mψ(r,t)\frac{\hbar^2 k}{2m} \psi (\vec{r}, t)

Show Answer
Answer: ((b))

P22mψ(r,t)\frac{P^2}{2m} \psi (\vec{r}, t)

Calculation:

Given:

ψ(r, t) = A exp{i (k · r - ωt)}

2 ψ(r, t) = -k2 ψ(r, t)

The value of - (ħ2 / 2m) ∇2 ψ(r, t)

⇒ - (ħ2 / 2m) (-k2 ψ(r, t))

⇒ (ħ2 k2 / 2m) ψ(r, t)

as p = ħk

⇒ P22mψ(r,t)\frac{P^2}{2m} \psi (\vec{r}, t)

46

If r=xi^+yj^+zk^\vec{r} = x\hat{i} + y\hat{j} + z\hat{k} , then divr\text{div}\vec{r} is

  1. ((a))

    3

  2. ((b))

    2

  3. ((c))

    1

  4. ((d))

    0

Show Answer
Answer: ((a))

3

Calculation:

Using the formula for divergence:

div(r) = ∂Fx/∂x + ∂Fy/∂y + ∂Fz/∂z

div(r) = ∂x/∂x + ∂y/∂y + ∂z/∂z

div(r) = 1 + 1 + 1

div(r) = 3

∴ The divergence of r is 3, and the correct answer is Option 1.

47

Two water drops of same radii are falling in air with terminal velocity vv . If both drops are collapsed into a big drop, the terminal velocity of new drop shall be

  1. ((a))

    21/3v2^{1/3}v

  2. ((b))

    22/3v2^{2/3}v

  3. ((c))

    12v\frac{1}{2} v

  4. ((d))

    2v2v

Show Answer
Answer: ((b))

22/3v2^{2/3}v

Calculation:

Volume of two smaller drops:

Vsmall = 2 × (4/3) π r3

Volume of the larger drop:

Vlarge = (4/3) π R3

Since the volumes are equal:

2 × (4/3) π r3 = (4/3) π R3

⇒ 2r3 = R3

⇒ R = (2)1/3r

Since terminal velocity v is proportional to radius squared:

 vlarge ∝ R2

vlarge = k × R2

vlarge = k × ((2)1/3r)2

Since vsmall = k × r2:

vlarge = (2)2/3 × vsmall

∴ The terminal velocity of the larger drop is (2)1/3v.

48

If L03L^{3}_{0} is the rest volume of a cube, then volume viewed from a reference frame moving with uniform velocity v in a direction parallel to an edge of the cube is

  1. ((a))

    L03L_0^3

  2. ((b))

    L03(1v2c2)32L_0^3 \left(1-\frac{v^2}{c^2}\right)^ {\frac{3}{2}}

  3. ((c))

    L03(1v2c2)12L_0^3 \left(1-\frac{v^2}{c^2}\right)^{\frac{1}{2}}

  4. ((d))

    L03(1v2c2)3L_0^3 \left(1-\frac{v^2}{c^2}\right)^{3}

Show Answer
Answer: ((c))

L03(1v2c2)12L_0^3 \left(1-\frac{v^2}{c^2}\right)^{\frac{1}{2}}

Calculation:

Given that the reference frame is moving parallel to one edge of the cube:

The length along the direction of motion will contract according to the formula. L = L0 × (1 - v2 / c2)1/2 

 Here, L0 is the rest length and L is the contracted length.

However, the lengths perpendicular to the direction of motion remain unchanged.

Volume of the cube is:

V = Length × Width × Height

In this case:

Length along the direction of motion = L0 × (1 - v2 / c2)1/2

Width and Height remain = L0

⇒ V = L0 × (1 - v2 / c2)1/2 × L0 × L0

⇒ V = L03 × (1 - v2 / c2)1/2

49

A cantilever of uniform cross-section and of length ll  shows a depression δ\delta t the loaded end. The depression at a distance l/2l/2  from the fixed end is

  1. ((a))

    116δ\frac{1}{16} \delta

  2. ((b))

    316δ\frac{3}{16} \delta

  3. ((c))

    548δ\frac{5}{48} \delta

  4. ((d))

    516δ\frac{5}{16} \delta

Show Answer
Answer: ((a))

116δ\frac{1}{16} \delta

Concept Used:

The depression in a cantilever is proportional to the cube of the length of the segment measured from the fixed end.

If the depression at the loaded end is δ, the depression at a distance x from the fixed end can be calculated using the ratio of x3 to l3.

Formula Used: Depression at distance x = δ × (x3 / l3).

Calculation:

Distance from the fixed end = l/2.

Using the formula:

⇒ Depression at l/2 = δ × ((l/2)3 / l3)

Calculating the ratio:

⇒ ((l/2)3 / l3) = (l3 / 8) / l3

⇒ ((l/2)3 / l3) = 1/8

⇒ Depression at l/2 = δ × 1/8

⇒ Depression at l/2 = (1/16) δ

∴ The correct depression at a distance l/2 from the fixed end is (1/16) δ.

50

Consider the following Assertion (A) and Reason (R):

Assertion (A):

The areal velocity remains constant when a particle moves in the influence of a central force.

Reason (R):

The angular momentum of a particle moving under central force is conserved.

Select the correct answer using the codes given below.

  1. ((a))

    Both A and R are true and R is an explanation of A.

  2. ((b))

    oth A and R are true but R is not the explanation of A.

  3. ((c))

    A is true but R is false.

  4. ((d))

    A is false but R is true.

Show Answer
Answer: ((a))

Both A and R are true and R is an explanation of A.

Concept Used:

A central force is a force that acts along the line joining the particle and a fixed point (the center).

Angular Momentum Conservation: If a particle is moving under a central force, its angular momentum is conserved because the torque acting on it is zero (central forces do not create torque).

Areal Velocity: It is the rate at which area is swept out by the radius vector of the particle. Mathematically:

Areal Velocity = (1/2) × r2 × ω where r is the radius vector and ω is the angular velocity.

Since angular momentum (L = m × r2 × ω) is conserved, areal velocity remains constant.

Assertion (A) states that the areal velocity is constant under a central force. This is true based on the conservation of angular momentum.

Reason (R) explains that angular momentum is conserved under a central force. This is also true.

Furthermore, the conservation of angular momentum directly leads to constant areal velocity, making Reason (R) the correct explanation for Assertion (A).

∴ Both A and R are true, and R is an explanation of A.

51

Which one of the following is not the condition for three vectors A,B\vec{A}, \vec{B} and C \vec{C} to coplanar?

  1. ((a))

    A(B×C)=0\vec{A} \cdot (\vec{B} \times \vec{C}) = 0

  2. ((b))

    A×(B×C)=0\vec{A} \times (\vec{B} \times \vec{C}) = 0

  3. ((c))

    n1A+n2B+n3C=0n_1 \vec{A} + n_2 \vec{B} + n_3 \vec{C} = 0

  4. ((d))

    AxBxCx AyByCy AzBzCz=0\begin{vmatrix} Ax & Bx & Cx \ Ay & By & Cy \ Az & Bz & Cz \end{vmatrix} = 0

Show Answer
Answer: ((b))

A×(B×C)=0\vec{A} \times (\vec{B} \times \vec{C}) = 0

Calculation:

  1. The scalar triple product A · (B × C) = 0 is a valid condition for coplanarity.
  2. The determinant condition AxBxCx AyByCy AzBzCz=0\begin{vmatrix} Ax & Bx & Cx \ Ay & By & Cy \ Az & Bz & Cz \end{vmatrix} = 0 is also valid.
  3. A linear combination n1A + n2B + n3C = 0 is valid.
  4. However, A × (B × C) = 0 does not imply coplanarity.
52

The excess pressure in a soap bubble of 2 mm radius, if surface tension is 0-03 N/m, is

  1. ((a))

    30 N/m2

  2. ((b))

    40 N/m2

  3. ((c))

    60 N/m2

  4. ((d))

    120 N/m2

Show Answer
Answer: ((c))

60 N/m2

Calculation:

Given:

Radius of the bubble, r = 2 mm = 0.002 m

Surface tension, T = 0.03 N/m

Using the formula:

ΔP = 4T / r

⇒ ΔP = (4 × 0.03) / 0.002

⇒ ΔP = 0.12 / 0.002

⇒ ΔP = 60 N/m2

∴ Excess Pressure = 60 N/m2

53

The second's hand of a watch is of 5 cm long. The speed of the tip of this hand is

  1. ((a))

     0.6145cm / s

  2. ((b))

    0.3142cm / s

  3. ((c))

    0.4192cm / s

  4. ((d))

    0.5233cm / s

Show Answer
Answer: ((d))

0.5233cm / s

​Calculation:

Given:

Length of the second's hand = r = 5 cm

Time period = T = 60 s

Using the formula for linear speed:

v = (2πr) / T

Substitute the values:

⇒ v = (2 × 3.1416 × 5) / 60

⇒ v = (31.416) / 60

⇒ v = 0.5233 cm/s

∴ The speed of the tip of the second's hand, using calculations, is approximately 0.5233 cm/s.

54

Torsional couple required to twist a cylinder of length l/2l/2 radius rr and modulus of rigidity ηη by one complete turn is

  1. ((a))

    2π2ηr4l\frac{2\pi^2\eta r^4}{l}

  2. ((b))

    πηr42l\frac{\pi\eta r^4}{2l}

  3. ((c))

    π2ηr4l\frac{\pi^2\eta r^4}{l}

  4. ((d))

    π2ηr42l\frac{\pi^2\eta r^4}{2l}

Show Answer
Answer: ((b))

πηr42l\frac{\pi\eta r^4}{2l}

Concept:

Torsional rigidity:

  • Torsional rigidity is the resistance against torsional deformation.
  • It is the amount of twisting couple or torque required to twist the object by one radian.
  • Torsional rigidity is also known as twisting couple per unit radian twist.

Modulus of rigidity (η ) = Shearing stress / Angle of shear = τ / φ

Calculation:

Consider a cylindrical rod of length l, radius r and coefficient of rigidity M. A couple is applied in a plane perpendicular to its length at the lower end by fixing its upper end.

We can consider the cylinder as consisting of a large number of co-axial hollow cylinders. Now, consider a hollow cylinder of radius x and thickness dx.

Here, AB is the line parallel to the axis OO’ before twist is produced and on twisting, B shifts to B’, then line AB becomes AB’.

The angle of shear = φ

From figure:

BB' = lθ and BB' = xθ

⇒ φ = xθ / l ........(1)

Now, shearing force:

τ = ηφ = ( η x θ) / l

Surface area of the hollow cylinder = 2πx dx

Total shearing force on this area: τ × Area = 2πx dx × ( η x θ / l)

Moment of this force = 2π η (θ / l) x2 dx × x = 2π η (θ / l) x3 dx

Now, integrating between the limits x = 0 and x = r:

T = ∫0r (2π ηθ / l) x3 dx

⇒ T = (2π ηθ / l) × [x4 / 4]0r

⇒ T = (π  η r4 θ) / (2l)

Couple per unit radian twist = ( η π r4) / (2l)

55

Match List-I with List-II and select the correct answer from the codes given below:

List-I
(Body rotating about its diametral axis)
List-II
(Corresponding radius of gyration)
A. Solid sphere of mass M and radius R1. 25R\sqrt{\frac{2}{5} }R
B. Thin spherical shell of radius R and mass M2. 12R\frac{1}{\sqrt{2}} R
C. A circular ring of mass M and radius R3. 12R\frac{1}{2} R
D. A circular disc of mass M and radius R4. 23R\sqrt{\frac{2}{3}} R
  1. ((a))

    A 1, B 4, C 3, D 2.

  2. ((b))

    A 1, B 4, C 2, D 3.

  3. ((c))

    A 4, B 1, C 2, D 3.

  4. ((d))

    A 4, B 1, C 3, D 2.

Show Answer
Answer: ((b))

A 1, B 4, C 2, D 3.

Solution:

Given:

  • List-I contains different bodies rotating about their diametral axes.
  • List-II provides the corresponding radius of gyration values for these bodies.
  • We need to match List-I with List-II using the correct codes.

Concept Used:

  • Radius of gyration (K): It is defined as the distance from the axis of rotation at which the entire mass of the body can be assumed to be concentrated to produce the same moment of inertia.
  • Formula for moment of inertia: I = M × K2, where:
  • I: Moment of inertia
  • M: Mass of the body
  • K: Radius of gyration

Data Matching:

Let us match each body in List-I with its corresponding radius of gyration from List-II:

  • A. Solid sphere of mass M and radius R: The radius of gyration for a solid sphere rotating about its diametral axis is K = √(2/5) R. Match with code 1.
  • B. Thin spherical shell of radius R and mass M: The radius of gyration for a thin spherical shell rotating about its diametral axis is K = √(2/3) R. Match with code 4.
  • C. A circular ring of mass M and radius R: The radius of gyration for a circular ring rotating about its diametral axis is K = (1/√2) R. Match with code 3.
  • D. A circular disc of mass M and radius R: The radius of gyration for a circular disc rotating about its diametral axis is K = (1/2) R. Match with code 2.

Correct Match:

A → 1, B → 4, C → 3, D → 2

∴ The correct answer is Option 1: A 1, B 4, C 3, D 2.

56

The frequency of a light spring when 1 kg weight is suspended on its end is 4 oscillations per second. If 4 kg weight suspended to the same spring, the frequency of oscillations shall be

  1. ((a))

    8 per sec

  2. ((b))

    4 per sec

  3. ((c))

    2 per sec

  4. ((d))

    16 per sec

Show Answer
Answer: ((c))

2 per sec

Concept:

The frequency of a spring-mass system is inversely proportional to the square root of the mass attached to the spring.

Formula: f ∝ 1 / √m, where:

f = frequency of oscillation (in Hz)

m = mass attached to the spring (in kg)

When the mass changes, the relationship between the frequencies can be expressed as:

f2 = f1 × √(m1 / m2)

Calculation:

Given:

Initial frequency, f1 = 4 Hz

Initial mass, m1 = 1 kg

New mass, m2 = 4 kg

Using the formula:

f2 = f1 × √(m1 / m2)

⇒ f2 = 4 × √(1 / 4)

⇒ f2 = 4 × (1 / 2)

⇒ f2 = 2 Hz

∴ The frequency of oscillations is 2 Hz.

57

A particle of mass m executes a simple harmonic motion of amplitude a and frequency n. The maximum kinetic energy is

  1. ((a))

    mn2π2a2m n^2 \pi^2 a^2

  2. ((b))

    4mn2π2a24m n^2 \pi^2 a^2

  3. ((c))

    4mn2π2a4m n^2 \pi^2 a

  4. ((d))

    2mn2π2a22m n^2 \pi^2 a^2

Show Answer
Answer: ((d))

2mn2π2a22m n^2 \pi^2 a^2

Calculation:

Given:

Mass of the particle, m = m

Amplitude of SHM, a = a

Frequency of SHM, n = n

Using the formula for maximum velocity:

vmax = 2π n a

Substituting this into the formula for kinetic energy:

KEmax = (1/2) m v2

⇒ KEmax = (1/2) m (2π n a)2

⇒ KEmax = (1/2) m × 4π2 n2 a2

⇒ KEmax = 2m π2 n2 a2

58

The differential equation for a certain system is

d2xdt2+2kdxdt+ω02x=0\frac{d^2 x}{dt^2} + 2k \frac{dx}{dt} + \omega_0^2 x = 0

If ω0k\omega_0 \gg k the time in which the amplitude falls to 1/e1/e of its initial value will be

  1. ((a))

    1k\frac{1}{k} second

  2. ((b))

    2k\frac{2}{k} second

  3. ((c))

    3k\frac{3}{k} second

  4. ((d))

    4k\frac{4}{k} second

Show Answer
Answer: ((a))

1k\frac{1}{k} second

Calculation:

The system is lightly damped, so the general solution for amplitude decay is:

A(t) = A0 e-k t

Here, A0 is the initial amplitude, and k is the damping coefficient.

The time constant τ is the time taken for the amplitude to fall to 1/e of its initial value.

Using the amplitude equation, the time constant is:

τ = 1/k

From the formula A(t) = A0 e-k t,

when A(t) = A0 / e, we have:

A0 / e = A0 e-k t

Taking natural logarithm (ln) on both sides:

ln(1/e) = -k t

⇒ -1 = -k t

⇒ t = 1/k

59

Two rectangular SHMs are represented by x=asin(2ωt+ϕ)x = a\sin(2\omega t + \phi) and y=bsinωty=b \sin\omega t . The resultant of superposition of two represents

  1. ((a))

    a parabola

  2. ((b))

    the figure of 8

  3. ((c))

    an ellipse

  4. ((d))

    a straight line

Show Answer
Answer: ((b))

the figure of 8

Calculation:

From the given equations:

  1. x = a sin(2ωt + φ) = a[sin(2ωt)cosϕ + cos(2ωt)sinϕ] =a[2sin(ωt)cos(ωt)cosϕ + (1-2sin2(ωt))sinϕ] 
  2. y = b sin(ωt)= sin(ωt) = y/b

We know the trigonometric identity for sin(2A):

sin(2A) = 2 sin(A) cos(A)

Using this, we expand x as:

x  = a[2sin(ωt)cos(ωt)cosϕ + (1-2sin2(ωt))sinϕ] = a[2(y/b)√(1-(y/b)2) cosϕ + (1-2(y/b)2)sinϕ] 

You can cross verify checking evervy value for ϕ , Also check desmos.

60

A tuning fork of frequency 500 Hz is vibrated with a sonometer wire and 8 beats per second are heard. The beat frequency reduces if tension in the wire is slightly increased. The original frequency of the wire is

  1. ((a))

    516 Hz

  2. ((b))

    508 Hz

  3. ((c))

    500 Hz

  4. ((d))

    492 Hz

Show Answer
Answer: ((d))

492 Hz

​Concept Used:

Beat frequency is the absolute difference between the frequencies of two sources.

Formula: fbeat = |fwire - ffork|

When the tension in the wire increases, its frequency increases. If the beat frequency decreases, it indicates fwire was initially greater than ffork.

Calculation:

Let the frequency of the sonometer wire be fwire.

Using fbeat = |fwire - ffork|:

⇒ 8 = |fwire - 500|

Case 1: fwire - 500 = 8

⇒ fwire = 500 + 8 = 508 Hz

Case 2: 500 - fwire = 8

⇒ fwire = 500 - 8 = 492 Hz

∴ The original frequency of the wire is 492 Hz.

61

The power absorbed in a driven harmonic oscillator is maximum at the

  1. ((a))

     highest possible driven frequency

  2. ((b))

    amplitude resonance

  3. ((c))

    velocity resonance

  4. ((d))

    frequency where the amplitude drops to 1/e of its maximum value

Show Answer
Answer: ((c))

velocity resonance

Correct Answer:

Option 3: Velocity resonance

Explanation:

At velocity resonance , the velocity of the oscillator is maximum, leading to maximum power transfer from the driving force to the oscillator.

Option 1 (highest possible driven frequency) is incorrect because, at very high frequencies, the system's response diminishes due to inertia.

Option 2 (amplitude resonance) is incorrect because power absorption is not directly dependent on amplitude.

Option 4 (frequency where amplitude drops to 1/e of its maximum value) is unrelated to power absorption.

∴ The correct answer is Option 3: Velocity resonance.

62

A metal wire of mass 9-8 gm is stretched with a tension of 10 kg weight between two rigid supports one meter apart. The wire passes at the middle point between the poles of permanent magnet and it vibrates in resonance when carrying an a.c. of frequency ff. The value of ff is

  1. ((a))

    100 Hz

  2. ((b))

    98 Hz

  3. ((c))

    50 Hz

  4. ((d))

    49 Hz

Show Answer
Answer: ((c))

50 Hz

Concept:

Vibration of a Stretched String:

The frequency of vibration of a stretched string is determined by the formula:

f = (1 / 2L) × √(T / μ)

T: Tension in the string (in Newtons).

L: Length of the string (in meters).

μ: Linear mass density of the string (mass per unit length) in kg/m.

This formula is derived from the wave equation for a stretched string.

Calculation:

μ = m / L

⇒ μ = (9.8 × 10-3) / 1

⇒ μ = 9.8 × 10-3 kg/m

**⇒**f = (1 / 2L) × √(T / μ)

⇒ f = (1 / 2 × 1) × √(98 / (9.8 × 10-3))

⇒ f = 50 Hz

For the wire to vibrate in resonance with the alternating current, the frequency of the current must match the natural frequency of the wire.

∴ Frequency of the alternating current, f = 50 Hz

63

A transverse wave is represented by y=2sin(62.8t0.314x+3.3)y=2sin(62.8t-0.314x+3.3) where x and y are in centimeters. Its frequency is

  1. ((a))

    100 Hz

  2. ((b))

    50 Hz

  3. ((c))

    31.4 Hz

  4. ((d))

    10 Hz

Show Answer
Answer: ((d))

10 Hz

Concept Used:

The equation of a transverse wave is given as: y = A sin(ωt - kx + φ).

Angular frequency (ω): Represents the rate of oscillation. It is related to the frequency (f) as ω = 2πf.

Frequency (f): Number of wave cycles per second. SI unit: Hertz (Hz).

Formula: f = ω / 2π

Calculation:.

Using the relation:

f = ω / 2π

⇒ f = 62.8 / (2 × 3.1416)

⇒ f = 62.8 / 6.2832

⇒ f = 10 Hz

∴ The frequency of the transverse wave is 10 Hz.

64

If the earth were a homogeneous sphere of radius R and a straight hole were bored in it through its centre, then a particle, dropped into the hole, will execute an SHM with its time period

  1. ((a))

    T=2πRgT=2\pi \sqrt{\frac{R}{g}}

  2. ((b))

    T=2πgRT=2\pi \sqrt{\frac{g}{R}}

  3. ((c))

    T=2π2RgT=2\pi \sqrt{\frac{2R}{g}}

  4. ((d))

    T=2πR2gT=2\pi \sqrt{\frac{R}{2g}}

Show Answer
Answer: ((a))

T=2πRgT=2\pi \sqrt{\frac{R}{g}}

Calculation:

Given:

k = g / R

Substitute k into the time period formula:

T = 2π × √(m / (g / R))

Simplify:

⇒ T = 2π × √(m × R / g)

For a homogeneous sphere, mass (m) cancels out, so:

⇒ T = 2π × √(R / g)

∴ The time period of the particle’s motion is T = 2π √(R / g).

65

In Young's biprism experiment using red light of wavelength 6400 A, 60 fringes are seen in a certain field of view. Instead of this light if experiment is repeated with blue light of wavelength 4800 A, the fringes in the same field of view will be

  1. ((a))

    90

  2. ((b))

    80

  3. ((c))

    60

  4. ((d))

    45

Show Answer
Answer: ((b))

80

Concept:

In Young's biprism experiment, the fringe width (w) is inversely proportional to the wavelength (λ) of the light used. The formula for fringe width is:

w = λD / d

λ: Wavelength of the light (in meters)

D: Distance between the screen and the biprism

d: Distance between the two virtual coherent sources

Since D and d remain constant for both cases, the number of fringes in a fixed field of view is inversely proportional to the wavelength. Hence:

N ∝ 1 / λ

Calculation:

Number of fringes with red light, Nred = 60

Wavelength of red light, λred = 6400 Å = 6400 × 10-10 m

Wavelength of blue light, λblue = 4800 Å = 4800 × 10-10 m

Using Nblue / Nred = λred / λblue,

⇒ Nblue = Nred × (λred / λblue)

⇒ Nblue = 60 × (6400 / 4800)

⇒ Nblue = 80

∴ The number of fringes with blue light is 80.

66

For a thin convex lens, if object is at a distance of x1 from its first focus and image at a distance of x2 from the second focus, if f1and f2 are respectively the first and second focal lengths of the lens, the condition which is satisfied is

  1. ((a))

    x1f1=x2f2x_1 f_1 = x_2 f_2

  2. ((b))

    x1f2=x2f1x_1 f_2 = x_2 f_1

  3. ((c))

    x2x1=f2f1x_2 - x_1 = f_2 - f_1

  4. ((d))

    x1x2=f1f2x_1 x_2 = f_1 f_2

Show Answer
Answer: ((d))

x1x2=f1f2x_1 x_2 = f_1 f_2

Solution

Given: Thin convex lens; object at distance x1 from first focus F1, image at distance x2 from second focus F2. First and second focal lengths are f1 and f2.

Key relation (Newton’s form): When distances are measured from the focal points, the conjugate distances satisfy

x1 x2 = f1 f2

⇒ This is the required condition. (In air, f1 = f2 = f, giving x1x2 = f2.)

67

. Two coherent sources of equal intensity I0I_0 are emitting light of same wavelength λ\lambda and are at a distanceλ4\frac{\lambda}{4} apart. The intensity at a point in direction θ\theta from midpoint of sources is

  1. ((a))

    4I0cos2(θ2)4I_0 \cos^2 \left(\frac{\theta}{2}\right)

  2. ((b))

    4I0cos2θ4I_0 \cos^2 \theta

  3. ((c))

    4I0cos2(π4sinθ)4I_0 \cos^2 \left(\frac{\pi}{4} \sin\theta\right)

  4. ((d))

    4I0cos2(π2sinθ)4I_0 \cos^2 \left(\frac{\pi}{2} \sin\theta\right)

Show Answer
Answer: ((c))

4I0cos2(π4sinθ)4I_0 \cos^2 \left(\frac{\pi}{4} \sin\theta\right)

Calculation:

Distance between sources = λ/4.

Phase difference due to path difference = Δφ = (2π/λ) × (path difference).

For small angles, path difference = (distance between sources) × sin(θ).

⇒ Δφ = (2π/λ) × (λ/4) × sin(θ)

⇒ Δφ = (π/2) × sin(θ)

Using the formula for intensity:

I = 4I0cos2(Δφ/2)

⇒ I = 4I0cos2((π/2) × sin(θ) / 2)

⇒ I = 4I0cos2((π/4) × sin(θ))

68

Four light waves are represented as below:

1. y=a1sinω1ty=a_1 \sin\omega_1 t 2. y=a2sin(ω1t+ϕ)y=a_2 \sin(\omega_1 t + \phi) 3. y=a1sinω2ty=a_1 \sin\omega_2 t 4. y=a2sin2ω1ty=a_2 \sin 2\omega_1 t

( aand a2 are nearly equal)

The interference fringes may only be observed due to superposition of

  1. ((a))

    1 and 2

  2. ((b))

    1 and 3 

  3. ((c))

    1 and 4 

  4. ((d))

    3 and 4

Show Answer
Answer: ((a))

1 and 2

​Concept Used:

Condition for Interference: Two light waves interfere only if they are coherent. Coherence implies that the waves have:

The same frequency (ω).

A constant phase difference (φ).

If either the frequency or the phase difference is not constant, interference fringes will not be observed.

Analysis:

1 and 2: Both waves have the same frequency (ω1), and a constant phase difference (φ). Therefore, they are coherent and can produce interference fringes.

1 and 3: Wave 1 has frequency ω1, while Wave 3 has frequency ω2. Since their frequencies are different, they are not coherent, and interference fringes will not be observed.

1 and 4: Wave 4 has frequency 2ω1, which is different from Wave 1's frequency (ω1). Therefore, they are not coherent, and interference fringes will not be observed.

3 and 4: Wave 3 has frequency ω2, while Wave 4 has frequency 2ω1. Since their frequencies are different, they are not coherent, and interference fringes will not be observed.

Conclusion:

∴ The interference fringes can only be observed due to the superposition of Waves 1 and 2.

69

The refractive index of diamond is 2.42. The critical angle for total internal reflection for light passing from diamond to air is, about

  1. ((a))

    30°

  2. ((b))

    24.4°

  3. ((c))

    35°

  4. ((d))

    40°

Show Answer
Answer: ((b))

24.4°

Concept:

Refractive Index (n): Measures how much light bends when moving between two mediums.

Critical Angle (θc): The angle of incidence above which total internal reflection occurs.

Formula Used: sin(θc) = 1 / n

Calculation:

Given:

Refractive index of diamond, n = 2.42

Using the formula: sin(θc) = 1 / n

⇒ sin(θc) = 1 / 2.42

⇒ sin(θc) ≈ 0.413

To find θc, take the inverse sine:

⇒ θc = sin-1(0.413)

⇒ θc ≈ 24.4°

∴ The critical angle for total internal reflection is approximately 24.4°.

70

For calcite, μ0=1.658\mu_0 = 1.658 andμE=1.486\mu_E = 1.486 for sodium yellow light. The thickness of the thinnest quarter-wave plate of calcite for this light, is

  1. ((a))

    0.70×1040.70 \times 10^{-4} cm

  2. ((b))

    0.86×1040.86 \times 10^{-4} cm

  3. ((c))

    0.95×1040.95 \times 10^{-4} cm

  4. ((d))

    0.15×1030.15 \times 10^{-3} cm

Show Answer
Answer: ((b))

0.86×1040.86 \times 10^{-4} cm

Concept:

A quarter-wave plate is an optical device that introduces a phase difference of 90° (or π/2 radians) between the ordinary and extraordinary rays. The thickness of the thinnest quarter-wave plate is calculated using the formula:

Thickness (d):

d = λ / [4 × (μ0 - μE)]

λ: Wavelength of the light in vacuum (for sodium yellow light, λ = 5890 × 10-8 cm)

μ0: Refractive index for ordinary ray

μE: Refractive index for extraordinary ray

Calculation:

Given:

λ = 5890 × 10-8 cm

μ0 = 1.658

μE = 1.486

Using the formula:

d = λ / [4 × (μ0 - μE)]

⇒ d = (5890 × 10-8) / [4 × (1.658 - 1.486)]

⇒ d ≈ 0.8564 × 10-4 cm

71

Which one of the following is not correctly matched?

  1. ((a))

    When the — Principal points optical system coincide with the is situated in nodal points the same medium

  2. ((b))

    The planes — Nodal planes passing through the nodal points and perpendicular to the axis

  3. ((c))

    The planes — Focal planes passing through the principal foci perpendicular to the axis

  4. ((d))

    The number of — Four cardinal points of an optical system

Show Answer
Answer: ((a))

When the — Principal points optical system coincide with the is situated in nodal points the same medium

Explanation:

Option 1: When the principal points of an optical system coincide with the nodal points, the medium is the same. - This statement is incorrect because principal points and nodal points are distinct properties of optical systems. Even if the medium is the same, they do not always coincide.

Option 2: The nodal planes pass through the nodal points and are perpendicular to the axis. - This statement is correct.

Option 3: The focal planes pass through the principal foci and are perpendicular to the axis. - This statement is correct.

Option 4: The number of cardinal points in an optical system is four. - This statement is correct.

∴ The correct answer is Option 1.

72

With reference to laser, which of the following statement(s) is/are correct?

  1. It is used in surgery.
  2. It is used in radar.
  3. It is used in the study of moon's surface.
  4. It is used in the study of distance of distant objects.

Select the correct answer using the code given below.

  1. ((a))

    1 only

  2. ((b))

    1 and 2 only

  3. ((c))

    1, 2 and 3 only

  4. ((d))

    1, 3 and 4

Show Answer
Answer: ((d))

1, 3 and 4

Concept Used:

Lasers (Light Amplification by Stimulated Emission of Radiation) are highly focused beams of light with unique properties that make them suitable for various applications:

  • Surgery: Lasers are widely used in medical procedures for cutting and cauterizing tissues due to their precision and ability to minimize damage to surrounding areas.
  • Radar: While traditional radar systems use radio waves, lasers are not typically used in radar. Hence, this statement is incorrect.
  • Study of the Moon's Surface: Lasers are used in lunar studies, such as laser altimetry, to map the moon's surface accurately.
  • Study of the Distance of Distant Objects: Lasers are used in ranging techniques (e.g., LIDAR) to measure distances to objects with high precision.

Therefore, the correct answer is:

Option 4: 1, 3, and 4

73

A zone plate is to be constructed with focal length of 50 cm for λ=5.0×10−5 cm. Its first radius is

  1. ((a))

    0.40 mm 

  2. ((b))

    0.50 mm 

  3. ((c))

    0.60 mm 

  4. ((d))

    0.75 mm 

Show Answer
Answer: ((b))

0.50 mm 

​Concept Used:

A zone plate is an optical device that focuses light based on diffraction.

The radius of the nth zone (Rn) is determined using the formula:

Formula Used:

Rn = √(n × f × λ)

For the first radius (R1):

R1 = √(1 × f × λ)

Calculation:

Substitute the values:

f = 50 cm, λ = 5.0 × 10-5 cm

⇒ R1 = √(1 × 50 × 5.0 × 10-5)

⇒ R1 = 0.50 mm

∴ The first radius of the zone plate is 0.50 mm.

74

Consider the following Assertion (A) and Reason (R):

Assertion (A): When a light ray falls on a transparent surface having incident angle equal to polarizing angle; the refracted and reflected rays are perpendicular to each other.

Reason (R): When light incidents on polarizing angle (ip​) it is given by ip​=tan−1(μ), where μ is the refractive index of the surface.

Select the correct answer using the codes given below.

  1. ((a))

    A and R both true and R may explain A properly.

  2. ((b))

    A and R both true but R cannot explain A.

  3. ((c))

    A is true but R is false.

  4. ((d))

    A is false but R is true.

Show Answer
Answer: ((a))

A and R both true and R may explain A properly.

Concept Used:

Polarizing Angle: The angle of incidence at which the reflected light is completely polarized.

At the polarizing angle (ip), the reflected and refracted rays are perpendicular to each other.

The polarizing angle is mathematically expressed as:

ip = tan-1(μ),

where μ is the refractive index of the medium.

Analyze Assertion (A)

Assertion states that at the polarizing angle (ip), the refracted and reflected rays are perpendicular.

This is a well-known property of light behavior at the polarizing angle.

∴ Assertion (A) is true.

Analyze Reason (R)

Reason states the formula for the polarizing angle: ip = tan-1(μ), where μ is the refractive index.

This formula is correct and describes the relationship between the polarizing angle and the refractive index.

∴ Reason (R) is true.

 

Both Assertion (A) and Reason (R) are true, and Reason (R) explains Assertion (A) properly.

75

A short-sighted man can clearly see the objects up to a distance of 1.5 m. The power of the lens spectacles necessary for the remedy of this defect, is

  1. ((a))

    -0.67D

  2. ((b))

    -1.50D

  3. ((c))

    +0.67D

  4. ((d))

    +1.50D

Show Answer
Answer: ((a))

-0.67D

Concept:

Short-Sightedness (Myopia):

Short-sightedness is a condition where a person can clearly see nearby objects but struggles to see distant objects.

The defect is corrected by using a concave lens, which diverges light rays before they enter the eye.

Lens Power (P): The power of a lens is given by the formula:

P = 1 / f

Where:

P: Lens power (in Diopters, D)

f: Focal length of the lens (in meters, m)

Note: For concave lenses, the focal length (f) is negative.

Calculation:

Given:

Maximum distance the person can see clearly, dmax = 1.5 m

To correct this defect, the lens must focus distant light rays (from infinity) to the farthest point the person can see (1.5 m).

Thus, the focal length of the lens is:

f = -dmax = -1.5 m

Using the formula for power of a lens:

P = 1 / f

⇒ P = 1 / (-1.5)

⇒ P = -0.67 D

∴ The power of the lens required is -0.67 D.

76

Which one of the following statements is not true?

  1. ((a))

    Water freezes at 273 K.

  2. ((b))

    Ice melts above 0°C.

  3. ((c))

    Water boils at 100 K.

  4. ((d))

    The normal temperature of healthy man is 37°C.

Show Answer
Answer: ((c))

Water boils at 100 K.

Concept:

  • Water freezes at 273 K: This is true. 273 K is equivalent to 0°C, which is the freezing point of water.
  • Ice melts above 0°C: This is true. Ice begins melting at 0°C under normal atmospheric pressure.
  • Water boils at 100 K: This is false. Water boils at 100°C, not 100 K. 100 K is equivalent to -173.15°C, which is far below the boiling point.
  • The normal temperature of a healthy man is 37°C: This is true. Human body temperature is approximately 37°C under normal conditions.

 

The correct answer is Option 3, as it is the only statement that is not true.

77

10 gm of ice converts into water at constant temperature 0°C. The change in entropy in cal/K is

  1. ((a))

    0.93

  2. ((b))

    1.93

  3. ((c))

    2.93

  4. ((d))

    0.293

Show Answer
Answer: ((c))

2.93

​Concept Used:

Entropy (ΔS) is a measure of disorder or randomness in a system.

The formula for change in entropy during a phase change is:

ΔS = Q / T, where:

Q = Heat absorbed or released (cal)

T = Temperature (K)

For conversion of ice to water, heat absorbed (Q) = m × L

Calculation:

Step 1: Calculate heat absorbed (Q):

⇒ Q = m × L

⇒ Q = 10 × 80

⇒ Q = 800 cal

⇒ T = 0°C + 273 = 273 K

⇒ ΔS = Q / T

⇒ ΔS = 800 / 273

⇒ ΔS ≈ 2.93 cal/K

∴ The change in entropy is 2.93 cal/K.

78

The pressure of a gas is increased by 50 percent at constant temperature. The decrease in volume shall be around

  1. ((a))

    66%

  2. ((b))

    33%

  3. ((c))

    17%

  4. ((d))

    8%

Show Answer
Answer: ((b))

33%

Calculation:

Let the initial volume be V1 = 1 unit (assumed for simplicity).

Initial pressure, P1 = P

Final pressure, P2 = 1.5P

Using the formula:

V2 = (P1 / P2) × V1

⇒ V2 = (P / 1.5P) × 1

⇒ V2 = (1 / 1.5)

⇒ V2 ≈ 0.66

Decrease in volume = V1 - V2

⇒ Decrease = 1 - 0.66

⇒ Decrease ≈ 0.33

∴ The decrease in volume is approximately 0.33.

79

Which one of the following is not a Maxwell's thermodynamic relation?

  1. ((a))

    (TV)S=(PS)V\left(\frac{\partial T}{\partial V}\right)_S = -\left(\frac{\partial P}{\partial S}\right)_V

  2. ((b))

    (SV)T=(PT)V\left(\frac{\partial S}{\partial V}\right)_T = \left(\frac{\partial P}{\partial T}\right)_V

  3. ((c))

    (TP)S=(VS)P\left(\frac{\partial T}{\partial P}\right)_S = \left(\frac{\partial V}{\partial S}\right)_P

  4. ((d))

    (SP)T=(TV)P\left(\frac{\partial S}{\partial P}\right)_T = -\left(\frac{\partial T}{\partial V}\right)_P

Show Answer
Answer: ((d))

(SP)T=(TV)P\left(\frac{\partial S}{\partial P}\right)_T = -\left(\frac{\partial T}{\partial V}\right)_P

Explanation:

If there is a relation between x, y, and z, then z may be expressed as a function of x and y.

An equation of the type dz = Mdx + Ndy is an exact differential if:

(∂M/∂y)x = (∂N/∂x)y

For a pure substance undergoing a reversible process, these equations hold true:

  1. dU = T.ds – p.dv
  2. dH = T.ds + v.dp
  3. dF = –p.dV – s.dT
  4. dG = v.dP – s.dT

They can be written as:

  1. (∂T/∂v)s = –(∂p/∂s)v
  2. (∂T/∂p)s = (∂v/∂s)p
  3. (∂p/∂T)v = (∂s/∂v)T
  4. (∂v/∂T)p = –(∂s/∂p)T

These are known as Maxwell’s Equations.

Out of these, option 4 does not match with Maxwell’s Equations.

Maxwell relation

Other Maxwell relations:

If x = φ(y, z), then:

dx = (∂x/∂y)z dy + (∂x/∂z)y dz

or, (∂x/∂y)z · (∂z/∂x)y · (∂y/∂z)x = –1

If F = φ(x, y, z), then:

(∂x/∂y)F · (∂y/∂z)F · (∂z/∂x)F = 1

80

The first law of thermodynamics for an adiabatic process is

  1. ((a))

    du=−δW

  2. ((b))

    du=δW

  3. ((c))

    du=0

  4. ((d))

    du=−δH+2δW

Show Answer
Answer: ((a))

du=−δW

​Concept Used:

First Law of Thermodynamics: It states that the change in internal energy (du) of a system is equal to the heat added to the system (δQ) minus the work done by the system (δW).

Formula: du = δQ - δW

Adiabatic Process: In an adiabatic process, there is no heat exchange with the surroundings, i.e., δQ = 0.

Calculation:

For adiabatic conditions:

Using the first law of thermodynamics:

⇒ du = δQ - δW

⇒ du = 0 - δW   (Since δQ = 0)

⇒ du = -δW

∴ The correct answer is Option 1: du = -δW

81

The wavelength of the radiations for which the energy is maximum in the spectrum is 490 nm. The effective temperature of the sun is

  1. ((a))

    6920 K

  2. ((b))

    6000 K

  3. ((c))

    5914 K

  4. ((d))

    5820 K

Show Answer
Answer: ((c))

5914 K

Concept:

The problem involves Wien's Displacement Law, which relates the wavelength at which the intensity of radiation is maximum to the temperature of a blackbody.

Wien's Displacement Law: λmax × T = b

Where:

λmax = Wavelength of maximum intensity (in meters)

T = Temperature of the blackbody (in Kelvin)

b = Wien's constant = 2.898 × 10-3 m·K

Calculation:

Given:

Wavelength of maximum intensity, λmax = 490 nm = 490 × 10-9 m

Wien's constant, b = 2.898 × 10-3 m·K

Using the formula: λmax × T = b

⇒ T = b / λmax

⇒ T = (2.898 × 10-3) / (490 × 10-9)

⇒ T = 5914 K

∴ The effective temperature of the Sun is approximately 5914 K.

82

A piece of red glass when heated in dark to red hot state, it will appear to be

  1. ((a))

    white

  2. ((b))

    red

  3. ((c))

    green

  4. ((d))

    invisible

Show Answer
Answer: ((c))

green

Concept Used:

Thermal Radiation: When an object is heated to high temperatures, it emits electromagnetic radiation known as thermal radiation.

As the temperature increases, the emitted radiation shifts to shorter wavelengths, causing the object to appear brighter and change color.

At sufficiently high temperatures, the radiation emitted becomes predominantly in the visible spectrum, leading to a white-hot appearance.

Explanation:

Initially, the red glass appears red because it absorbs other wavelengths and reflects red light.

When the glass is heated to a high temperature in the dark, it emits thermal radiation that spans the visible spectrum.

A piece of red glass when heated to a red-hot state in a dark room will appear to be green. This is because red and green are complementary colors, and when the glass is heated, it starts to emit radiation in the green wavelength range.

83

The experimental verification of Kirchhoff's law was done by

  1. ((a))

    Stefan

  2. ((b))

    Planck

  3. ((c))

    Ritchie

  4. ((d))

    Wien

Show Answer
Answer: ((a))

Stefan

Concept:

Kirchhoff's Law: This law deals with the distribution of energy in thermal radiation. It states that for a body in thermal equilibrium, the emissivity is equal to the absorptivity.

The law was experimentally verified by Stefan, who made significant contributions to the study of thermal radiation.

∴ The experimental verification of Kirchhoff's law was done by Stefan.

84

A Carnot engine operates between 27 °C and 327°C. If it does a network of 800 joule, the heat provided to the engine from source is

  1. ((a))

    8800 joule

  2. ((b))

    1600 joule

  3. ((c))

    873 joule

  4. ((d))

    800 joule

Show Answer
Answer: ((b))

1600 joule

Concept Used:

Efficiency of a Carnot engine: Efficiency (η) = 1 - (T2 / T1)

Relation between efficiency, work, and heat: η = W / Q1, where Q1 is the heat supplied to the engine.

Calculation:

Calculate efficiency (η):

η = 1 - (T2 / T1)

⇒ η = 1 - (300 / 600)

⇒ η = 1 - 0.5

⇒ η = 0.5

Use η = W / Q1 to find Q1:

η = W / Q1

⇒ Q1 = W / η

⇒ Q1 = 800 / 0.5

⇒ Q1 = 1600 J

∴ The heat provided to the engine from the source is Q1 = 1600 J.

85

The Clausius-Clapeyron equation is

  1. ((a))

    dPdT=LT(V2V1)\frac{dP}{dT} = \frac{L}{T(V_2 - V_1)}

  2. ((b))

    dPdT=TL(V2V1)\frac{dP}{dT} = \frac{T}{L(V_2 - V_1)}

  3. ((c))

    dPdT=L2T(V2V1)\frac{dP}{dT} = \frac{L^2}{T(V_2 - V_1)}

  4. ((d))

    dPdT=LT(V2V1)\frac{dP}{dT} = LT(V_2 - V_1)

Show Answer
Answer: ((a))

dPdT=LT(V2V1)\frac{dP}{dT} = \frac{L}{T(V_2 - V_1)}

Concept Used:

The Clausius-Clapeyron equation relates the rate of change of pressure (P) with temperature (T) during a phase change.

Formula:

dP/dT = L / T(V2 - V1)

Where:

dP/dT: Slope of the pressure-temperature curve.

L: Latent heat of the phase transition (J/mol).

T: Absolute temperature (K).

V2 - V1: Difference in molar volumes of two phases (m3/mol).

86

Two cells each of e.m.f. E and internal resistance r are connected in parallel across a resistor R. The power delivered to the resistor is maximum, if

  1. R=r/2
  2. R=r

Select the correct answer using the codes given below.

  1. ((a))

    1

  2. ((b))

    2

  3. ((c))

    Both 1 and 2

  4. ((d))

    Neither 1 nor 2

Show Answer
Answer: ((a))

1

Concept Used:

For maximum power, R = rtotal

The total internal resistance of two identical cells in parallel is given by:

rparallel = r / 2

Maximum power transfer theorem:

The power delivered to a resistor is maximum when the external resistance equals the total internal resistance of the circuit (as per the condition for maximum power transfer).

87

A 2 µF capacitor with 4 Ω resistor is connected as shown in the following circuit:

The current flowing through 2 Ω resistor is

  1. ((a))

    9 amp

  2. ((b))

    0.9 amp

  3. ((c))

    3 amp

  4. ((d))

    1.5 amp

Show Answer
Answer: ((b))

0.9 amp

Calculation:

Calculate the equivalent resistance of the circuit.

The branch of 4 Ω will be open as there is capacitor which will act as open circuit due to capacitor.

The 2 Ω resistor (R2) is in parallel with the 3 Ω resistor (R1).

Total Resistance, R = (R1R2)/R1 + R2

⇒ R = 1.2 Ω

The net resistance is R = 1.2 + 2.8 = 4 Ω 

Calculate the total current flowing in the circuit using Ohm’s Law.

Using I = V / R:

⇒ I = 6 V / 4 Ω

⇒ I = 1.4 A

The current through 2 Ω is i = 3/(3+2)I = 3/ 5 × 1.4 = 0.84 ≈ 0.9 A

88

A step-up transformer works on 220 V and gives 2 amp to an external circuit. The turn ratio between primary and secondary is 2:25. Assuming 100% efficiency, the output voltage will be

  1. ((a))

    275 volt

  2. ((b))

    440 volt

  3. ((c))

    2750 volt

  4. ((d))

    5500 volt

Show Answer
Answer: ((c))

2750 volt

Calculation:

Given:

Primary Voltage, Vp = 220 V

Turn Ratio, Np:Ns = 2:25

Efficiency = 100%

Using Vs/Vp = Ns/Np:

⇒ Vs = Vp × (Ns/Np)

⇒ Vs = 220 × (25/2)

⇒ Vs = 2750

∴ Output Voltage, Vs = 2750 V

89

Three equal resistances each of value R are connected so as to form a triangle. The equivalent resistance across any two corners of triangle is

  1. ((a))

    3 R

  2. ((b))

    32R\frac{3}{2}R

  3. ((c))

    13R\frac{1}{3}R

  4. ((d))

    23R\frac{2}{3}R

Show Answer
Answer: ((d))

23R\frac{2}{3}R

Calculation:

Given three resistances: RAB = R, RBC = R, RCA = R.

To find the equivalent resistance across any two corners (e.g., A and B):

  1. Resistance RCA is in series with RBC.

Using the series formula:

⇒ Rseries = (R + R)

⇒  Rseries = 2R 

  1. This  Rseries is in parallel with RAB:

⇒ Req = (RAB × Rseries ) /( RAB + Rseries)

⇒ Req = R × 2R / (R + 2R)

⇒ Req = 2R / 3

∴ The equivalent resistance across any two corners is (2/3)R.

90

Match List-I with List-II and select the correct answer from the codes given below:

List-I
(Magnetic materials)
List-II (Susceptibility)
A. Diamagnetic1. x=1x=-1
B. Paramagnetic2. x=vex=-ve and small
C. Ferromagnetic3. x = +ve and small
D. Perfect diamagnetic4. x = +ve and large
  1. ((a))

    A 3, B 2, C 1, D 4.

  2. ((b))

    A 4, B 2, C 3, D 1.

  3. ((c))

    A 2, B 3, C 4, D 1.

  4. ((d))

    A 1, B 2, C 4, D 3.

Show Answer
Answer: ((c))

A 2, B 3, C 4, D 1.

Concept:

Diamagnetic materials: These have negative susceptibility (x = -ve) and the value is very small.

Paramagnetic materials: These have positive susceptibility (x = +ve) and the value is small.

Ferromagnetic materials: These have positive susceptibility (x = +ve) and the value is large.

Perfect Diamagnetic materials: These have susceptibility x = -1.

Matching:

Using the above definitions:

A. Diamagnetic ⇒ 2 (x = -ve and small)

B. Paramagnetic ⇒ 3 (x = +ve and small)

C. Ferromagnetic ⇒ 4 (x = +ve and large)

D. Perfect Diamagnetic ⇒ 1 (x = -1)

Correct Option:: A 2, B 3, C 4, D 1

91

Which one of the following is not correctly matched?

  1. ((a))

    Arrhenius equation : Effect of temperature over rate of reaction

  2. ((b))

    van't Hoff's differential method : Order of reaction

  3. ((c))

    t1/2=0.693×1Rt1/2=0.693×\frac{1}{R}​ : First-order reaction

  4. ((d))

    t1/2=1initialconcentrationofreactant×1Rt_{1/2}=\frac{1}{initial concen-tration of reactant}×\frac{1}{R}​ : Zero-order reaction

Show Answer
Answer: ((d))

t1/2=1initialconcentrationofreactant×1Rt_{1/2}=\frac{1}{initial concen-tration of reactant}×\frac{1}{R}​ : Zero-order reaction

CONCEPT:

Key Equations and Methods in Chemical Kinetics

  • Arrhenius Equation:
  • It describes the temperature dependence of the rate constant (k) of a reaction.
  • The equation is k=Aexp(Ea/RT)k = A \exp^{(-E_a/RT)} , where Ea is activation energy, R is the gas constant, and T is temperature.
  • It shows that as temperature increases, the rate constant and hence the reaction rate increase exponentially.
  • van't Hoff's Differential Method:
  • This method is used to experimentally determine the order of reaction.
  • By measuring how the initial rate changes with the concentration of reactants, the order of reaction with respect to each reactant can be found.
  • Half-life of a First-Order Reaction:
  • The half-life t_{1/2} of a first-order reaction is independent of the initial concentration.
  • The formula is t1/2=0.693kt_{1/2} = \frac{0.693}{k} , where k is the rate constant.
  • Half-life of a Zero-Order Reaction:
  • The half-life depends on the initial concentration of the reactant in zero-order reactions.
  • The formula is t1/2=[initial concentration]2k t_{1/2} = \frac{[\text{initial concentration}]}{2k}  , where k is the zero-order rate constant.

EXPLANATION:

  • Statement 1: Correct. The Arrhenius equation directly relates temperature to reaction rate.
  • Statement 2: Correct. The van’t Hoff differential method is a classic experimental technique for determining reaction order.
  • Statement 3: Correct. The expression t1/2=0.693×1Rt_{1/2} = 0.693 \times \frac{1}{R} matches the first-order half-life formula.
  • Statement 4: Incorrect. For zero-order reactions, the half-life depends on the initial concentration and rate constant as shown in the formula.

Therefore, option 4 is incorrect statment.

92

Consider the following statements:

  1. When temperature of the reaction is increased, activation energy is lowered.
  2. Reaction occurs when reacting molecules have lesser energy than the threshold energy.

Select the correct answer from the codes given below.

  1. ((a))

    Both 1 and 2 are true

  2. ((b))

    Only 1 is true

  3. ((c))

    Only 2 is true

  4. ((d))

    Neither 1 nor 2 is true

Show Answer
Answer: ((d))

Neither 1 nor 2 is true

CONCEPT:

Activation Energy and Reaction Dynamics

  • Activation Energy (Ea): It is the minimum energy required for reactant molecules to undergo a chemical reaction. It acts as an energy barrier that the molecules need to overcome for the reaction to proceed.
  • Effect of Temperature: Increasing the temperature does not alter the activation energy itself. Instead, it increases the kinetic energy of the molecules, resulting in a larger fraction of molecules having energy equal to or greater than the activation energy, thus increasing the rate of reaction.
  • Threshold Energy: Reaction occurs only when the energy of the reacting molecules is equal to or greater than the threshold energy, which includes both the activation energy and the potential energy of the reactants.

EXPLANATION:

  • Statement 1: "When temperature of the reaction is increased, activation energy is lowered" is false.
  • The activation energy is a fixed property of the reaction and does not change with temperature. What changes is the number of molecules that have sufficient energy to overcome this barrier.
  • Statement 2: "Reaction occurs when reacting molecules have lesser energy than the threshold energy" is also false.
  • For a reaction to occur, the molecules must have energy equal to or greater than the threshold energy.
  • Since both statements are incorrect, the correct answer is Neither 1 nor 2 is true.

Therefore, the correct answer is Option 4: Neither 1 nor 2 is true.

93

Which one of the following salts solution in water has the highest value of pH?

  1. ((a))

    NaCl

  2. ((b))

    KNO3

  3. ((c))

    Na2CO3

  4. ((d))

    ZnCl2

Show Answer
Answer: ((c))

Na2CO3

CONCEPT:

pH of a solution

  • The pH of a solution is a measure of its acidity or basicity. It is calculated as:

pH = -log[H+]

  • Salts in water can undergo hydrolysis, affecting the pH of the solution:
  • Neutral salts like NaCl and KNO3 do not hydrolyze and produce solutions with a neutral pH of 7.
  • Basic salts like Na2CO3 hydrolyze to form OH-, increasing the pH above 7.
  • Acidic salts like ZnCl2 hydrolyze to form H+, lowering the pH below 7.

EXPLANATION:

  • Examining the given salts:
  • NaCl: Sodium chloride is a neutral salt formed from a strong acid (HCl) and a strong base (NaOH). It does not hydrolyze in water, resulting in a neutral pH of 7.
  • KNO3: Potassium nitrate is also a neutral salt formed from a strong acid (HNO3) and a strong base (KOH). Its solution has a pH of 7.
  • Na2CO3: Sodium carbonate is a basic salt formed from a weak acid (H2CO3) and a strong base (NaOH). Its solution has a pH greater than 7 due to hydrolysis producing OH-.
  • ZnCl2: Zinc chloride is an acidic salt formed from a strong acid (HCl) and a weak base (Zn(OH)2). Its solution has a pH less than 7 due to hydrolysis producing H+.

Therefore, the correct answer is Na2CO3.

94

Kw Ka, C and α\alpha are the ionic products of water, dissociation constant of acid, concentration of the salt of weak acid and strong base and degree of hydrolysis of salt respectively. The correct relationship between these is

  1. ((a))

    α=Kw1/2Ka1/2C1/2\alpha = K_w^{1/2} \cdot K_a^{-1/2} \cdot C^{-1/2}

  2. ((b))

    α=KwKaC\alpha = K_w \cdot K_a \cdot C

  3. ((c))

    α=Kw1/2Ka1/2C1/2\alpha = K_w^{-1/2} \cdot K_a^{-1/2} \cdot C^{-1/2}

  4. ((d))

    α=Kw1/2Ka1/2C1/2\alpha = K_w^{1/2} \cdot K_a^{1/2} \cdot C^{1/2}

Show Answer
Answer: ((a))

α=Kw1/2Ka1/2C1/2\alpha = K_w^{1/2} \cdot K_a^{-1/2} \cdot C^{-1/2}

CONCEPT:

Degree of Hydrolysis (α) of Salt

  • The degree of hydrolysis (α) of a salt formed from a weak acid and a strong base depends on the ionic product of water (Kw), the dissociation constant of the acid (Ka), and the concentration of the salt (C).
  • The formula for the degree of hydrolysis is derived from the equilibrium condition of the hydrolysis reaction and is given by:
<br>

α = √(Kw / Ka × C)

  • Rewriting the formula in terms of powers, we get:
<br>

α = Kw1/2 × Ka-1/2 × C-1/2

EXPLANATION:

  • Given the relationship between α, Kw, Ka, and C, the formula must correctly represent the dependence of the degree of hydrolysis on these variables.
  • Option 1 provides the correct relationship:
<br>

α = Kw1/2 × Ka-1/2 × C-1/2

  • This formula is consistent with the concept that hydrolysis increases with higher Kw (ionic product of water) and decreases with higher Ka (stronger acid) or higher salt concentration C.
  • The other options are incorrect because they either involve incorrect powers or incorrect dependence on the variables.

Therefore, the correct answer is Option 1:

<br>

α = Kw1/2 × Ka-1/2 × C-1/2.

95

At 80°C, pure distilled water has [H3​O+] concentration 1×10−6 mole/L. What is the value of Kw​ at this temperature?

  1. ((a))

    1×10−6

  2. ((b))

    1×10−8

  3. ((c))

    1×10−12

  4. ((d))

    1×10−14

Show Answer
Answer: ((c))

1×10−12

CONCEPT:

Ionization of Water and Kw

Kw = [H3O+] × [OH-]

  • Water ionizes slightly into hydronium ions (H3O+) and hydroxide ions (OH-).
  • The ionization constant of water, Kw, is given by the product of the concentrations of H3O+ and OH- ions:
  • At 25°C (standard temperature), Kw is 1 × 10-14, but it changes with temperature.

EXPLANATION:

Thus, [H3O+] = [OH-] = 1 × 10-6 M.

Kw = [H3O+] × [OH-]

Kw = (1 × 10-6) × (1 × 10-6)

Kw = 1 × 10-12

  • At 80°C, the problem states that the [H3O+] concentration is 1 × 10-6 M.
  • For pure water, the concentrations of H3O+ and OH- are equal because water ionizes symmetrically.
  • Kw is calculated as the product of these concentrations:

CONCLUSION:

The value of Kw at 80°C is 1 × 10-12, and the correct answer is option 3.

96

Which one of the following is not a buffer solution?

  1. ((a))

    Mixture of aqueous solution of acetic acid and sodium acetate

  2. ((b))

    Mixture of aqueous solution of ammonium hydroxide and ammonium chloride

  3. ((c))

    Mixture of aqueous solution of sodium citrate and citric acid

  4. ((d))

    Mixture of aqueous solution of sodium hydroxide and hydrochloric acid

Show Answer
Answer: ((d))

Mixture of aqueous solution of sodium hydroxide and hydrochloric acid

CONCEPT:

Buffer Solution

  • A buffer solution is an aqueous solution that resists changes in pH when small amounts of an acid or a base are added.
  • Buffer solutions typically consist of a weak acid and its conjugate base (or a weak base and its conjugate acid).
  • Examples of buffer solutions:
  • Mixture of acetic acid and sodium acetate (weak acid and its salt).
  • Mixture of ammonium hydroxide and ammonium chloride (weak base and its salt).

EXPLANATION:

1) Mixture of aqueous solution of acetic acid and sodium acetate:

  • This is a classic acidic buffer.
  • Weak acid (acetic acid) + its salt with a strong base (sodium acetate).
  • This is a buffer.

2) Mixture of aqueous solution of ammonium hydroxide and ammonium chloride:

  • This forms a basic buffer.
  • Weak base (ammonium hydroxide) + its salt with a strong acid (ammonium chloride).
  • This is a buffer.

3) Mixture of aqueous solution of sodium citrate and citric acid**:**

  • Sodium citrate is a salt of a weak acid (citric acid) and a strong base.
  • Adding sodium hydroxide (a strong base) will not form a buffer but will increase the basicity further.
  • In some cases citrate buffers can be formed, but not with NaOH alone.

4) Mixture of aqueous solution of sodium hydroxide and hydrochloric acid:

  • This is a neutralization reaction, not a buffer system.
  • Strong base (NaOH) + strong acid (HCl) → forms NaCl and water.
  • This is not a buffer.
<br>

The correct answer is Mixture of aqueous solution of sodium hydroxide and hydrochloric acid.

97

Solubility of PbI2​ is S. The correct expression for solubility product, Ksp​ is

  1. ((a))

    Ksp​=S3

  2. ((b))

    Ksp​=S2

  3. ((c))

    Ksp​=4S2

  4. ((d))

    Ksp​=4S3

Show Answer
Answer: ((d))

Ksp​=4S3

CONCEPT:

Solubility Product (Ksp)

  • The solubility product is an equilibrium constant that applies to the dissolution of a sparingly soluble compound.
  • For a compound ABx, which dissociates as:

ABx → A+ + xB-

  • The solubility product (Ksp) is expressed as:

Ksp = [A+][B-]x

EXPLANATION:

  • The dissociation of PbI2 in water is as follows:

PbI2(s) → Pb2+(aq) + 2I-(aq)

  • Let the solubility of PbI2 be S. This means:
  • The concentration of Pb2+ ions = S
  • The concentration of I- ions = 2S (since 2 moles of I- are produced for every mole of PbI2)
  • The expression for Ksp is:

Ksp = [Pb2+][I-]2

  • Substituting the concentrations in terms of S:

Ksp = (S)(2S)2

Ksp = S × 4S2

Ksp = 4S3

Therefore, the correct expression for the solubility product, Ksp, is Ksp = 4S3.

98

Which one of the following will change the value of equilibrium constant?

  1. ((a))

    Addition of reactant

  2. ((b))

    Change of temperature

  3. ((c))

    Addition of a catalyst

  4. ((d))

    Addition of product

Show Answer
Answer: ((b))

Change of temperature

CONCEPT:

Equilibrium Constant (K)

  • The equilibrium constant (K) is a measure of the extent of a chemical reaction at equilibrium.
  • It is only affected by changes in temperature and is not influenced by the addition of reactants, products, or catalysts.
  • The relationship between temperature and K is governed by the Van't Hoff equation:

K = e(-ΔG/RT)

  • ΔG: Gibbs free energy change
  • R: Universal gas constant
  • T: Temperature (in Kelvin)

EXPLANATION:

  • Factors affecting the equilibrium constant:
  • Change of temperature: The equilibrium constant changes because temperature affects ΔG, which directly impacts K.
  • Addition of reactant or product: Adding more reactants or products shifts the equilibrium position but does not alter the value of K.
  • Addition of a catalyst: A catalyst speeds up the attainment of equilibrium but does not change K.
  • In the given question:
  • Option 1 (Addition of reactant): Does not affect K.
  • Option 2 (Change of temperature): Correct answer. Temperature is the only factor that changes the value of K.
  • Option 3 (Addition of a catalyst): Does not affect K.
  • Option 4 (Addition of product): Does not affect K.

Therefore, the correct answer is Option 2: Change of temperature.

99

In a reversible reaction, which one of the following equilibrium constants, k suggests the fastest completion of the reaction?

  1. ((a))

    k=1

  2. ((b))

    k=102

  3. ((c))

    k=10

  4. ((d))

    k=10−2

Show Answer
Answer: ((b))

k=102

CONCEPT:

Equilibrium Constant (K) and Extent of Reaction

  • The equilibrium constant K gives the ratio of the concentrations of products to reactants at equilibrium.
  • If K is much greater than 1, it indicates that the products are highly favored at equilibrium, meaning the reaction proceeds almost completely towards products.
  • If K is close to 1, significant amounts of both reactants and products are present at equilibrium.
  • If K is much less than 1, reactants are favored, and the reaction proceeds very little towards products.
  • However, it is important to note that K indicates the extent of reaction, not the rate. But since the question asks for "fastest completion" in terms of product formation at equilibrium, we interpret it as the reaction that reaches the highest extent towards product formation.

EXPLANATION:

  • k = 1 : Neither reactants nor products are favored. Moderate completion.
  • k = 102 : Products are highly favored. Reaction proceeds almost to completion.
  • k = 10 : Products are favored, but less than when k = 102 .
  • k = 10-2 : Reactants are favored. Very little product formation.

Therefore, k = 102 suggests the reaction proceeds almost completely towards products, indicating the "fastest completion" in the context of product formation.

Therefore, the correct answer is k = 102 .

100

Kp​ and Kc​ are equilibrium constants of a reversible reaction when concentrations are expressed in terms of partial pressure and mole litre-1 respectively. Which one of the following reactions will have Kp​​= Kc​?

  1. ((a))

    PCl5(g)PCl3(g)+Cl2(g)\text{PCl}_5(\text{g}) \rightleftharpoons \text{PCl}_3(\text{g}) + \text{Cl}_2(\text{g} )

  2. ((b))

    N2(g)+3H2(g)2NH3(g)\text{N}_2(\text{g}) + 3\text{H}_2(\text{g}) \rightleftharpoons 2\text{NH}_3(\text{g} )

  3. ((c))

    COCl2(g)CO(g)+Cl2()\text{COCl}_2(\text{g}) \rightleftharpoons \text{CO}(\text{g}) + \text{Cl}_2(\text{g })

  4. ((d))

    H2(g)+I2(g)2HI(g)\text{H}_2(\text{g}) + \text{I}_2(\text{g}) \rightleftharpoons 2\text{HI}(\text{g} )

Show Answer
Answer: ((d))

H2(g)+I2(g)2HI(g)\text{H}_2(\text{g}) + \text{I}_2(\text{g}) \rightleftharpoons 2\text{HI}(\text{g} )

CONCEPT:

Relationship between Kp and Kc

  • The equilibrium constants Kp and Kc are related by the equation:

Kp = Kc(RT)Δn

  • Here:
  • Kp = equilibrium constant in terms of partial pressures
  • Kc = equilibrium constant in terms of concentrations
  • R = universal gas constant
  • T = temperature in kelvin
  • Δn = change in the number of moles of gas between products and reactants
  • If Δn = 0, then Kp = Kc because (RT)Δn = (RT)0 = 1.

EXPLANATION:

    1. PCl5(g) ⇌ PCl3(g) + Cl2(g)
  • Δn = (1 + 1) - 1 = 1 (Kp ≠ Kc)
    1. N2(g) + 3H2(g) ⇌ 2NH3(g)
  • Δn = 2 - (1 + 3) = -2 (Kp ≠ Kc)
    1. COCl2(g) ⇌ CO(g) + Cl2(g)
  • Δn = (1 + 1) - 1 = 1 (Kp ≠ Kc)
    1. H2(g) + I2(g) ⇌ 2HI(g)
  • Δn = 2 - (1 + 1) = 0 (Kp = Kc)

From the calculations, only reaction 4) H2(g) + I2(g) ⇌ 2HI(g) has Δn = 0, which means Kp = Kc.

Therefore, the correct answer is H2(g)+I2(g)2HI(g)\text{H}_2(\text{g}) + \text{I}_2(\text{g}) \rightleftharpoons 2\text{HI}(\text{g} )

101

Formation of ammonia is represented by the following reaction:

N2(g)+3H2(g)2NH3(g)+22.0 kcal\text{N}_2(\text{g}) + 3\text{H}_2(\text{g}) \rightleftharpoons 2\text{NH}_3(\text{g}) + 22.0 \text{ kcal}

Which one of the following conditions is most favourable for the formation of ammonia?

  1. ((a))

    Increase of temperature

  2. ((b))

    Increase of temperature and decrease of pressure

  3. ((c))

    Decrease of temperature and increase of pressure

  4. ((d))

    Decrease of pressure

Show Answer
Answer: ((c))

Decrease of temperature and increase of pressure

CONCEPT:

Effect of Temperature and Pressure on Chemical Equilibrium

  • The formation of ammonia is represented by the reaction:

N2(g)+3H2(g)⇌2NH3(g)+22.0 kcalN2(g)+3H2(g)⇌2NH3(g)+22.0 kcal

  • This is an exothermic reaction since heat is released during the formation of ammonia.
  • Le Chatelier's Principle states that if a system at equilibrium is subjected to a change in temperature, pressure, or concentration, the system will adjust itself to counteract that change and restore equilibrium.
  • According to Le Chatelier's Principle:
  • For an exothermic reaction, lowering the temperature favors the formation of products (ammonia in this case).
  • For reactions where there is a decrease in the number of moles of gas, increasing the pressure favors the formation of products. Here, 4 moles of reactants (1 mole of N2 + 3 moles of H2) form 2 moles of NH3, so an increase in pressure will favor ammonia formation.

EXPLANATION:

  • In the given reaction:

N2(g)+3H2(g)⇌2NH3(g)+22.0 kcalN2(g)+3H2(g)⇌2NH3(g)+22.0 kcal

  • To maximize the formation of ammonia:
  • We must decrease the temperature since the reaction is exothermic. Lowering the temperature will shift the equilibrium toward the products (ammonia).
  • We must increase the pressure since fewer gas molecules are present on the product side. Higher pressure favors the side with fewer gas molecules.
  • Option 3, "Decrease of temperature and increase of pressure," satisfies both these conditions and is the most favorable for ammonia formation.

Therefore, the correct answer is Option 3: Decrease of temperature and increase of pressure.

102

Which one of the following is not correctly matched?

  1. ((a))

    CP:(HT)PC_P : \left(\frac{\partial H}{\partial T}\right)_P

  2. ((b))

    ΔH:PΔV+ΔE\Delta H : P\Delta V + \Delta E

  3. ((c))

    CPCV:V(PT)VC_P - C_V : V\left(\frac{\partial P}{\partial T}\right)_V

  4. ((d))

    CVdT:dEC_V dT : dE

Show Answer
Answer: ((c))

CPCV:V(PT)VC_P - C_V : V\left(\frac{\partial P}{\partial T}\right)_V

CONCEPT:

Heat Capacity and Thermodynamic Relations

  • Heat capacity at constant pressure:

CP = (∂H/∂T)P

  • Heat capacity at constant volume:

CV = (∂E/∂T)V

  • Enthalpy is defined as:

H = E + PV

  • For a constant pressure process:

ΔH = ΔE + PΔV

  • The general thermodynamic relation between heat capacities is:

CP − CV = T (∂P/∂T)V (∂V/∂T)P

EXPLANATION:

  • CP = (∂H/∂T)P

This is the correct definition of heat capacity at constant pressure.

  • ΔH = PΔV + ΔE

Since H = E + PV, at constant pressure:

ΔH = ΔE + PΔV

Hence, this relation is correct.

  • CP − CV = V (∂P/∂T)V

This is incorrect. The correct relation is:

CP − CV = T (∂P/∂T)V (∂V/∂T)P

For an ideal gas:

CP − CV = R

Therefore, the given matching in option 3 is wrong.

  • CVdT = dE

Since CV = (∂E/∂T)V, at constant volume:

dE = CVdT

Hence, this is correct.

Therefore, the incorrectly matched option is CPCV:V(PT)VC_P - C_V : V\left(\frac{\partial P}{\partial T}\right)_V

103

Which one of the following is correct?

  1. ((a))

    Enthalpy is an intensive property.

  2. ((b))

    Enthalpy of reaction is negative for an endothermic reaction.

  3. ((c))

    Internal energy is a function of state.

  4. ((d))

    Enthalpy of reaction is zero for an exothermic reaction.

Show Answer
Answer: ((c))

Internal energy is a function of state.

CONCEPT:

Enthalpy and Internal Energy

  • Enthalpy (H) is a thermodynamic property that is defined as the sum of the internal energy (U) of a system and the product of its pressure (P) and volume (V):

H = U + PV

  • Intensive vs. Extensive Properties:
  • Intensive properties do not depend on the amount of matter in the system (e.g., temperature, pressure).
  • Extensive properties depend on the amount of matter (e.g., enthalpy, internal energy).
  • Internal Energy: Internal energy is a state function, meaning it depends only on the state of the system and not on how it got there.
  • Endothermic vs. Exothermic Reactions:
  • In an endothermic reaction, the system absorbs heat, and the enthalpy of the reaction is positive (ΔH > 0).
  • In an exothermic reaction, the system releases heat, and the enthalpy of the reaction is negative (ΔH < 0).

EXPLANATION:

  • "Enthalpy is an intensive property."
  • This statement is incorrect because enthalpy is an extensive property, as it depends on the amount of substance in the system.
  • "Enthalpy of reaction is negative for an endothermic reaction."
  • This statement is incorrect. For an endothermic reaction, the enthalpy change (ΔH) is positive, as heat is absorbed by the system.
  • "Internal energy is a function of state."
  • This statement is correct. Internal energy (U) is a state function because it depends only on the current state of the system and not on the path taken to reach that state.
  • Option 4: "Enthalpy of reaction is zero for an exothermic reaction."
  • This statement is incorrect because, in an exothermic reaction, the enthalpy change (ΔH) is negative as heat is released by the system.

Therefore, the correct answer is Option 3: "Internal energy is a function of state."

104

A heat engine is operating between temperatures 500 K and 400 K. What is the efficiency of the engine?

  1. ((a))

    0.20

  2. ((b))

    0.80

  3. ((c))

    1.25

  4. ((d))

    0.50

Show Answer
Answer: ((a))

0.20

CONCEPT:

Efficiency of a Heat Engine

  • The efficiency of a heat engine is the ratio of the work output to the heat input. It is given by the formula:

Efficiency (η) = 1 - (Tcold / Thot)

  • Here, Thot is the temperature of the hot reservoir, and Tcold is the temperature of the cold reservoir. Both temperatures must be in Kelvin (K).
  • The efficiency is always a fraction (or percentage) less than 1 (or 100%), as no heat engine can have 100% efficiency due to the second law of thermodynamics.

EXPLANATION:

  • In the given problem:
  • Thot = 500 K
  • Tcold = 400 K
  • Using the efficiency formula:

η = 1 - (Tcold / Thot)

  • Substitute the values:

η = 1 - (400 / 500)

η = 1 - 0.8

η = 0.2

  • Therefore, the efficiency of the engine is 0.2 or 20%.

The correct answer is option 1: 0.2.

105

Consider the following reaction at temperature T:

SO2(g)+12O2(g)SO3(g)\text{SO}_2(\text{g}) + \frac{1}{2}\text{O}_2(\text{g}) \rightarrow \text{SO}_3(\text{g})

What is correct relationship between change in enthalpy, ΔH and change in internal energy, ΔE for this reaction?

  1. ((a))

    ΔH=ΔERT\Delta H = \Delta E - RT

  2. ((b))

    ΔH=ΔE+RT\Delta H = \Delta E + RT

  3. ((c))

    ΔH=ΔE+12RT\Delta H = \Delta E + \frac{1}{2} RT

  4. ((d))

    ΔH=ΔE12RT\Delta H = \Delta E - \frac{1}{2} RT

Show Answer
Answer: ((d))

ΔH=ΔE12RT\Delta H = \Delta E - \frac{1}{2} RT

CONCEPT:

Relationship between Enthalpy (ΔH) and Internal Energy (ΔE)

  • The change in enthalpy (ΔH) and the change in internal energy (ΔE) are related by the equation:

ΔH = ΔE + ΔngRT

  • Here:
  • Δng = Change in the number of moles of gaseous species during the reaction.
  • R = Universal gas constant.
  • T = Temperature at which the reaction occurs.

EXPLANATION:

  • In the given reaction:

SO2(g) + 1/2 O2(g) → SO3(g)

  • Reactants: 1 mole of SO2 (g) and 0.5 moles of O2 (g) = Total 1.5 moles of gas.
  • Products: 1 mole of SO3 (g).
  • Change in the number of moles of gas (Δng):

Δng = Moles of products - Moles of reactants

Δng = 1 - 1.5 = -0.5

  • Using the relationship:

ΔH = ΔE + ΔngRT

ΔH = ΔE + (-0.5)RT

ΔH = ΔE - 0.5RT

Therefore, the correct relationship is ΔH = ΔE - 0.5RT

106

Consider the following statements for Gibbs-Helmholtz equations:

  1. It is applicable for a closed system.
  2. It relates change in free energy and entropy.

Select the correct answer from the codes given below.

  1. ((a))

    1 is correct but 2 is false

  2. ((b))

     1 is false but 2 is correct

  3. ((c))

    Both 1 and 2 are correct

  4. ((d))

    Both 1 and 2 are false

Show Answer
Answer: ((a))

1 is correct but 2 is false

CONCEPT:

Gibbs-Helmholtz Equation

  • The Gibbs-Helmholtz equation is used to relate the change in Gibbs free energy (ΔG) to the change in enthalpy (ΔH) and entropy (ΔS).
  • It is expressed as:

ΔG = ΔH - TΔS

where T is the absolute temperature in Kelvin.

  • This equation is applicable to closed systems where no matter is exchanged with the surroundings.

EXPLANATION:

  • Statement 1: It is applicable for a closed system.
  • This is correct because the Gibbs-Helmholtz equation assumes a closed system where energy exchanges, but no matter exchanges, take place.
  • Statement 2: It relates change in free energy and entropy.
  • This is incorrect because the equation not only relates Gibbs free energy (ΔG) and entropy (ΔS) but also includes enthalpy (ΔH) and temperature (T).

Correct Answer: Option 1 (1 is correct but 2 is false).

107

Which one of the following species/compounds will be formed on heating CHCl3​ with alc.KOH?

  1. ((a))

  2. ((b))

  3. ((c))

  4. ((d))

Show Answer
Answer: ((b))

CONCEPT:

Reaction of CHCl3 with alcoholic KOH

  • When chloroform (CHCl3) is heated with alcoholic potassium hydroxide (alc. KOH), a base-induced dehydrohalogenation reaction occurs.
  • This reaction leads to the formation of a highly reactive intermediate known as dichlorocarbene (:CCl2).
  • Dichlorocarbene is an example of a carbenic intermediate, which is neutral and contains a divalent carbon atom with two non-bonding electrons.

EXPLANATION:

  • The reaction mechanism involves the following steps:
  • Alcoholic KOH first abstracts a proton (H+) from CHCl3, forming the trichloromethyl anion (CCl3-).
  • The trichloromethyl anion then loses a chloride ion (Cl-) to form the dichlorocarbene intermediate (:CCl2).

The overall reaction is:

CHCl3 + alc. KOH → :CCl2 + KCl + H2O

  • When chloroform (CHCl3) is heated with alcoholic KOH:
  • The product formed is dichlorocarbene (:CCl2).
  • Dichlorocarbene is highly reactive and can participate in further reactions, such as cyclopropanation of alkenes.

Therefore, the correct answer is option 1.

108

In which one of the following compounds, the C—Cl bond dissociation energy will be the least?

  1. ((a))

  2. ((b))

  3. ((c))

  4. ((d))

Show Answer
Answer: ((b))

CONCEPT:

Bond Dissociation and Carbocation Stability

  • When a C–Cl bond breaks heterolytically, a carbocation forms. The stability of this carbocation largely determines how easily the bond breaks.
  • More stable carbocations require less energy for formation, meaning lower bond dissociation energy (BDE).
  • Stability order of carbocations:

 3° (tertiary) > 2° (secondary) > Allylic ≈ Benzylic >1° (primary) > Vinyl / Aryl

EXPLANATION:

  • (Chlorobenzene):
  • If the C–Cl bond breaks, it would form an aryl carbocation (which is highly unstable due to lack of resonance stabilization on the positively charged carbon). Very high BDE.
  • (Tertiary alkyl chloride):
  • Forms a tertiary carbocation, which is relatively stable due to inductive and hyperconjugation effects.
  • (Allyl chloride):
  • Forms an allylic carbocation, which is highly stabilized by resonance. This stabilization lowers the bond dissociation energy the most.
  • (Vinyl chloride):
  • Forms a vinyl carbocation, which is very unstable due to sp2 hybridization and no resonance stabilization. Very high BDE.

Therefore, the C–Cl bond in (Tertiary alkyl chloride.

109

Which one of the following is the most stable carbocation?

  1. ((a))

  2. ((b))

  3. ((c))

  4. ((d))

Show Answer
Answer: ((a))

CONCEPT:

Stability of Carbocations

  • Carbocations are positively charged carbon species, and their stability depends on the ability to delocalize the positive charge.
  • The factors influencing carbocation stability include:
  • Resonance: Carbocations stabilized by resonance are more stable because the positive charge is delocalized over multiple atoms.
  • Hyperconjugation: The overlap of adjacent C-H sigma bonds with the empty p-orbital of the carbocation helps stabilize it.
  • Inductive Effect: Electron-donating groups (e.g., alkyl groups) stabilize carbocations by reducing the electron deficiency.
  • Hybridization: A carbocation with an sp2 hybridized carbon is more stable than one with an sp hybridized carbon.
  • Carbocations are positively charged species where the positive charge is located on a carbon atom. Their stability depends on the ability to delocalize the positive charge or on the electron-donating or withdrawing groups attached to the carbon center.
  • The order of carbocation stability is as follows:
  • Ter­tiary > Secondary > Primary > Methyl
  • Electron-donating groups (like alkyl groups) stabilize carbocations, while electron-withdrawing groups (like NO2, Cl, OH) destabilize them.

EXPLANATION:

  • Among the given carbocations, the one in option 1 (with a CH3 group) is the most stable because methyl groups are electron-donating and stabilize the positive charge on the carbocation. This is better than the one with a NO2 group, which is an electron-withdrawing group, making the carbocation less stable.
  • Therefore, the carbocation with the CH3 group is the most stable because electron-donating groups help in stabilizing the positive charge.

Therefore, the most stable carbocation is the one in Option 1.

110

Consider the following statements about resonance:

  1. Resonating structures differ only in arrangement of electrons.
  2. All atoms participating in resonance lie in the same plane.
  3. Resonance hybrid is less stable than the contributing structures.

Select the correct answer from the codes given below.

  1. ((a))

    Only 1 and 3 are correct

  2. ((b))

    Only 2 and 3 are correct

  3. ((c))

    Only 1 and 2 are correct

  4. ((d))

    1, 2 and 3 are correct

Show Answer
Answer: ((c))

Only 1 and 2 are correct

CONCEPT:

Resonance

  • Resonance occurs in molecules where the electrons are delocalized, resulting in multiple possible structures, called resonating structures.
  • Resonating structures differ only in the arrangement of electrons, not in the arrangement of atoms.
  • All atoms participating in resonance are in the same plane to allow for effective delocalization of electrons.
  • The resonance hybrid is the actual structure of the molecule, which is more stable than any of the individual resonating structures due to electron delocalization.

EXPLANATION:

  • Statement 1: Resonating structures differ only in arrangement of electrons - This is correct because resonance involves delocalization of electrons without changing the positions of atoms.
  • Statement 2: All atoms participating in resonance lie in the same plane - This is correct because resonance requires a planar structure for effective overlap of p-orbitals, enabling electron delocalization.
  • Statement 3: Resonance hybrid is less stable than the contributing structures - This is incorrect because the resonance hybrid is more stable than any individual resonating structure due to the delocalization of electrons, which lowers the overall energy of the molecule.
  • Thus, only Statements 1 and 2 are correct.

Therefore, the correct answer is Option 3: Only 1 and 2 are correct.

111

Which one of the following compounds will not be formed in the given reaction?

  1. ((a))

  2. ((b))

  3. ((c))

  4. ((d))

Show Answer
Answer: ((a))

CONCEPT:

Formation of Compounds in a Reaction

  • In a chemical reaction, the formation of specific compounds depends on the reaction mechanism, the available reactants, and the thermodynamic feasibility of the products.
  • A compound will not be formed if the reaction conditions or the mechanism does not favor its formation.
  • In the given reaction, certain compounds will be formed based on the reactants' properties and the reaction's path, while others may not be feasible.

EXPLANATION:

Therefore, the correct answer is Option 1, as the compound corresponding to this option will not be formed in the given reaction.

112

Which one of the following compounds will be the most reactive in SN 1 reaction?

  1. ((a))

  2. ((b))

  3. ((c))

  4. ((d))

Show Answer
Answer: ((c))

CONCEPT:

Reactivity in SN1 Reaction

  • In an SN1 reaction, the rate-determining step is the formation of the carbocation intermediate.
  • The reactivity of the compound depends on:
  • Carbocation stability: More stable carbocations form faster.
  • Leaving group ability: Better leaving groups (I- > Cl-) facilitate carbocation formation.
  • Electron-donating groups (such as oxygen) stabilize adjacent carbocations through the +M (mesomeric) effect.

EXPLANATION:

  • Option 1: Contains a Cl leaving group and oxygen adjacent to the carbocation, providing +M stabilization. However, Cl is a poorer leaving group than I.
  • Option 2: Also has a Cl leaving group, but the oxygen is further from the carbocation, reducing stabilization. Reactivity is lower than Option 1.
  • Option 3: Has a better leaving group (I-), but the carbocation lacks adjacent stabilization. Reactivity is moderate.
  • Option 4: Contains the best leaving group (I-) and oxygen directly adjacent to the carbocation, stabilizing it through +M effect. This makes the carbocation highly stable and the compound most reactive in SN1.

Therefore, the correct answer is Option 3 because it has both.

113

Consider the following statements about SN 2 reactions:

  1. They are bimolecular reactions.
  2. They proceed with inversion of configuration. complete
  3. They involve the formation of an intermediate.
  4. No rearrangement is involved in them.

Select the correct answer from the codes given below.

  1. ((a))

    Only 1, 2 and 3 are correct

  2. ((b))

    Only 2, 3 and 4 are correct

  3. ((c))

    Only 1, 3 and 4 are correct

  4. ((d))

    Only 1, 2 and 4 are correct

Show Answer
Answer: ((d))

Only 1, 2 and 4 are correct

CONCEPT:

SN2 Reaction

  • SN2 reactions are bimolecular nucleophilic substitution reactions.
  • They follow a one-step mechanism where the nucleophile attacks the substrate and the leaving group departs simultaneously.
  • The reaction leads to inversion of configuration, known as the "Walden inversion."
  • No rearrangements occur in SN2 reactions because there is no carbocation intermediate involved.

EXPLANATION:

SN2 Reaction: Know Description ...

  • Statement 1: "They are bimolecular reactions."
  • Correct. SN2 reactions involve two species (nucleophile and substrate) participating in the rate-determining step.
  • Statement 2: "They proceed with inversion of configuration."
  • Correct. The backside attack by the nucleophile causes inversion of the stereochemistry of the product.
  • Statement 3: "They involve the formation of an intermediate."
  • Incorrect. SN2 reactions do not involve the formation of a carbocation or any other intermediate; the reaction proceeds in a single concerted step.
  • Statement 4: "No rearrangement is involved in them."
  • Correct. Since SN2 reactions lack a carbocation intermediate, rearrangements do not occur.

The correct option is 4, "Only 1, 2 and 4 are correct."

114

The correct name of the reaction

is

  1. ((a))

    Knoevenagel reaction

  2. ((b))

    Wittig reaction

  3. ((c))

    Aldol condensation

  4. ((d))

    Cannizzaro reaction

Show Answer
Answer: ((a))

Knoevenagel reaction

CONCEPT:

Knoevenagel Reaction

  • The Knoevenagel reaction is a base-catalyzed condensation reaction between an aldehyde (or ketone) and a compound containing an active methylene group (such as diethyl malonate).
  • It typically results in the formation of an α,β-unsaturated compound through the elimination of water.
  • In this reaction, the base deprotonates the methylene group, forming a carbanion, which then attacks the carbonyl carbon of the aldehyde.

Cinnamic Acid Formula: Know Its ...

EXPLANATION:

  • In the given reaction, benzaldehyde (C6H5CHO) reacts with diethyl malonate (CH2(COOC2H5)2) in the presence of a base.
  • The reaction forms an α,β-unsaturated diester as the product, which is a characteristic product of the Knoevenagel condensation.
  • The other options are incorrect:
  • Wittig reaction: Forms alkenes using phosphonium ylides, not applicable here.
  • Wittig Reaction: Know Definition ...
  • Aldol condensation: Involves carbonyl compounds reacting with each other, not an active methylene compound.
  • Aldol Condensation: Learn Definition ...
  • Cannizzaro reaction: Occurs in aldehydes without alpha hydrogens and involves oxidation-reduction, not observed here.
  • Cannizzaro Reaction Mechanism: Learn ...

Therefore, the correct answer is Option 1: Knoevenagel reaction.

115

Which one of the following ylides will be the least reactive for nucleophilic addition to >C=O group?

  1. ((a))

  2. ((b))

  3. ((c))

  4. ((d))

Show Answer
Answer: ((d))

CONCEPT:

Reactivity of Phosphonium Ylides in Nucleophilic Addition to Carbonyl Compounds

  • Phosphonium ylides (Wittig reagents) react with carbonyl groups (>C=O) to form alkenes in the Wittig reaction.
  • The reactivity of the ylide depends on the stability of the ylide:
  • Unstabilized ylides (without electron-withdrawing groups) are more reactive.
  • Stabilized ylides (containing electron-withdrawing groups like esters, ketones) are less reactive because they are resonance-stabilized and less nucleophilic.

EXPLANATION:

  • Option 1: Ph3P=CH2 — Simple ylide, highly reactive, no stabilization.
  • Option 2: Ph3P=CH–CH3 — Alkyl-substituted ylide, still fairly reactive.
  • Option 3: Ph3P=CH–CH2–CH3 — Slightly bulkier alkyl group, but still reactive.
  • Option 4: Ph3P=CH–COOC2H5 — Strongly stabilized ylide due to the electron-withdrawing ester group (–COOC2H5), making it the least reactive.
  • Electron-withdrawing groups stabilize the negative charge on the ylide carbon through resonance, lowering its nucleophilicity.

Therefore, the least reactive ylide is option 4) Ph3P=CH–COOC2H5.

116

CΘN is a specific catalyst for benzoin condensation, because 

  1. it is a nucleophile
  2. its electron-withdrawing ability facilitates loss hydrogen of aldehydic
  3. it is a good leaving group
  4. it is a strong base

Select the correct answer from the codes given below.

  1. ((a))

    1, 2, 3 and 4 are true

  2. ((b))

    Only 1, 2 and 3 are true

  3. ((c))

    Only 1, 3 and 4 are true

  4. ((d))

    Only 2, 3 and 4 are true

Show Answer
Answer: ((b))

Only 1, 2 and 3 are true

CONCEPT:

Benzoin Condensation and Role of Catalyst

  • Benzoin condensation is a reaction where two aldehydes combine in the presence of a catalyst to form an α-hydroxy ketone (benzoin).
  • The catalyst facilitates the reaction by stabilizing intermediates and promoting nucleophilic attack.

EXPLANATION:

Benzoin Condensation: Definition ...

  • CΘN (Cyanide Ion) acts as a specific catalyst for benzoin condensation due to the following reasons:
  • 1. It is a nucleophile: Cyanide ion can attack the carbonyl carbon of the aldehyde, initiating the reaction.
  • 2. Its electron-withdrawing ability facilitates the loss of hydrogen from the aldehydic group: The cyanide ion stabilizes the intermediate by pulling electron density, making the hydrogen more acidic and easier to lose.
  • 3. It is a good leaving group: After the reaction progresses, cyanide can detach easily from the intermediate, allowing the reaction to proceed to completion.
  • 4. It is not a strong base: Cyanide ion is not highly basic, which ensures that it doesn’t hinder the reaction by side reactions.
  • Based on the above points, all four statements (1, 2, 3,) are true.

Therefore, the correct answer is 1, 2, 3 are true.

117

Consider the following Assertion (A) and Reason (R):

Assertion (A):

All aldehydes undergo Aldol condensation.

Reason (R):

a-hydrogens acidic. on aldehydes are

Select the correct answer from the codes given below.

  1. ((a))

    Both A and R are true and R is the correct explanation of A.

  2. ((b))

    Both A and R are true but R is not the correct explanation of A.

  3. ((c))

    A is true but R is false.

  4. ((d))

    A is false but R is true.

Show Answer
Answer: ((d))

A is false but R is true.

CONCEPT:

Aldol Condensation and the Role of α-Hydrogens

  • Aldol condensation occurs when an aldehyde or ketone contains at least one α-hydrogen atom (hydrogen atom on the carbon adjacent to the carbonyl group).
  • The α-hydrogen is slightly acidic due to resonance stabilization of the enolate ion formed during the reaction mechanism.
  • Thus, aldehydes with α-hydrogens undergo aldol condensation in the presence of a base or acid.

Aldol Condensation: Learn Definition ...

  • However, aldehydes without α-hydrogens (e.g., formaldehyde, benzaldehyde) do not undergo aldol condensation. They may undergo other reactions like Cannizzaro reaction.

EXPLANATION:

  • Assertion (A): All aldehydes undergo aldol condensation → This is false because aldehydes lacking α-hydrogens (like formaldehyde) cannot participate in aldol condensation.
  • Reason (R): α-hydrogens on aldehydes are acidic → This is true and explains why aldehydes that do have α-hydrogens undergo aldol condensation.

Therefore, the correct answer is: 4) A is false but R is true.

118

Which one of the following reactions does not result in carbon-carbon bond formation?

  1. ((a))

    Friedel-Crafts reaction

  2. ((b))

    Perkin reaction

  3. ((c))

    Diels-Alder reaction

  4. ((d))

    Hydroboration reaction

Show Answer
Answer: ((d))

Hydroboration reaction

CONCEPT:

Carbon-Carbon Bond Formation

  • A carbon-carbon bond is formed when two carbon atoms are directly connected through a covalent bond in a chemical reaction.
  • Several organic reactions, such as the Friedel-Crafts reaction, Perkin reaction, and Diels-Alder reaction, involve the formation of carbon-carbon bonds.
  • However, not all reactions necessarily lead to carbon-carbon bond formation. Some reactions involve other types of bond formation, like carbon-hydrogen or carbon-heteroatom bonds.

EXPLANATION:

  • Friedel-Crafts Reaction:
  • This reaction is used to form carbon-carbon bonds in aromatic systems by introducing an alkyl or acyl group onto an aromatic ring.
  • For example: C6H6 + RCl → C6H5R (in the presence of AlCl3 catalyst).

Friedel-Crafts Reaction - Definition ...

  • Thus, Friedel-Crafts reaction involves carbon-carbon bond formation.
  • Perkin Reaction:
  • In this reaction, an aromatic aldehyde reacts with an acid anhydride in the presence of a base to form a cinnamic acid derivative.
  • This reaction results in the formation of a new carbon-carbon double bond.

Perkin Reaction Mechanism: Learn ...

  • Hence, Perkin reaction involves carbon-carbon bond formation.
  • Diels-Alder Reaction:
  • This is a [4+2] cycloaddition reaction between a diene and a dienophile, which forms a six-membered ring with new carbon-carbon bonds.
  • For example: 1,3-butadiene + ethene → cyclohexene.
  • Diels Alder Reaction: Know Mechanism ...
  • Thus, Diels-Alder reaction involves carbon-carbon bond formation.
  • Hydroboration Reaction:
  • In this reaction, an alkene reacts with diborane (B2H6) to form an organoborane intermediate, which is then oxidized to form an alcohol.
  • Hydroboration reaction does not involve the formation of a new carbon-carbon bond; instead, it forms carbon-hydrogen and carbon-oxygen bonds.

Hydroboration Oxidation Reaction: Definition, Reagents, Mechanism

  • Hence, hydroboration reaction does not result in carbon-carbon bond formation.

Therefore, the correct answer is Hydroboration reaction.

119

Glucose and fructose form identical osazones, because

  1. ((a))

    they have same molecular formula

  2. ((b))

    they have identical configuration about C3 C4 and C5 atoms

  3. ((c))

     both of them are monosaccharides

  4. ((d))

    aldehydes and ketones react with phenylhydrazine in similar manner

Show Answer
Answer: ((b))

they have identical configuration about C3 C4 and C5 atoms

CONCEPT:

Formation of Osazones

  • Osazones are crystalline derivatives formed when sugars react with excess phenylhydrazine.
  • The reaction involves the carbonyl group of the sugar (aldehyde or ketone) and the adjacent carbon atom.
  • Since the reaction affects only the first two carbon atoms (C1 and C2), the configuration of the remaining carbon atoms (C3, C4, and C5) remains unchanged.
  • As a result, sugars that differ only in their configuration at C1 (epimers) form identical osazones.

EXPLANATION:

Glucose, Mannose and fructose.give identical osazones. Explain

  • Glucose and fructose are structural isomers, with glucose being an aldose (aldehyde group) and fructose being a ketose (ketone group).
  • Despite their structural differences, both glucose and fructose have identical configurations at carbon atoms C3, C4, and C5.
  • When glucose and fructose react with phenylhydrazine, the osazone formation involves only the C1 and C2 atoms, while the remaining structure remains unchanged.
  • Thus, glucose and fructose form identical osazones because their configurations at C3, C4, and C5 are identical.

Therefore, the correct answer is Option 2: They have identical configuration about C3, C4, and C5 atoms.

120

Which one of the following reactions of glucose is not matched correctly?

      Reagent              Product

  1. ((a))

    Bromine water : Gluconic acid

  2. ((b))

    Nitric acid : Glucuronic acid

  3. ((c))

    Sodium borohydride : Sorbito

  4. ((d))

    Conc. HI and  red phosphorus : n-hexane

Show Answer
Answer: ((b))

Nitric acid : Glucuronic acid

CONCEPT:

Reactions of Glucose

  • Glucose is a versatile molecule that undergoes various chemical reactions, producing different products depending on the reagent used.
  • Some common reactions include:
  • Oxidation with bromine water to produce gluconic acid.
  • Oxidation with nitric acid to produce glucaric acid (not glucuronic acid).
  • Reduction with sodium borohydride to produce sorbitol.
  • Reduction with concentrated HI and red phosphorus to produce n-hexane.

EXPLANATION:

  • Let us analyze each reaction mentioned in the options:
  • Option 1: Bromine water oxidizes the aldehyde group (-CHO) in glucose to a carboxylic acid group (-COOH), forming gluconic acid. This reaction is correct.
  • Option 2: Nitric acid oxidizes both the aldehyde group and the primary alcohol group in glucose to carboxylic acid groups, forming glucaric acid (not glucuronic acid). This reaction is incorrectly matched.
  • Option 3: Sodium borohydride reduces the aldehyde group in glucose to a primary alcohol, forming sorbitol. This reaction is correct.
  • Option 4: Concentrated HI and red phosphorus reduce glucose completely to n-hexane. This reaction is correct.
  • Thus, the reaction of glucose with nitric acid producing glucuronic acid is not correctly matched.

Therefore, the correct answer is Option 2.

CONCEPT:

Reactions of Glucose with Different Reagents

  • Bromine water: Oxidizes the aldehyde group (–CHO) of glucose to a carboxylic acid group, forming gluconic acid. ✅

Glucose reacts with bromine water to ...

  • Nitric acid: Oxidizes both the aldehyde and primary alcohol group, forming glucaric acid (not glucuronic acid). Incorrect matching.
  • Glucose is oxidized by nitric acid and ...
  • Sodium borohydride: Reduces the aldehyde group of glucose to a primary alcohol, forming sorbitol (a sugar alcohol).

Sodium Borohydride (NaBH4) As A Reagent ...

  • Conc. HI and red phosphorus: Completely reduces glucose to an alkane, forming n-hexane

reduced with HI and Red Phosphorus gives

EXPLANATION:

  • The incorrect matching is Nitric acid : Glucuronic acid. Nitric acid oxidizes both ends of the glucose molecule to give glucaric acid (not glucuronic acid).
  • Glucuronic acid is formed by the selective oxidation of the primary alcohol group on C6, not by nitric acid but typically by enzymatic or mild chemical oxidation.

Therefore, the correct answer is: 2) Nitric acid : Glucuronic acid.

121

Identify the polymer whose structural segment is given below:

  1. ((a))

    Nylon 44

  2. ((b))

    Nylon 4

  3. ((c))

    Nylon 6

  4. ((d))

    Dacron

Show Answer
Answer: ((a))

Nylon 44

CONCEPT:

Polymers and their structural segments

  • Polymers are large molecules formed by the repeated linking of smaller units called monomers.
  • Different types of polymers have distinct structural segments depending on the monomers used and the polymerization process.
  • Nylon is a synthetic polymer and belongs to the family of polyamides. It is formed by condensation reactions between diamines and dicarboxylic acids.
  • Nylon types are named based on the number of carbon atoms in the diamine and dicarboxylic acid used in the polymerization.

EXPLANATION:

  • Nylon 44 is synthesized from tetramethylenediamine (a diamine with 4 carbon atoms) and adipic acid (a dicarboxylic acid with 4 carbon atoms).
  • The "44" in Nylon 44 refers to the number of carbon atoms in the diamine and dicarboxylic acid used in its formation.

  • Nylon 4: This polymer is formed using monomers with 4 carbon atoms but does not match the given segment.
  • Nylon 6: This polymer is formed using caprolactam, which contains 6 carbon atoms, and does not match the given segment.
  • Dacron: Dacron is a polyester and is chemically different from Nylon polyamides.

  • Therefore, the structural segment given matches the composition of Nylon 44.

The correct answer is Nylon 44.

122

Match List-I with List-II and select the correct answer from the codes given below the Lists:

List-1 (Polymer)List-II (Monomer/s)
A. Natural rubber1.
B. Orlon2.
C. Teflon3.
D. Terrylene4.
  1. ((a))

    A1, B2, C3, D4

  2. ((b))

    A3, B4, C2, D1

  3. ((c))

    A2, B3, C4, D1

  4. ((d))

    A4, B1, C2, D3

Show Answer
Answer: ((b))

A3, B4, C2, D1

CONCEPT:

Polymers and Monomers

  • A polymer is a large molecule composed of repeating structural units (monomers) connected by covalent chemical bonds.
  • Monomers are the building blocks of polymers. Each polymer is made up of specific monomers that undergo polymerization.

EXPLANATION:

  • The question asks to match polymers in List-I with their respective monomers in List-II.
  • Let's analyze each polymer and its corresponding monomer:
  • A. Natural rubber: Its monomer is isoprene (2-methyl-1,3-butadiene).

  • B. Orlon: Its monomer is acrylonitrile (CH2=CH-CN).

  • C. Teflon: Its monomer is tetrafluoroethylene (CF2=CF2).

  • D. Terrylene: Its monomers are terephthalic acid and ethylene glycol.

  • Using this information, the correct matching is:
  • A → 3 (Isoprene)
  • B → 4 (Acrylonitrile)
  • C → 2 (Tetrafluoroethylene)
  • D → 1 (Terephthalic acid and ethylene glycol)
  • Thus, the correct answer is Option 2.

Therefore, A3, B4, C2, D1

123

The absolute configurations of the chiral centre and double bond in

are respectively

  1. ((a))

    R and E

  2. ((b))

    Rand Z

  3. ((c))

    S and E

  4. ((d))

    S and Z

Show Answer
Answer: ((a))

R and E

CONCEPT:

Absolute Configuration of Chiral Centers and Double Bonds

  • Chiral centers and double bonds can be assigned absolute configurations using the Cahn-Ingold-Prelog (CIP) priority rules.
  • For chiral centers:
  • The substituents attached to the chiral center are ranked based on atomic number; higher atomic number gets higher priority.
  • The molecule is oriented so that the lowest priority group is pointing away from the viewer.
  • If the arrangement of the remaining groups in descending priority is clockwise, the configuration is R; if counterclockwise, it is S.
  • For double bonds:
  • The groups attached to each carbon of the double bond are assigned priorities based on atomic number.
  • If the higher priority groups are on opposite sides of the double bond, the configuration is E; if they are on the same side, it is Z.

EXPLANATION:

  • In the given molecule:
  • The chiral center is assigned using the CIP rules. Based on the arrangement of substituents, the configuration is determined to be R.
  • The double bond is analyzed using the CIP rules for the groups attached to each carbon. The higher priority groups are on opposite sides of the bond, so the configuration is E.
  • Thus, the absolute configurations of the chiral center and the double bond are R and E, respectively.

Therefore, the correct answer is R and E.

124

Consider the following statements for geometrical isomerism:

  1. All geometrical isomers have a double bond.
  2. All geometrical isomers are diastereoisomers.
  3. All geometrical isomers have restricted rotation about a bond.
  4. No two substituents on any of the atoms about which there is restricted rotation, should be the same.

Of these, the correct statements are

  1. ((a))

    only 1, 2 and 3

  2. ((b))

    only 1, 2 and 4

  3. ((c))

    only 2, 3 and 4

  4. ((d))

    only 1, 3 and 4

Show Answer
Answer: ((c))

only 2, 3 and 4

CONCEPT:

Geometrical Isomerism

  • Geometrical isomerism arises due to the restricted rotation about a bond, leading to different spatial arrangements of substituents.
  • It is a subtype of stereoisomerism where the arrangement of groups around a double bond or a ring system is different.
  • Geometrical isomers are diastereoisomers, as they are stereoisomers that are not mirror images of each other.
  • For geometrical isomerism to exist:
  • The molecule must have restricted rotation (e.g., a double bond or a ring system).
  • Two substituents on each atom involved in the restricted rotation should not be identical.

EXPLANATION:

  • Statement 1: "All geometrical isomers have a double bond."
  • This statement is incorrect. Geometrical isomerism can also arise in cyclic compounds due to restricted rotation, even without a double bond.
  • Statement 2: "All geometrical isomers are diastereoisomers."
  • This statement is correct because geometrical isomers are stereoisomers that are not mirror images of each other, making them diastereoisomers.
  • Statement 3: "All geometrical isomers have restricted rotation about a bond."
  • This statement is correct because restricted rotation (due to a double bond or a ring system) is a prerequisite for geometrical isomerism.
  • Statement 4: "No two substituents on any of the atoms about which there is restricted rotation, should be the same."
  • This statement is correct because if two substituents on the same atom are identical, it would not lead to different spatial arrangements required for geometrical isomerism.

Therefore, the correct answer is option 3.

125

Arrange the following compounds in order of their decreasing carbon-oxygen double bond stretching frequency:

  1. ((a))

    1 > 2 > 3 > 4

  2. ((b))

    2 > 1 > 3 > 4

  3. ((c))

    3 > 1 > 2 > 4

  4. ((d))

    2 > 1 > 4 > 3

Show Answer
Answer: ((b))

2 > 1 > 3 > 4

CONCEPT:

Carbon-Oxygen Double Bond Stretching Frequency

  • The stretching frequency of a carbon-oxygen (C=O) double bond in infrared (IR) spectroscopy depends on the bond strength and the electronic environment around the bond.
  • Stronger C=O bonds (due to less conjugation, less resonance, or electron-withdrawing groups) have higher stretching frequencies.
  • Weaker C=O bonds (due to more conjugation, resonance, or electron-donating groups) have lower stretching frequencies.

EXPLANATION:

  • Conjugation: Conjugation with a double bond or aromatic ring lowers the stretching frequency due to delocalization of electrons, weakening the C=O bond.
  • Substituents: Electron-withdrawing groups increase the stretching frequency by strengthening the C=O bond, while electron-donating groups decrease it.
    • Compound 1: Likely has the less conjugation or electron-donating effects, leading to the highest frequency.
  • Compound 2: most due to some conjugation or electron-donating effects. EWG by -I effect
  • Compound 3: More conjugation or electron-donating effects, further lowering the frequency.
  • Compound 4: Likely has the least conjugation or electron-donating effects, leading to the lowest frequency.

Therefore, the correct answer is  2 > 1 > 3 > 4

126

Which one of the following does not affect the position of Vmax in IR spectrum?

  1. ((a))

    Hydrogen bond

  2. ((b))

    Inductive and mesomeric effects

  3. ((c))

    Fermi resonance

  4. ((d))

    Doppler effect

Show Answer
Answer: ((d))

Doppler effect

CONCEPT:

Factors Affecting Vmax in IR Spectrum

  • Vmax, or the wavenumber corresponding to the maximum absorption, is influenced by various factors, including molecular interactions and resonance effects.
  • Key factors that affect Vmax include:
  • Hydrogen bonding: Hydrogen bonds can shift the absorption position by altering the bond strength and vibrational frequency.
  • Inductive and mesomeric effects: These electronic effects influence the distribution of electron density, affecting bond strength and hence the IR absorption position.
  • Fermi resonance: This occurs when two vibrational modes of similar energy interact, leading to a shift in the observed absorption frequencies.
  • Other phenomena, like Doppler effects, are unrelated to molecular vibrations and do not impact the position of Vmax in IR spectra.

EXPLANATION:

  • Hydrogen bonding: It directly affects Vmax in the IR spectrum by modifying the bond strength and vibrational frequency, leading to shifts in absorption peaks.
  • Inductive and mesomeric effects: These electronic effects alter the bond strength and are major contributors to shifts in Vmax.
  • Fermi resonance: This interaction between vibrational modes can cause the splitting or shifting of absorption peaks.
  • Doppler effect: This phenomenon is related to relative motion between the light source and observer and is primarily relevant to spectral broadening rather than the position of Vmax. It does not affect molecular vibrations or IR absorption positions.

Correct Answer: Option 4 (Doppler effect)

Therefore, the Doppler effect does not affect the position of Vmax in the IR spectrum.

127

Which one of the following compounds will have λ\lambda max at 273 nm?

  1. ((a))

  2. ((b))

  3. ((c))

  4. ((d))

Show Answer
Answer: ((a))

CONCEPT:

λλ

max (Wavelength of Maximum Absorption)

  • λλ

max of a compound refers to the wavelength at which the compound absorbs the maximum light in a UV-Vis spectrum.

  • The electronic transitions in a molecule, especially the transitions of π-electrons or non-bonding electrons (n), determine the λλ

max value.

  • Conjugation and functional groups significantly affect the λλ

max of a compound. More conjugation generally shifts the λλ

max to a higher wavelength (red shift).

EXPLANATION:

  • To determine which compound has a λλ

max at 273 nm, we need to consider the structure and conjugation of each option.

  • Option 1 has a specific arrangement of conjugated double bonds or functional groups that absorb light at 273 nm.
  • Other options might have either less conjugation (resulting in a lower λλ

max) or different substituents that affect the absorption wavelength.

  • For example:
  • Option 1 might have a benzene ring or a conjugated system that absorbs UV light near 273 nm.
  • Options 2, 3, and 4 might lack sufficient conjugation or have functional groups that shift the λλ

max to a different region.

Therefore, the compound in Option 1 has λλ

max at 273 nm because of its specific conjugation and structure.

128

Which one of the following electronic transitions requires the least energy?

  1. ((a))

    σσ\sigma \rightarrow \sigma^*

  2. ((b))

    nσn \rightarrow \sigma^*

  3. ((c))

    ππ\pi \rightarrow \pi^*

  4. ((d))

    nπn \rightarrow \pi^*

Show Answer
Answer: ((d))

nπn \rightarrow \pi^*

CONCEPT:

Electronic Transitions and Energy Requirements

  • In electronic transitions, electrons move from one molecular orbital to another due to the absorption of energy.
  • The energy required for a transition depends on the energy gap between the molecular orbitals involved.
  • Common electronic transitions in molecules include:
  • σ → σ*: Transition between bonding and antibonding sigma orbitals. This requires the highest energy because sigma bonds are the strongest.
  • n → σ*: Transition from a non-bonding orbital to an antibonding sigma orbital. This requires less energy than σ → σ*.
  • π → π*: Transition between bonding and antibonding pi orbitals. This requires less energy than the above two transitions.
  • n → π*: Transition from a non-bonding orbital to an antibonding pi orbital. This requires the least energy among the listed transitions.

EXPLANATION:

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  • σ → σ* involves the largest energy gap, so it requires the most energy.
  • n → σ* involves a smaller energy gap than σ → σ*, so it requires less energy.
  • π → π* involves an even smaller energy gap than the above two transitions.
  • n → π* involves the smallest energy gap, so it requires the least energy.

Therefore, the electronic transition that requires the least energy is n → π.*

129

EE^\circ values of two half cells are given below:

Fe2+/Fe,E=0.44VFe^{2+}/Fe, E^\circ=-0.44 V

Fe3+/Fe,E=0.036VFe^{3+}/Fe, E^\circ=-0.036 V

The potential of the cell, Fe3++eFe2+Fe^{3+} + e^{-} \rightarrow Fe^{2+}will be

  1. ((a))

    0.476 V

  2. ((b))

    0.404 V

  3. ((c))
    • 0.404 V
  4. ((d))

    0.772 V

Show Answer
Answer: ((d))

0.772 V

CONCEPT:

Relation between Eo and Gibbs Free Energy

  • Electrode potential (Eo) is an intensive property, so it cannot be directly added or subtracted.
  • We must first convert Eo into Gibbs free energy using:

ΔGo = -nFEo

  • After combining reactions using ΔGo, we convert back to Eo using:

Eo = -ΔGo / nF

EXPLANATION:

  • Given half-reactions:
  • Fe2+ + 2e- → Fe     Eo = -0.44 V
  • Fe3+ + 3e- → Fe     Eo = -0.036 V
  • Convert each to ΔGo:
  • ΔGo1 = -2F(-0.44) = +0.88F
  • ΔGo2 = -3F(-0.036) = +0.108F
  • Target reaction:

Fe3+ + e- → Fe2+

  • This is obtained by:

(Fe3+ → Fe) − (Fe2+ → Fe)

  • So,
  • ΔGo = ΔGo2 − ΔGo1
  • = 0.108F − 0.88F
  • = -0.772F
  • Now convert back to Eo:
  • Eo = -ΔGo / nF
  • = -(-0.772F) / (1 × F)
  • = 0.772 V

Therefore, the correct standard potential is 0.772 V.

130

Standard reduction potentials of four elements A, B, C and D are respectively -2.90, +1.50, -0.74 and +0.34 volts. Which one of these is the strongest reducing agent?

  1. ((a))

    A

  2. ((b))

    B

  3. ((c))

    C

  4. ((d))

    D

Show Answer
Answer: ((a))

A

CONCEPT:

Standard Reduction Potential and Reducing Agent

  • Standard reduction potential (Eo) measures the tendency of a chemical species to gain electrons (be reduced).
  • A more negative Eo value indicates a stronger reducing agent because the species is more likely to lose electrons (be oxidized).
  • Reducing agents are substances that donate electrons and are oxidized in the process.

EXPLANATION:

  • Given standard reduction potentials of the elements:
  • EoA = -2.90 V
  • EoB = +1.50 V
  • EoC = -0.74 V
  • EoD = +0.34 V
  • To identify the strongest reducing agent:
  • The strongest reducing agent will have the most negative standard reduction potential because it is more likely to lose electrons and be oxidized.
  • From the given data:
  • EoA = -2.90 V is the most negative value.
  • Therefore, element A is the strongest reducing agent.

Therefore, the correct answer is Option 1: A.

131

Which one of the following cations has the maximum hydration number?

  1. ((a))

    Cs+

  2. ((b))

    K+

  3. ((c))

    Rb+

  4. ((d))

    Li+

Show Answer
Answer: ((d))

Li+

CONCEPT:

Hydration Number

  • Hydration number refers to the number of water molecules that surround a cation in an aqueous solution.
  • The hydration number is influenced by the size and charge density of the cation. Smaller and highly charged cations tend to have a higher hydration number because they have a stronger attraction for water molecules.
  • Charge density is calculated as the ratio of charge to ionic radius. Higher charge density leads to a higher hydration number.

EXPLANATION:

  • Li+ is the smallest and most highly charged among the alkali metals (with charge density). Its smaller size allows it to attract more water molecules, giving it a higher hydration number compared to other alkali metal cations like K+, Rb+, and Cs+.
  • Cs+ is highly charged and has a small ionic radius, which suggests that it would have a very high hydration number, possibly the highest among the listed options.
  • K+ and Rb+ have much larger ionic radii and thus lower charge densities, leading to fewer water molecules being associated with them compared to Li+.
  • Thus, the cation with the maximum hydration number is Li+ (option 4).

Therefore, the cation with the maximum hydration number is Li+.

132

Among the following, which one has the maximum lattice energy?

  1. ((a))

    BaF2​

  2. ((b))

    BaCl2​

  3. ((c))

    BaBr2​

  4. ((d))

    BaI2​

Show Answer
Answer: ((a))

BaF2​

CONCEPT:

Lattice Energy

  • Lattice energy is the energy released when one mole of an ionic compound forms from its gaseous ions.
  • The lattice energy depends on two key factors:
  • Charge of ions: Higher charges result in stronger electrostatic attraction and higher lattice energy.
  • Size of ions: Smaller ions lead to shorter interionic distances, increasing the electrostatic force and lattice energy.
  • Lattice energy decreases as the size of the anion increases because larger anions create longer interionic distances, reducing the electrostatic attraction.

EXPLANATION:

  • In the given options:
  • BaF2, BaCl2, BaBr2, and BaI2 are ionic compounds of barium with halide anions (F-, Cl-, Br-, I-).
  • The cation (Ba2+) is the same in all compounds, so the difference in lattice energy arises from the size of the anion.
  • The sizes of the halide anions increase in the order: F- < Cl- < Br- < I-.
  • Smaller anions, like F-, result in shorter interionic distances and stronger electrostatic attraction, leading to higher lattice energy.
  • Therefore, among the given options, BaF2 has the highest lattice energy due to the smallest anion (F-).

Correct Answer: Option 1 (BaF2).

133

Which one of the following cations has the maximum ionic mobility?

  1. ((a))

    Ba2+

  2. ((b))

    Ca2+

  3. ((c))

    Sr2+

  4. ((d))

    Be2+

Show Answer
Answer: ((a))

Ba2+

CONCEPT:

Ionic Mobility

  • Ionic mobility refers to the ability of an ion to move through a solution under the influence of an electric field.
  • It depends on several factors, including the size of the ion, its charge density, and the ease with which it can move through the solvent.
  • Smaller ions with higher charge densities tend to have lower ionic mobilities due to stronger interactions with the solvent molecules, which result in the formation of a larger hydration shell.

EXPLANATION:

  • The given options are divalent cations: Ba2+, Ca2+, Sr2+, Be2+.
  • Among these cations, Ba2+ is the largest in size, while Be2+ is the smallest.
  • Smaller ions (like Be2+) have high charge density, which leads to strong interactions with water molecules in the solution and the formation of a larger hydration shell.
  • A larger hydration shell reduces the mobility of the ion because the effective size of the hydrated ion becomes much larger.
  • On the other hand, larger ions (like Ba2+) have lower charge density and weaker interactions with the solvent, resulting in a smaller hydration shell and higher ionic mobility.
  • Therefore, Ba2+ has the maximum ionic mobility among the given cations.

The correct Answer is Ba2+

134

Which one of the following oxides is most basic?

  1. ((a))

    Sb2​O3​

  2. ((b))

    Bi2​O3​

  3. ((c))

    SeO2​

  4. ((d))

    Al2​O3​

Show Answer
Answer: ((b))

Bi2​O3​

CONCEPT:

Basicity of Oxides

  • The basicity of oxides depends on the electronegativity of the element and the nature of the oxide.
  • Oxides of metals generally tend to be basic, whereas oxides of non-metals tend to be acidic.
  • The basic nature of an oxide increases as we move down a group in the periodic table, because the metallic character increases.
  • The basicity of an oxide also increases as the oxidation state of the metal decreases. Lower oxidation states tend to form more basic oxides.

EXPLANATION:

    • Sb2O3 (Antimony(III) oxide): Antimony is a post-transition metal, and the oxide is moderately basic.
  • Bi2O3 (Bismuth(III) oxide): Bismuth is a heavier post-transition metal, and its oxide is also basic but less so compared to Sb2O3.
  • SeO2 (Selenium dioxide): Selenium is a non-metal, and its oxide is acidic in nature.
  • Al2O3 (Aluminum oxide): Aluminum is a metal, and its oxide is amphoteric, meaning it can act both as an acid and as a base depending on the conditions.
  • Among the given oxides, Bi2O3 is most basic, as it is from a metal with a lower oxidation state and is less acidic or amphoteric compared to the others.

Therefore, Bi2O3 is the most basic oxide among the given options.

135

Which one of the following anions is least stable?

  1. ((a))

    Be

  2. ((b))

    Li

  3. ((c))

    B

  4. ((d))

    C

Show Answer
Answer: ((a))

Be

CONCEPT:

Stability of Anions

  • The stability of anions depends on various factors, including:
  • The electronegativity of the atom carrying the negative charge.
  • The ability of the atom to delocalize the negative charge (resonance effects).
  • The size of the atom: Larger atoms can better accommodate negative charge due to lower charge density.
  • Electronegativity is a key factor because more electronegative atoms are better able to stabilize negative charges.
  • In this case, we compare the stability of the anions: Be⊖, Li⊖, B⊖, and C⊖.

EXPLANATION:

  • Be (Beryllium) is the least electronegative element among the given options. It has the lowest ability to stabilize a negative charge.
  • Be⊖: Neutral Beryllium (Be) has atomic number 4 with configuration 1s^2 2s^2.
  • As Be⊖: 1s^2 2s^2 2p^1.
  • The additional electron enters the 2p orbital. Beryllium has a low electron affinity and does not stabilize the extra electron well
  • Li (Lithium) is slightly more electronegative than Be, so the Li⊖ anion is slightly more stable than Be⊖.
  • B (Boron) is more electronegative than both Be and Li, so the B⊖ anion is more stable than Be⊖ and Li⊖.
  • C (Carbon) is the most electronegative among the given options, so the C⊖ anion is the most stable of all.
  • As a result, the Be⊖ anion is the least stable because Beryllium is the least electronegative and the least able to stabilize the negative charge.

Therefore, Be⊖ (Beryllium) is the least stable anion due to its low electron affinity and high-energy 2p electron configuration.

136

The total number of lone pairs of electrons in XeO4​ is

  1. ((a))

    zero

  2. ((b))

    one

  3. ((c))

    two

  4. ((d))

    three

Show Answer
Answer: ((a))

zero

CONCEPT:

Determination of Lone Pairs in XeO4

  • Xenon (Xe) belongs to group 18 (noble gases) and has 8 valence electrons.
  • In XeO4, xenon forms bonds with 4 oxygen atoms through double bonds.
  • Each oxygen atom contributes 2 electrons to form a double bond with xenon.
  • Since all 8 valence electrons of xenon are involved in bonding, there are no lone pairs remaining on the xenon atom.

EXPLANATION:

  • The molecular structure of XeO4 involves xenon in the center with 4 oxygen atoms forming double bonds around it.
  • Each double bond consists of 4 electrons (2 from xenon and 2 from oxygen).
  • Thus, the total number of electrons used for bonding is 8, which is equal to the valence electrons of xenon.
  • Since all electrons are utilized in bonding, xenon has no lone pairs of electrons in XeO4.

Therefore, the total number of lone pairs of electrons in XeO4 is zero.

137

In which one of the following compounds, all the bonds are not equal?

  1. ((a))

    BF3​

  2. ((b))

    AlF3​

  3. ((c))

    NF3​

  4. ((d))

    ClF3​

Show Answer
Answer: ((d))

ClF3​

CONCEPT:

Bond Equality in Molecules

  • In a molecule, the equality of bonds depends on the symmetry and electronic environment around the atoms.
  • If the molecule has a symmetrical structure and all the atoms around the central atom are identical, the bonds are usually equal.
  • If the molecule has an asymmetrical structure or the surrounding atoms are different, the bonds may not be equal.

EXPLANATION:

  • BF3: Boron trifluoride has a symmetrical trigonal planar structure. All the bonds in BF3 are equal because the fluorine atoms are identical and the electronic environment is the same.

  • AlF3: Aluminum trifluoride also has a symmetrical trigonal planar structure. All the bonds in AlF3 are equal for the same reasons as BF3.

  • NF3: Nitrogen trifluoride has a pyramidal structure due to the lone pair on nitrogen. However, all the bonds between nitrogen and fluorine are equal because the fluorine atoms are identical.
  • ClF3: Chlorine trifluoride has a T-shaped structure due to the presence of lone pairs on chlorine. In this molecule, the bonds are not equal because the fluorine atoms occupy different positions relative to the lone pairs, creating an asymmetrical electronic environment.

  • Therefore, in the given compounds, ClF3 is the one where not all bonds are equal.

Correct Answer: Option 4 (ClF3)

138

Which of the following compounds/species have undistorted octahedral structure?

  1. SF6​
  2. PF6
  3. SiF6​
  4. XeF6​

​Select the correct answer from the codes given below.

  1. ((a))

    2, 3 and 4

  2. ((b))

    1, 3 and 4

  3. ((c))

    2 and 3

  4. ((d))

    1, 2 and 3

Show Answer
Answer: ((d))

1, 2 and 3

CONCEPT:

Undistorted Octahedral Structure

  • Octahedral geometry is observed when a central atom is surrounded by six ligands arranged symmetrically around it at 90-degree bond angles.
  • An undistorted octahedral structure occurs if the central atom has no lone pairs and the bonding is not affected by steric or electronic factors.

EXPLANATION:

  • SF6:
  • Sulfur is the central atom, surrounded by six fluorine atoms.
  • Sulfur has no lone pairs, and the geometry is perfectly octahedral.

Sulphur Hexafluoride (SF6) - Properties ...

  • PF6:
  • Phosphorus is the central atom, surrounded by six fluorine atoms.
  • Phosphorus has no lone pairs, and the geometry is undistorted octahedral.

  • SiF6:
  • Silicon is the central atom, surrounded by six fluorine atoms.
  • Silicon has no lone pairs, and the structure is undistorted octahedral.

  • XeF6:
  • Xenon is the central atom, surrounded by six fluorine atoms.
  • Xenon has one lone pair, which causes distortion in the geometry, making it a distorted octahedral structure.

Hybridization of XeF6 (Xenon ...

CONCLUSION:

  • The compounds/species with undistorted octahedral structures are SF6, PF6, and SiF6.
  • XeF6 is excluded due to the distortion caused by the lone pair.

Correct Answer: Option 4 (1, 2 and 3)

139

Which one of the following compounds has a permanent dipole moment?

  1. ((a))

    SiF4​

  2. ((b))

    SF4​

  3. ((c))

    XeF4

  4. ((d))

    BF3

Show Answer
Answer: ((b))

SF4​

CONCEPT:

Dipole Moment

  • A dipole moment arises in a molecule when there is a separation of charge due to the difference in electronegativity of the bonded atoms and an asymmetric geometry.
  • In molecules with a symmetric geometry, the individual bond dipoles cancel out, resulting in no net dipole moment (non-polar molecule).
  • In contrast, an asymmetric geometry can result in a permanent dipole moment if the bond dipoles do not cancel out.

EXPLANATION:

  • SiF4: Silicon tetrafluoride has a symmetric tetrahedral geometry. The bond dipoles cancel out, resulting in no net dipole moment. Non-polar.

  • SF4: Sulfur tetrafluoride has a seesaw geometry due to the presence of a lone pair on sulfur. The bond dipoles do not cancel out, resulting in a permanent dipole moment.

  • XeF4: Xenon tetrafluoride has a square planar geometry with lone pairs on xenon. The bond dipoles cancel out, resulting in no net dipole moment. Non-polar.

  • BF3: Boron trifluoride has a symmetric trigonal planar geometry. The bond dipoles cancel out, resulting in no net dipole moment. Non-polar.

![Solved] Amongst the following compounds ...](https://cdn.testbook.com/images/production/quesImages/qImage687791c28e114c34b0a1c9fa.png)

Correct Answer: The molecule with a permanent dipole moment is SF4 (Option 2).

140

Consider the following Assertion (A) and Reason (R).

Assertion (A): Azimuthal quantum number suggests about the shape of the orbital.

Reason (R): It gives information about spatial distribution of electron cloud about the nucleus.

Select the correct answer from the codes given below.

  1. ((a))

    Both A and R are true and R is the correct explanation of A.

  2. ((b))

    Both A and R are true but R is not the correct explanation of A.

  3. ((c))

    A is true but R is false.

  4. ((d))

    A is false but R is true.

Show Answer
Answer: ((a))

Both A and R are true and R is the correct explanation of A.

CONCEPT:

Azimuthal Quantum Number (l)

  • The azimuthal quantum number is one of the four quantum numbers that describe the unique quantum state of an electron in an atom.
  • It determines the shape of the orbital in which the electron is likely to be found.
  • The azimuthal quantum number is denoted by the letter l.
  • It also gives information about the spatial distribution of the electron cloud around the nucleus, which is related to the shape of the orbital.

EXPLANATION:

  • Assertion (A): Azimuthal quantum number suggests about the shape of the orbital.
  • This is true because the azimuthal quantum number (l) determines the shape of the orbital (e.g., spherical for s-orbitals, dumbbell-shaped for p-orbitals, etc.).
  • Reason (R): It gives information about spatial distribution of electron cloud about the nucleus.
  • This is also true because the azimuthal quantum number (l) provides details on how the electron density is distributed in space, which is closely related to the orbital shape.
  • Both the assertion and reason are correct, and the reason is the correct explanation of the assertion, as the shape of the orbital is determined by the spatial distribution of the electron cloud.

Therefore, the correct answer is option 1: Both A and R are true and R is the correct explanation of A.

141

For the spectrum of H-atom, which of the following statements is/are correct?

  1. When electron returns to the ground state from higher energy levels, Lyman series is obtained.
  2. The wavelengths of spectral lines of Lyman series are in ultra-violet region. Select the correct answer from the codes given below.
  1. ((a))

    Both 1 and 2

  2. ((b))

    Neither 1 nor 2

  3. ((c))

    Only 1

  4. ((d))

    Only 2

Show Answer
Answer: ((a))

Both 1 and 2

CONCEPT:

Hydrogen Atom Spectrum and Lyman Series

  • When electrons in a hydrogen atom transition from higher energy levels (n > 1) to the ground state (n = 1), they emit energy in the form of light. These transitions correspond to the Lyman series.
  • The Lyman series involves electronic transitions to the first energy level (n = 1).
  • The wavelengths of the Lyman series fall in the ultraviolet (UV) region of the electromagnetic spectrum.

EXPLANATION:

  • Statement 1: "When electron returns to the ground state from higher energy levels, Lyman series is obtained."
  • This is correct. The Lyman series includes all transitions to n = 1.
  • Statement 2: "The wavelengths of spectral lines of Lyman series are in ultra-violet region."
  • This is also correct. UV wavelengths are characteristic of Lyman transitions.

Therefore, both statements are correct.

Correct Answer: 1) Both 1 and 2

142

Heisenberg's uncertainty principle can be expressed by

  1. ((a))

    Δx×Δphπ\Delta x \times \Delta p \ge \frac{h}{\pi}

  2. ((b))

    ΔphΔx\Delta p \ge \frac{h}{\Delta x}

  3. ((c))

    Δx×Δph4π\Delta x \times \Delta p \ge \frac{h}{4\pi}

  4. ((d))

    Δx×Δph2π\Delta x \times \Delta p \ge \frac{h}{2\pi}

Show Answer
Answer: ((c))

Δx×Δph4π\Delta x \times \Delta p \ge \frac{h}{4\pi}

EXPLANATION:

Heisenberg's Uncertainty Principle

  • The Heisenberg Uncertainty Principle is a fundamental concept in quantum mechanics.
  • It states that it is impossible to simultaneously determine the exact position (Δx) and momentum (Δp) of a particle with absolute precision.
  • The principle is mathematically expressed as:

Δx × Δp ≥ h / (4π)

where:

  • Δx = uncertainty in position
  • Δp = uncertainty in momentum
  • h = Planck’s constant
  • Among the given options:
  • Option (3): Δx × Δp ≥ h / 4π is the correct standard form of the Heisenberg uncertainty relation.

Therefore, the correct answer is Δx × Δp ≥ h / 4π

143

Which one of the following ions contains the maximum number of unpaired electrons?

  1. ((a))

    Mg2+

  2. ((b))

    Ti3+

  3. ((c))

    V3+

  4. ((d))

    Fe2+

Show Answer
Answer: ((d))

Fe2+

CONCEPT:

Unpaired Electrons in Ions

  • Unpaired electrons in an ion correspond to the electrons that are not paired in the orbitals of the ion's electron configuration.
  • The number of unpaired electrons depends on the electronic configuration of the ion and follows Hund's rule, which states that electrons occupy degenerate orbitals singly before pairing occurs.

EXPLANATION:

  • Mg2+: Magnesium loses 2 electrons, resulting in a configuration of [Ne]. All orbitals are fully paired, so there are 0 unpaired electrons.
  • Ti3+: Titanium loses 3 electrons, resulting in a configuration of [Ar] 3d1. There is 1 unpaired electron.
  • V3+: Vanadium loses 3 electrons, resulting in a configuration of [Ar] 3d2. According to Hund's rule, there are 2 unpaired electrons.
  • Fe2+: Iron loses 2 electrons, resulting in a configuration of [Ar] 3d6. Following Hund's rule, there are 4 unpaired electrons.
  • Comparing the number of unpaired electrons:
  • Mg2+: 0 unpaired electrons
  • Ti3+: 1 unpaired electron
  • V3+: 2 unpaired electrons
  • Fe2+: 4 unpaired electrons
  • Among the given ions, Fe2+ has the maximum number of unpaired electrons (4).

Therefore, the correct answer is option 4: Fe2+.

144

Considering H2​O as a weak field ligand, the number of unpaired electrons in [Mn(H2​O)6​]2+ will be

  1. ((a))

    5

  2. ((b))

    2

  3. ((c))

    4

  4. ((d))

    3

Show Answer
Answer: ((a))

5

CONCEPT:

Weak Field Ligands and Crystal Field Splitting

  • Ligands like H2O are considered weak field ligands as they cause a small crystal field splitting in the d-orbitals of the central metal ion.
  • In the presence of weak field ligands, the crystal field splitting energy (Δo) is less than the pairing energy. Therefore, electrons prefer to remain unpaired and occupy higher energy orbitals, following Hund's rule.

EXPLANATION:

  • The given complex is [Mn(H2O)6]2+, where Mn is in the +2 oxidation state.
  • To determine the number of unpaired electrons:
  • The electronic configuration of Mn (atomic number 25) in its neutral state is: [Ar] 3d5 4s2.
  • In the Mn2+ ion, two electrons are removed (from the 4s orbital), so the configuration becomes: [Ar] 3d5.
  • Since H2O is a weak field ligand, the crystal field splitting energy is small, and the 3d electrons remain unpaired in the five d-orbitals.
  • Thus, all five electrons in the 3d orbitals of Mn2+ are unpaired.

Therefore, the number of unpaired electrons in [Mn(H2O)6]2+ is 5.

145

If Δ0​<p, then the electronic configuration of d4 species will be

  1. ((a))

    \(\text{t}{2\text{g}}^{4} \text{e}{\text{g}}^{0}\)

  2. ((b))

    \(\text{e}{\text{g}}^{4} \text{t}{2\text{g}}^{0}\)

  3. ((c))

    \(\text{t}{2\text{g}}^{3} \text{e}{\text{g}}^{1}\)

  4. ((d))

    \(\text{e}{\text{g}}^{2} \text{t}{2\text{g}}^{2}\)

Show Answer
Answer: ((c))

\(\text{t}{2\text{g}}^{3} \text{e}{\text{g}}^{1}\)

CONCEPT:

Crystal Field Splitting and Weak Field Ligands

  • In a coordination complex, the d-orbitals of the central metal ion split into two sets of orbitals: t2g (lower energy) and eg (higher energy).
  • The splitting energy between these two sets of orbitals is denoted as Δ0.
  • The relative magnitude of Δ0 compared to the pairing energy (p) determines the arrangement of electrons in the d-orbitals.
  • If Δ0 < p (weak field ligands), electrons prefer to occupy higher energy orbitals (eg) before pairing in the lower energy orbitals (t2g).

EXPLANATION:

  • For a d4 configuration, if Δ0 < p (weak field case):
  • Electrons will follow Hund's Rule, occupying each orbital singly before pairing occurs.
  • The first three electrons will occupy the lower energy t2g orbitals.
  • The fourth electron will occupy one of the higher energy eg orbitals.
  • This results in the electronic configuration: t2g3 eg1.

Therefore, the correct answer is Option 3: t2g3 eg1.

146

Which one of the following hybridizations is involved in the compounds having bipyramidal structure?

  1. ((a))

    sp3d2

  2. ((b))

    sp3d

  3. ((c))

    sp3d3

  4. ((d))

    d2sp3

Show Answer
Answer: ((b))

sp3d

CONCEPT:

Hybridization and Molecular Geometry

  • Hybridization is the process of mixing atomic orbitals to form new hybrid orbitals suitable for the pairing of electrons.
  • The geometry of a molecule depends on the type of hybridization involved.
  • A trigonal bipyramidal structure corresponds to sp3d hybridization.
  • An octahedral structure corresponds to sp3d2 hybridization.

EXPLANATION:

  • In molecules with bipyramidal geometry:
  • The central atom utilizes one s orbital, three p orbitals, and one d orbital to form five sp3d hybrid orbitals.
  • These hybrid orbitals arrange themselves to minimize electron repulsion, forming a trigonal bipyramidal structure.
  • Examples of compounds with trigonal bipyramidal geometry include:
  • PCl5 (Phosphorus pentachloride)
  • PF5 (Phosphorus pentafluoride)
  • Other hybridizations, such as sp3d2, sp3d3, and d2sp3, result in different molecular geometries (e.g., octahedral or pentagonal bipyramidal).

Therefore, the hybridization involved in compounds having bipyramidal structure is sp3d.

147

When 92238 U disintegrates, which one of the following stable elements is formed as the end-product?

  1. ((a))

    83200Bi_{83}^{200}\text{Bi}

  2. ((b))

    82208Pb_{82}^{208}\text{Pb}

  3. ((c))

    82206Pb_{82}^{206}\text{Pb}

  4. ((d))

    82207Pb_{82}^{207}\text{Pb}

Show Answer
Answer: ((c))

82206Pb_{82}^{206}\text{Pb}

CONCEPT:

Radioactive Disintegration of Uranium-238

  • Uranium-238 (238U) undergoes a natural radioactive decay series known as the uranium series or radium series.
  • This process involves a sequence of alpha (α) and beta (β) decays.
  • In alpha decay, the nucleus loses 2 protons and 2 neutrons: mass number decreases by 4 and atomic number decreases by 2.
  • In beta decay, a neutron is converted into a proton: atomic number increases by 1, mass number remains unchanged.

EXPLANATION:

  • 238U (Z = 92) decays through a series of 8 α-decays and 6 β--decays.
  • Each α-decay reduces the atomic number by 2 and mass number by 4.
  • Each β--decay increases the atomic number by 1 (mass unchanged).
  • Applying this:
  • 8 α-decays → mass number = 238 - 8×4 = 206
  • Atomic number after 8 α-decays = 92 - 8×2 = 76
  • Then, 6 β--decays → atomic number = 76 + 6 = 82
  • The end product is 206Pb (lead-206), which is stable and non-radioactive.

Therefore, the correct answer is: 3) 20682Pb.

148

What is the half-life of C14, if its disintegration constant (λ) is 2.31×10−4 years-1?

  1. ((a))

    0.3×104 years

  2. ((b))

    0.3×106 years

  3. ((c))

    3.0×104 years

  4. ((d))

    0.3×103 years

Show Answer
Answer: ((a))

0.3×104 years

CONCEPT:

Half-Life and Disintegration Constant

  • The half-life (t1/2) of a radioactive substance is the time it takes for half of the substance to decay.
  • The relationship between the half-life and the disintegration constant (λ) is given by the formula:

t1/2 = ln(2) / λ

  • ln(2) is the natural logarithm of 2, approximately equal to 0.693.
  • λ is the disintegration constant and has units of time-1.

EXPLANATION:

  • Given:
  • Disintegration constant (λ) = 2.31 × 10-4 years-1
  • Using the formula for half-life:

t1/2 = ln(2) / λ

  • t1/2 = 0.693 / (2.31 × 10-4)
  • Performing the calculation:

t1/2 = 0.693 / 2.31 × 10-4

t1/2 ≈ 3.0 × 103 years

  • However, this value matches Option 1 because it is expressed as 0.3 × 104 years (equivalent to 3.0 × 103 years).

Therefore, the correct answer is 0.3 × 104 years.

149

With reference to catalysis, which of the following statements is/are correct?

  1. Catalyst lowers the energy of activation of the reaction.
  2. The overall change in energy of reaction is unaffected. Select the correct answer from the codes given below.
  1. ((a))

    Only 2 

  2. ((b))

    Only 1

  3. ((c))

    Both 1 and 2

  4. ((d))

    Neither 1 nor 2

Show Answer
Answer: ((c))

Both 1 and 2

CONCEPT:

Catalysis

  • A catalyst is a substance that increases the rate of a chemical reaction without itself undergoing any permanent chemical change.
  • The catalyst works by lowering the activation energy of the reaction, making it easier for reactants to convert into products.
  • The overall change in energy of the reaction (ΔH or enthalpy change) remains unaffected because the catalyst only affects the pathway of the reaction, not the thermodynamics.

EXPLANATION:

  • Statement 1: "Catalyst lowers the energy of activation of the reaction."
  • This statement is correct. A catalyst provides an alternative pathway with lower activation energy, allowing the reaction to proceed faster.
  • Statement 2: "The overall change in energy of reaction is unaffected."
  • This statement is also correct. The catalyst does not alter the enthalpy change (ΔH) of the reaction; it only modifies the reaction pathway.
  • Since both statements are correct, the correct answer is Option 3: Both 1 and 2.

Therefore, the correct answer is Option 3.

150

The rate law for a reaction is given below : 

rate = \(k \ \text{C}{\text{A}}^{r} \ \text{C}{\text{B}}^{s} \ \text{C}_{\text{C}}^{t}\)

Where CA​, CB​ and CC​ are molar concentrations of reactants A, B and C respectively. What is the order with respect to B?

  1. ((a))

    r

  2. ((b))

    t

  3. ((c))

    r+t

  4. ((d))

    s

Show Answer
Answer: ((d))

s

CONCEPT:

Order of Reaction with Respect to a Reactant

  • The order of a reaction with respect to a given reactant refers to the power of its concentration in the rate law expression.
  • For a general rate law of the form:

rate = k [A]^r [B]^s [C]^t

  • Where:
  • [A], [B], and [C] are the concentrations of reactants A, B, and C.
  • r, s, and t are the orders of the reaction with respect to A, B, and C respectively.
  • The order of the reaction with respect to a particular reactant is the exponent of its concentration in the rate law expression.

EXPLANATION:

  • From the given rate law:

rate = k [A]^r [B]^s [C]^t

  • The order with respect to reactant B is the exponent of [B], which is s.

Therefore, the order with respect to B is: 4) s.

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